Publications 2017

Operando X-ray absorption spectroscopy: A powerful tool toward water splitting catalyst development E. Fabbri, D.F. Abbott, M. Nachtegaal, T.J. Schmidt

DOI: 10.1016/j.coelec.2017.08.009OG-5423
 

Microstructure-property relationships in a gas diffusion layer (GDL) for Polymer Electrolyte Fuel Cells, Part II: pressure-induced water injection and liquid permeability L. Holzer, O. Pecho, J. Schumacher, Ph. Marmet, F.N. Büchi, A. Lamibrac, B. Münch

DOI: 10.1016/j.electacta.2017.04.141OG-5422
 

Microstructure-property relationships in a gas diffusion layer (GDL) for Polymer Electrolyte Fuel Cells, Part I: effect of compression and anisotropy of dry GDL L. Holzer, O. Pecho, J. Schumacher, Ph. Marmet, O. Stenzel, F.N. Büchi, A. Lamibrac, B. Münch

DOI: 10.1016/j.electacta.2017.01.030OG-5422
 

Experimental and pore-level numerical investigation of water evaporation in gas diffusion layers of polymer electrolyte fuel cells M.A. Safi, N.I. Prasianakis, J. Mantzaras, A. Lamibrac, F.N. Büchi

DOI: 10.1016/j.ijheatmasstransfer.2017.07.050OG-5422
 

Electrochemical hydrogen compression: Efficient pressurization concept derived from an energetic evaluation M. Suermann, T. Kiupel, T.J. Schmidt, F.N. Büchi

DOI: 10.1149/2.1361712jesOG-5422
 

Influence of operating conditions and material properties on the mass transport losses of polymer electrolyte water electrolysis M. Suermann, K. Takanohashi, A. Lamibrac, T.J. Schmidt, F.N. Büchi

DOI: 10.1149/2.13517109jesOG-5422
 

Fighting the noise: Towards the limits of subsecond X-ray tomographic microscopy of PEFC H. Xu, M. Bührer, F. Marone, T.J. Schmidt, F.N. Büchi, J. Eller

DOI: 10.1149/08008.0395ecstOG-5422
 

Operando monitoring of early Ni-mediated surface reconstruction in layered lithiated Ni–Co–Mn oxides D. Streich, C. Erk, A. Guéguen, P. Müller, F.-F. Chesneau, E.J. Berg

DOI: 10.1021/acs.jpcc.7b02303OG-5410 , OG-5412
 

Hydrocarbon proton exchange membranes: Degradation and stabilization L. Gubler, W. Koppenol

DOI: 10.1002/9781119196082.ch5OG-5421
 

Crystal structure evolution via operando neutron diffraction during long-term cycling of a customized 5 V full Li-ion cylindrical cell LiNi0.5Mn1.5O4vs. graphite L. Boulet-Roblin, D. Sheptyakov, P. Borel, C. Tessier, P. Novák, C. Villevieille

DOI: 10.1039/C7TA07917FOG-5410 , OG-5411
 

Nanostructuring noble metals as unsupported electrocatalysts for polymer electrolyte fuel cells B. Cai, S. Henning, J. Herranz, T.J. Schmidt, A. Eychmüller

DOI: 10.1002/aenm.201700548OG-5423
 

Membrane architecture with ion-conducting channels through swift heavy ion induced graft copolymerization V. Sproll, M. Handl, R. Hiesgen, K.A. Friedrich, T.J. Schmidt, L. Gubler

DOI: 10.1039/C7TA07323BOG-5421
 

Cycling behavior of silicon-containing graphite electrodes, Part B: Effect of the silicon source T. Schott, R. Robert, S.Pacheco Benito, P.A. Ulmann, P. Lanz, S. Zürcher, M.E. Spahr, P. Novák, S. Trabesinger

DOI: 10.1021/acs.jpcc.7b08457OG-5410 , OG-5413
 

Elucidation of reaction mechanisms of Ni2SnP in Li-ion and Na-ion systems C. Marino, N. Dupré, C. Villevieille

DOI: 10.1016/j.jpowsour.2017.08.096OG-5410 , OG-5411
 

Interface and safety properties of phosphorus-based negative electrodes in Li-ion batteries C. Marino, M. El Kazzi, E.J. Berg, M. He, C. Villevieille

