The Lithium conducting electrolyte is a critical component of Li-ion batteries, as it has an important impact on performance and its durability, in particular in case of extreme environmental conditions. At low temperatures, a partial solidification can occur, while high temperatures can promote the degradation of the electrolyte. Using time-of-flight (ToF) neutron radiography, the possibility of imaging such changes in a fully non-invasive manner was demonstrated for the first time.