A star is born

Swiss Light Source SLS reveals complex chemistry inside ‘stellar nurseries’

An international team of researchers has uncovered what might be a critical step in the chemical evolution of molecules in cosmic “stellar nurseries.” In these vast clouds of cold gas and dust in space, trillions of molecules swirl together over millions of years. The collapse of these interstellar clouds eventually gives rise to young stars and planets.

Using PEPICO spectroscopy at the SLS, researchers discovered how hexagonally-shaped ortho-benzyne molecules can combine with methyl radicals to form a series of larger organic molecules, each containing a ring of five carbon atoms. (Credit: Henry Cardwell)

Like human bodies, stellar nurseries contain a lot of organic molecules, which are made up mostly of carbon and hydrogen atoms. The group's results, published in the journal Nature Astronomy, reveal how certain large organic molecules may form inside these clouds. It’s one tiny step in the eons-long chemical journey that carbon atoms undergo—forming in the hearts of dying stars, then becoming part of planets, living organisms on Earth and perhaps beyond.

“In these cold molecular clouds, you’re creating the first building blocks that will, in the end, form stars and planets,” said Jordy Bouwman, research associate at the Laboratory for Atmospheric and Space Physics (LASP) and assistant professor in the Department of Chemistry at University Colorado Boulder.

For the new study, Bouwman and his colleagues took a deep dive into one stellar nursery in particular: the Taurus Molecular Cloud (TMC-1). This region sits in the constellation Taurus and is roughly 440 light years (more than 2 quadrillion miles) from Earth. The chemically complex environment is an example of what astronomers call an “accreting starless core.” Its cloud has begun to collapse, but scientists haven’t yet detected embryonic stars emerging inside it.

The team's findings hinge on a deceptively simple molecule called ortho-benzyne. Drawing on experiments using photoelectron photoion coincidence (PEPICO) spectroscopy at the Swiss Light Source SLS, the researchers showed that this molecule can readily combine with others in space to form a wide range of larger organic molecules. Small building blocks, in other words, become big building blocks. And, Bouwman said, those reactions could be a sign that stellar nurseries are a lot more interesting than scientists give them credit for.

“We’re only at the start of truly understanding how we go from these small building blocks to larger molecules,” he said. “I think we’ll find that this chemistry is so much more complex than we thought, even at the earliest stages of star formation.”

Fateful observation

On the surface, cold molecular clouds might not seem like a hotbed of chemical activity. As their name suggests, these galactic primordial soups tend to be frigid, often hovering around -263 degrees Celsius, just 10 degrees above absolute zero. Most reactions need at least a little bit of heat to get a kick-start.

But cold or not, complex chemistry seems to be happening in stellar nurseries. TMC-1, in particular, contains surprising concentrations of relatively large organic molecules with names like fulvenallene and 1- and 2-ethynylcyclopentadiene. Chemists call them “five-membered ring compounds” because they each contain a ring of carbon atoms shaped like a pentagon.

“Researchers kept detecting these molecules in TMC-1, but their origin was unclear,” Bouwman said. Now, he and his colleagues think they have an answer.

In 2021, researchers using the Yebes 40-metre Radiotelescope in Spain found an unexpected molecule hiding in the clouds of gas of TMC-1: ortho-benzyne. Bouwman explained that this small molecule, made up of a ring of six carbon atoms with four hydrogens, is one of the extroverts of the chemistry world. It easily interacts with a number of other molecules and doesn’t require a lot of heat to do so. “There's no barrier to reaction,” Bouwman said. “That means it has the potential to drive complex chemistry in cold environments.”

PEPICO spectroscopy reveals the culprit

To find out what kind of complex chemistry was happening in TMC-1, Bouwman and his colleagues—who hail from the United States, Germany, the Netherlands and Switzerland— turned to PEPICO spectroscopy at the Vacuum Ultraviolet (VUV) beamline of the SLS. This combines two different analytical techniques: photoelectron spectroscopy and mass spectrometry – something that is only possible at a few synchrotron facilities worldwide. “This give us a unique spectroscopic fingerprint of the reaction intermediates and products, so we can really work out what’s going on in a reaction,” explains András Bödi, leader of the Reaction Dynamics Group at PSI.

The team saw that ortho-benzyne and methyl radicals, another common constituent of molecular clouds, readily combine to form larger and more complex organic compounds. They then drew on computer models to explore the role of ortho-benzyne in a stellar nursery spread out over several light-years deep in space. The results were promising: The models generated clouds of gas containing roughly the same mix of organic molecules that astronomers had observed in TMC-1 using telescopes. Ortho-benzyne, in other words, seems to be a prime candidate for driving the gas-phase organic chemistry that occurs within these stellar nurseries, Bouwman said.

He added that scientists still have a lot of work to do to fully understand all of the reactions happening in TMC-1. He wants to examine, for example, how organic molecules in space also pick up nitrogen atoms—key components of the DNA and amino acids of living organisms on Earth. “Our findings may just change the view on what ingredients we have in the first place to form new stars and new planets,” Bouwman said.

Co-authors on the new paper include researchers at Leiden University in the Netherlands, Benedictine College in the U.S., the University of Würzburg in Germany and Paul Scherrer Institute in Switzerland.

Text: Based on a press release by Univerity of Colarado Boulder / Daniel Strain with additions by Paul Scherrer Institute / Miriam Arrell

Further information

Reaction insights help make sustainable liquid fuels | Labs & User Services | Paul Scherrer Institut (PSI)


Dr. András Bödi
Group Leader Reaction Dynamics
Paul Scherrer Institute, Forschungsstrasse 111, 5232 Villigen PSI, Switzerland

Telephone: +41 56 310 44 71, e-mail: andras.boedi@psi.ch

Original Publication

Five-membered ring compounds from the ortho-benzyne + methyl radical reaction under interstellar conditions
Jordy Bouwman, Morgan N. McCabe, Christopher N. Shingledecker, Joseph Wandishin, Virginia Jarvis, Engelbert Reusch, Patrick Hemberger & Andras Bodi

Nature Astronomy, 6. February 2023
DOI: 10.1038/ s41550-023-01893-2


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