DOI: 10.1021/acs.chemmater.7b01128OG-5410 , OG-5411 , OG-5412 , OG-5414
 

Direct observation of active material interactions in flowable electrodes using X-ray tomography K.B. Hatzell, J. Eller, S.L. Morelly, M.H. Tang, N.J. Alvarez, Y. Gogotsi

DOI: 10.1039/C6FD00243AOG-5422
 

Tackling capacity fading in vanadium flow batteries with amphoteric membranes F. Oldenburg, T.J. Schmidt, L. Gubler

DOI: 10.1016/j.jpowsour.2017.09.051OG-5421
 

Electrochemical impedance spectroscopy of a Li–S battery: Part 2. Influence of separator chemistry on the lithium electrode/electrolyte interface J. Conder, C. Villevieille, S. Trabesinger, P. Novák, L. Gubler, R. Bouchet

DOI: 10.1016/j.electacta.2017.09.148OG-5410 , OG-5411 , OG-5413 , OG-5421
 

Capacitive electronic metal-support interactions: Outer surface charging of supported catalyst particles T. Binninger, T.J. Schmidt, D. Kramer

DOI: 10.1103/PhysRevB.96.165405OG-5423
 

Cycling behavior of silicon-containing graphite electrodes, Part A: Effect of the lithiation protocol T. Schott, R. Robert, P.A. Ulmann, P. Lanz, S. Zürcher, M.E. Spahr, P. Novák, S. Trabesinger

DOI: 10.1021/acs.jpcc.7b05919OG-5410 , OG-5413
 

Boosting Pt oxygen reduction reaction activity by tuning the tin oxide support E. Fabbri, A. Rabis, Y. Chino, M. Uchida, T.J. Schmidt

DOI: 10.1016/j.elecom.2017.09.006OG-5423
 

A new concept of an air-electrode catalyst for Li2O2 decomposition using MnO2 nanosheets on rechargeable Li-O2 batteries M. Saito, S. Kosaka, T. Fujinami, Y. Tachikawa, H. Shiroishi, D. Streich, E.J. Berg, P. Novák, S. Seki

DOI: 10.1016/j.electacta.2017.08.183OG-5410 , OG-5412
 

Dynamic surface self-reconstruction is the key of highly active perovskite nano-electrocatalysts for water splitting E. Fabbri, M. Nachtegaal, T. Binninger, X. Cheng, B.-J. Kim, J. Durst, F. Bozza, T. Graule, R. Schäublin, L. Wiles, M. Pertoso, N. Danilovic, K.E. Ayers, T.J. Schmidt

DOI: 10.1038/nmat4938OG-5423
 

Colloidal synthesis and electrochemistry of surface coated nano-LiNi0.80Co0.15Al0.05O2 R. Asakura, P. Novák, R. Robert

DOI: 10.1149/2.1431712jesOG-5410 , OG-5414
 

Unsupported Pt-Ni aerogels with enhanced high current performance and durability in fuel cell cathodes S. Henning, H. Ishikawa, L. Kühn, J. Herranz, E. Müller, A. Eychmüller, T.J. Schmidt

DOI: 10.1002/anie.201704253OG-5423
 

Durability of unsupported Pt-Ni aerogels in PEFC cathodes S. Henning, J. Herranz, H. Ishikawa, B.J. Kim, D. Abbott, L. Kühn, A. Eychmüller, T.J. Schmidt

DOI: 10.1149/2.0131712jesOG-5423
 

Comparative operando study of degradation mechanisms in carbon-based electrochemical capacitors with Li2SO4 and LiNO3 electrolytes K. Fic, M. He, E.J. Berg, P. Novák, E. Frackowiak

DOI: 10.1016/j.carbon.2017.05.061OG-5410 , OG-5412
 

Amphoteric ion-exchange membranes with significantly improved vanadium barrier properties for all-vanadium redox flow batteries O. Nibel, T. Rojek, T.J. Schmidt, L. Gubler

DOI: 10.1002/cssc.201700610OG-5421
 

Numerical partitioning model for the Koutecký-Levich analysis of electrochemical flow cells with a combined channel/wall-jet geometry S.A. Tschupp, S.E. Temmel, N. Poyatos Salguero, J. Herranz, T.J. Schmidt

