Scientific Highlights

Quantum spin liquids are exotic states of matter that form when strongly frustrated magnetic interactions induce a highly entangled quantum paramagnet far below the energy scale of the magnetic interactions. Three-dimensional cases are especially challenging due to the significant reduction of the influence of quantum fluctuations. Here, we report the magnetic characterization of K₂Ni₂(SO₄)₃ forming a three-dimensional network of Ni²⁺ spins.

Materials with strongly correlated electrons often exhibit interesting physical properties. An example of these materials is the layered oxide perovskite Sr₂RuO₄, which has been intensively investigated due to its unusual properties. Whilst the debate on the symmetry of the superconducting state in Sr₂RuO₄ is still ongoing, a deeper understanding of the Sr₂RuO₄ normal state appears crucial as this is the background in which electron pairing occurs. Here, by using low-energy muon spin spectroscopy we discover the existence of surface magnetism in Sr₂RuO₄ in its normal state.

The crystal structure and magnetic correlations in triangular antiferromagnet FeGa2S4 are studied by x-ray diffraction, magnetic susceptibility, neutron diffraction, and neutron inelastic scattering. We report significant mixing at the cation sites and disentangle magnetic properties dominated by major and minor magnetic sites.

GeTe that exhibits a strong anharmonicity and a ferroelectric phase transition between the rhombohedral and cubic structures has emerged as one of the leading thermoelectric materials. Herein, combining molecular dynamics simulations and inelastic neutron scattering measurements, the lattice dynamics in GeTe have been investigated to reveal the soft-mode mechanisms across the phase transition.

Magnetic anisotropy is anticipated to govern the formation of exotic spin textures reported recently in cubic chiral magnets, like low-temperature tilted conical and skyrmion lattice (SkL) states and metastable SkLs with various lattice geometry. Motivated by these findings, we quantified the cubic anisotropy in a series of CoZnMn-type cubic chiral magnets. We found that the strength of anisotropy is highly enhanced towards low temperatures. Moreover, not only the magnitude but also the character of cubic anisotropy drastically varies upon changing the Co/Mn ratio.

There is considerable evidence that the superconducting state of Sr₂RuO₄ breaks time reversal symmetry. In the experiments showing time reversal symmetry breaking, its onset temperature, T_TRSB, is generally found to match the critical temperature, T_c, within resolution. In combination with evidence for even parity, this result has led to consideration of a d_xz ± id_yz order parameter.

CeRh₂As₂, a nonsymmorphic heavy fermion material, was recently reported to host a remarkable temperature versus z-axis magnetic-field phase diagram with two superconducting phases. In this material, the two inequivalent Ce sites per unit cell, related by inversion symmetry, introduce a sublattice structure corresponding to an extra internal degree of freedom. In this work, we propose a classification of the possible superconducting states in CeRh₂As₂ from the two Ce-sites' perspective.

Schematic representation of the method used to grow RENiO₃ nickelate single crystals covering the full 4f series and Y. This novel procedure, based on the use of moderate oxygen gas pressures (2000 bar), solvothermal growth in a temperature gradient, and highly reactive eutectic salt mixtures as fluxes, yields prismatic-shaped crystals with flat facets and sizes up to ∼75 μm.

The Kitaev quantum spin liquid epitomizes an entangled topological state, for which twoflavors of fractionalized low-energy excitations are predicted: the itinerant Majorana fermion and the Z₂ gauge flux. It was proposed recently that fingerprints of fractional excitations are encoded in the phonon spectra of Kitaev quantum spin liquids through a novel fractional- excitation-phonon coupling. Here, we detect anomalous phonon effects in α-RuCl₃ using inelastic X-ray scattering with meV resolution.

Intertwining quantum order and non-trivial topology is at the frontier of condensed matter physics. A charge- density-wave-like order with orbital currents has been pro- posed for achieving the quantum anomalous Hall effect in topological materials and for the hidden phase in cuprate high-temperature superconductors. However, the experimental realization of such an order is challenging. Here we use high-resolution scanning tunnelling microscopy to discover an unconventional chiral charge order in a kagome material, KV₃Sb₅, with both a topological band structure and a superconducting ground state.

The silver ruthenium oxide AgRuO₃ consists of honeycomb Ru₂⁵⁺O₆²⁻ layers and can be considered and can be considered an analogue of SrRu₂O₆ with a different intercalation. We present measurements of magnetic susceptibility and specific heat on AgRuO₃ single crystals, which reveal a sharp antiferromagnetic transition at 342(3) K. The electrical transport in single crystals of AgRuO₃ is determined by a combination of activated conduction over an intrinsic semiconducting gap of ≈100 meV and carriers trapped and thermally released from defects.

Various imaging methods in materials research have pursued the characterization of material composition and its change in space and time. When it comes to liquid matter far from equilibrium, such as mixing and evaporating mixtures of solutes and solvents, of paramount importance in diverse solution-processing methods, the quantitative and in situ characterization remains challenging. Our research with the evaporating ...

Ultrafast manipulation of magnetic states holds great promise for progress in our understanding of new quantum states and technical applications, but our current knowledge of transient magnetism is very limited. Our work elucidates the nature of transient magnetism in gapped antiferromagnets using Sr₃Ir₂O₇ as a model material. We find that transient magnetic fluctuations are trapped throughout the entire Brillouin zone while remaining present beyond the time that is required to restore the original spin network.

The exploration of topological electronic phases that result from strong electronic correlations is a frontier in condensed matter physics. One class of systems that is currently emerging as a platform for such studies are so-called kagome magnets based on transition metals. Using muon spin-rotation, we explore magnetic correlations in the kagome magnet Co₃Sn_2−xIn_xS₂ as a function of In-doping, providing putative evidence for an intriguing incommensurate helimagnetic (HM) state. Our results show that, while the undoped sample exhibits an out-of-plane ferromagnetic (FM) ground state, at 5% of In-doping the system enters a state in which FM and in-plane antiferromagnetic (AFM) phases coexist.

Chiral superconductors are novel topological materials with finite angular momentum Cooper pairs circulating around a unique chiral axis, thereby spontaneously breaking time-reversal symmetry. They are rather scarce and usually feature triplet pairing: a canonical example is the chiral p-wave state realized in the A-phase of superfluid He³. Chiral triplet super- conductors are, however, topologically fragile with the corresponding gapless boundary modes only weakly protected against symmetry-preserving perturbations in contrast to their singlet counterparts. Using muon spin relaxation measurements ...

Revealing the predominant driving force behind symmetry breaking in correlated materials is sometimes a formidable task due to the intertwined nature of different degrees of freedom. This is the case for La_2−xSr_xNiO_4+δ, in which coupled incommensurate charge and spin stripes form at low temperatures. Here, we use resonant x-ray photon correlation spectroscopy to study the temporal stability and domain memory of the charge and spin stripes in La_2−xSr_xNiO_4+δ.