DOI: 10.1149/2.0441711jesOG-5423
 

State-of-the-art nanofabrication in catalysis K. Waiz, S.A. Tschupp, J. Herranz, T.J. Schmidt, Y. Ekinci, J.A. van Bokhoven

DOI: 10.2533/chimia.2017.160OG-5423
 

Highly active and stable iridium pyrochlores for oxygen evolution reaction D. Lebedev, M. Povia, K. Waltar, P.M. Abdala, I.E. Castelli, E. Fabbri, M.V. Blanco, A. Fedorov, C. Coperet, N. Marzari, T.J. Schmidt

DOI: 10.1021/acs.chemmater.7b00766OG-5423
 

Effect of ball milling on the electrocatalytic activity of Ba0.5Sr0.5Co0.8Fe0.2O3 towards the oxygen evolution reaction X. Cheng, E. Fabbri, B-J. Kim, M. Nachtegaal, T.J. Schmidt

DOI: 10.1039/c7ta00794aOG-5423
 

Effect of acid washing on the oxygen reduction reaction activity of Pt-​Cu aerogel catalysts S. Henning, L. Kuhn, J. Herranz, M. Nachtegaal, R. Hubner, M. Werheid, A. Eychmuller, T.J. Schmidt

DOI: 10.1016/j.electacta.2017.03.019OG-5423
 

Improved electrochemical performances of Li-rich nickel cobalt manganese oxide by partial substitution of Li+ by Mg2+ S. Sallard, D. Sheptyakov, C. Villevieille

DOI: 10.1016/j.jpowsour.2017.05.028OG-5410 , OG-5411
 

Surface and morphological investigation of the electrode/electrolyte properties in an all-solid-state battery using a Li2S-P2S5 solid electrolyte X. Wu, M. El Kazzi, C. Villevieille

DOI: 10.1007/s10832-017-0084-zOG-5410 , OG-5411 , OG-5414
 

Elucidation of the reaction mechanisms of isostructural FeSn2 and CoSn2 negative electrodes for Na-ion batteries L.O. Vogt, C. Villevieille

DOI: 10.1039/C6TA10535AOG-5410 , OG-5411
 

Performance of different carbon electrode materials: Insights into stability and degradation under real vanadium redox flow battery operating conditions O. Nibel, S.M. Taylor, A. Pătru, E. Fabbri, L. Gubler, T.J. Schmidt

DOI: 10.1149/2.1081707jesOG-5421 , OG-5423
 

Direct observation of lithium polysulfides in lithium–sulfur batteries using operando X-ray diffraction J. Conder, R. Bouchet, S. Trabesinger, C. Marino, L. Gubler, C. Villevieille

DOI: 10.1038/nenergy.2017.69OG-5410 , OG-5411 , OG-5421
 

Polyvinylamine-containing adsorbent by radiation-induced grafting of N-Vinylformamide onto ultrahigh molecular weight polyethylene films and hydrolysis for CO2 capture T. Rojek, L. Gubler, M.M. Nasef, E. Abouzari-Lotf

DOI: 10.1021/acs.iecr.7b00862OG-5421
 

Electrochemical impedance spectroscopy of a Li–S battery: Part 1. Influence of the electrode and electrolyte compositions on the impedance of symmetric cells J. Conder, C. Villevieille, S. Trabesinger, P. Novák, L. Gubler, R. Bouchet

DOI: 10.1016/j.electacta.2017.05.041OG-5410 , OG-5411 , OG-5413 , OG-5421
 

Ligand influence in Li-ion battery hybrid active materials: Ni methylenediphosphonate vs. Ni dimethylamino methylenediphosphonate S. Schmidt, S. Sallard, D. Sheptyakov, P. Novák, C. Villevieille

DOI: 10.1039/C7CC01982COG-5410 , OG-5411
 

High pressure polymer electrolyte water electrolysis: Test bench development and electrochemical analysis M. Suermann, A. Pătru, T.J. Schmidt, F.N. Buechi

DOI: 10.1016/j.ijhydene.2017.01.224OG-5422 , OG-5423
 

Unraveling thermodynamics, stability, and oxygen evolution activity of strontium ruthenium perovskite oxide B.-J. Kim, D.F. Abbott, X. Cheng, E. Fabbri, M. Nachtegaal, F. Bozza, I.E. Castelli, D. Lebedev, R. Schäublin, C. Copéret, T. Graule, N. Marzari, T.J. Schmidt

DOI: 10.1021/acscatal.6b03171OG-5423
 

Impact of cobalt content in Na0.67MnxFeyCozO2 (x + y + z = 1), a cathode material for sodium ion batteries C. Marino, E. Marelli, C. Villevieille

DOI: 10.1039/C7RA00566KOG-5410 , OG-5411
 

Stabilization of Pt nanoparticles due to electrochemical transistor switching of oxide support conductivity T. Binninger, R. Mohamed, A. Patru, K. Waltar, E. Gericke, X. Tuaev, E. Fabbri, P. Levecque, A. Hoell, T.J. Schmidt

DOI: 10.1021/acs.chemmater.6b04851OG-5423
 

Unraveling the interaction mechanism between amidoxime groups and vanadium ions at various pH conditions O. Nibel, M. Bon, M.L. Agiorgousis, T. Laino, L. Gubler, T.J. Schmidt

DOI: 10.1021/acs.jpcc.6b12540OG-5421
 

Mask-assisted electron radiation grafting for localized through-volume modification of porous substrates: influence of electron energy on spatial resolution A. Forner-Cuenca, V. Manzi-Orezzoli, P.M. Kristiansen, L. Gubler, T.J. Schmidt

DOI: 10.1016/j.radphyschem.2017.01.036OG-5420 , OG-5424
 

Silicone Nanofilament-Supported Mixed Nickel-Metal Oxides for AlkalineWater Electrolysis D.F. Abbott, M. Meier, G.R. Meseck, E. Fabbri, S. Seeger, T.J. Schmidt

DOI: 10.1149/2.0201704jesOG-5423
 

IrO2-​TiO2: a High-​Surface Area, Active and Stable Electrocatalyst for Oxygen Evolution Reaction E. Oakton, D. Lebedev, M. Povia, D.F. Abbott, E. Fabbri, A. Fedorov, M. Nachtegaal, C. Coperet, T.J. Schmidt

DOI: 10.1021/acscatal.6b03246OG-5423
 

Critical review—identifying critical Gaps for polymer electrolyte water electrolysis development U. Babic, M. Suermann, F.N. Büchi, L. Gubler, T.J. Schmidt

DOI: 10.1149/2.1441704jesOG-5421 , OG-5422
 

Structural analysis and electrochemical properties of bimetallic palladium–platinum aerogels prepared by a two-step gelation process M. Oezaslan , A.-K. Herrmann, M. Werheid, A.I. Frenkel, M. Nachtegaal, C. Dosche, C. Laugier Bonnaud, H.C. Yilmaz, L. Kühn, E. Rhiel, N. Gaponik, A. Eychmüller, T.J. Schmidt

DOI: 10.1002/cctc.201600667OG-5423
 

Fe and Co methylene diphosphonates as conversion materials for Li-ion batteries S. Schmidt, S. Sallard, D. Sheptyakov, M. Nachtegaal, P. Novák, C. Villevieille

DOI: 10.1016/j.jpowsour.2016.12.090OG-5410 , OG-5411
 

CuSbS2 as a negative electrode material for sodium ion batteries C. Marino, T. Block, R. Pöttgen, C. Villevieille

DOI: 10.1016/j.jpowsour.2016.12.100OG-5410 , OG-5411
 

The counterintuitive impact of separator–electrolyte combinations on the cycle life of graphite–silicon composite electrodes T. Schott, J.L. Gómez-Cámer, Ch. Bünzli, S. Trabesinger, P. Novák

DOI: 10.1016/j.jpowsour.2017.01.055OG-5410 , OG-5413
 

Operando properties of gas diffusion layers: Saturation and liquid permeability J. Eller, J. Roth, F. Marone, M. Stampanoni, F.N. Büchi

DOI: 10.1149/2.0881702jesOG-5422
 

Relationship between the properties and cycle Life of Si/C composites as performance-enhancing additives to graphite electrodes for Li-Ion batteries T. Schott, J.L. Gómez-Cámer, P. Novák, S. Trabesinger

DOI: 10.1149/2.0701702jesOG-5410 , OG-5413
 

Influence of surface oxygen groups on V(II) oxidation reaction kinetics S.M. Taylor, A. Patru, E. Fabbri, T.J. Schmidt

DOI: 10.1016/j.elecom.2016.12.003OG-5423