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Delving into Fe-content effects on surface reconstruction of Ba0.50Sr0.50Co1−xFexO3−δ for the oxygen evolution reaction
Journal of Materials Chemistry A. 2024; 12(9): 5156-5169. https://doi.org/10.1039/d3ta06156f
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Bhattacharya S
Atomic level insight into irradiation effects in nuclear fuel materials
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Borca CN, Huthwelker T, Filella M
A step towards understanding plastic complexity: antimony speciation in consumer plastics and synthetic textiles revealed by XAS
Journal of Environmental Sciences. 2024. https://doi.org/10.1016/j.jes.2024.02.006
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X-Ray Absorption Spectroscopy to investigate precipitated oxides in Nb3Sn wires with an internal oxygen source
IEEE Transactions on Applied Superconductivity. 2024; 34(3): 6000205 (5 pp.). https://doi.org/10.1109/TASC.2024.3354232
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Buema G, Minuti AE, Borhan AI, Borca CN, Dirtu D, Dirtu AC, et al.
Unmodified Mg/Al layered double hydroxide clay with versatile and specific adsorption capacity over high spectrum type of harmful contaminants
Materials Chemistry and Physics. 2024; 326: 129835 (11 pp.). https://doi.org/10.1016/j.matchemphys.2024.129835
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Non-destructive and non-invasive approaches for the identification of hydroxy lead–calcium phosphate solid solutions ((Pb x Ca1−x)5(PO4)3OH) in cultural heritage materials
Applied Spectroscopy. 2024. https://doi.org/10.1177/00037028241243375
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Hydrogen evolution with hot electrons on a plasmonic-molecular catalyst hybrid system
Nature Communications. 2024; 15(1): 445 (12 pp.). https://doi.org/10.1038/s41467-024-44752-y
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Furcas FE, Mundra S, Lothenbach B, Borca CN, Huthwelker T, Angst UM
The influence of silicon on the formation and transformation of corrosion products
Cement and Concrete Research. 2024; 182: 107554 (11 pp.). https://doi.org/10.1016/j.cemconres.2024.107554
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Huang J, Hales N, Clark AH, Yüzbasi NS, Borca CN, Huthwelker T, et al.
Operando tracking the interactions between CoOx and CeO2 during oxygen evolution reaction
Advanced Energy Materials. 2024; 14(11): 2303529 (10 pp.). https://doi.org/10.1002/aenm.202303529
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Huang J, Clark AH, Hales N, Borca CN, Huthwelker T, Skoupy R, et al.
Spectroscopic investigations of complex electronic interactions by elemental doping and material compositing of cobalt oxide for enhanced oxygen evolution reaction activity
Advanced Functional Materials. 2024; 34(44): 2405384 (9 pp.). https://doi.org/10.1002/adfm.202405384
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Huang J, Borca CN, Huthwelker T, Yüzbasi NS, Baster D, El Kazzi M, et al.
Surface oxidation/spin state determines oxygen evolution reaction activity of cobalt-based catalysts in acidic environment
Nature Communications. 2024; 15(1): 3067 (9 pp.). https://doi.org/10.1038/s41467-024-47409-y
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Kleinsasser JM, Konecke BA, Simon AC, Northrup P, Lanzirotti A, Newville M, et al.
Sulfur speciation in dacitic melts using X-ray absorption near-edge structure spectroscopy of the S K-edge (S-XANES): Consideration of radiation-induced changes and the implications for sulfur in natural arc systems
American Mineralogist. 2024; 109(8): 1359-1374. https://doi.org/10.2138/am-2022-8833
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Kubeneck LJ, Notini L, Rothwell KA, Fantappiè G, Huthwelker T, ThomasArrigo LK, et al.
Transformation of vivianite in intertidal sediments with contrasting sulfide conditions
Geochimica et Cosmochimica Acta. 2024; 370: 173-187. https://doi.org/10.1016/j.gca.2024.01.020
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Moragues T, Giannakakis G, Ruiz-Ferrando A, Borca CN, Huthwelker T, Bugaev A, et al.
Droplet‐based microfluidics reveals insights into cross‑coupling mechanisms over single‑atom heterogeneous catalysts
Angewandte Chemie International Edition. 2024; 63(20): e202401056 (6 pp.). https://doi.org/10.1002/anie.202401056
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Radu I, Borhan AI, Ghercă D, Popescu DG, Borca CN, Huthwelker T, et al.
Enhancement of SrTiO3 photocatalytic efficiency by Al doping: answers from the structure, morphology and electronic properties contributions
Ceramics International. 2024; 50(11): 20664-20675. https://doi.org/10.1016/j.ceramint.2024.03.188
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Rzepka P, Signorile M, Huthwelker T, Checchia S, Rosso F, Bordiga S, et al.
Quantitative localisation of titanium in the framework of titanium silicalite-1 using anomalous X-ray powder diffraction
Nature Communications. 2024; 15(1): 7757. https://doi.org/10.1038/s41467-024-51788-7
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Vo PHN, Vogel C, Nguyen HTM, Hamilton BR, Thai PK, Roesch P, et al.
µ-X-ray fluorescence (XRF) and fluorine K-edge µ-X-ray absorption near-edge structure (XANES) spectroscopy for detection of PFAS distribution in the impacted concrete
Journal of Hazardous Materials Letters. 2024; 5: 100134 (5 pp.). https://doi.org/10.1016/j.hazl.2024.100134
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Wu YH, Janák M, Abdala PM, Borca CN, Wach A, Kierzkowska A, et al.
Probing surface transformations of lanthanum nickelate electrocatalysts during oxygen evolution reaction
Journal of the American Chemical Society. 2024; 146(17): 11887-11896. https://doi.org/10.1021/jacs.4c00863
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Adams P, Creazzo F, Moehl T, Crockett R, Zeng P, Novotny Z, et al.
Solution phase treatments of Sb2Se3 heterojunction photocathodes for improved water splitting performance
Journal of Materials Chemistry A. 2023; 11(15): 8277-8284. https://doi.org/10.1039/d3ta00554b
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Co1-xFexOy oxygen evolution nanocatalysts: on the way to resolve (electro)chemically triggered surface-bulk discrepancy
ACS Catalysis. 2023; 13: 15899-15909. https://doi.org/10.1021/acscatal.3c04138
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Chimia. 2023; 77(10): 694-696. https://doi.org/10.2533/chimia.2023.694
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Borhan AI, Ghemes AI, Husanu M-A, Popescu D-G, Borca CN, Huthwelker T, et al.
Carbon-based heterostructure from multi-photo-active nanobuilding blocks SrTiO3@NiFe2O4@Fe0@Ni0@CNTs with derived nanoreaction metallic clusters for enhanced solar light-driven photodegradation of harmful antibiotics
Applied Surface Science. 2023; 622: 156987 (17 pp.). https://doi.org/10.1016/j.apsusc.2023.156987
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Borhan A-I, Herea D-D, Husanu M-A, Georgeta Popescu D, Borca CN, Huthwelker T, et al.
Straightforward FeOOH nanografting of Al-based SrTiO3 perovskite material as core-shell nanoflower-like heteronanostructure with enhanced solar light-driven photodegradation capability
Applied Surface Science. 2023; 614: 156247 (12 pp.). https://doi.org/10.1016/j.apsusc.2022.156247
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Brandalise Nunes F, Comini N, Diulus JT, Huthwelker T, Iannuzzi M, Osterwalder J, et al.
Dynamic equilibrium at the HCOOH-saturated TiO2(110)-water interface
Journal of Physical Chemistry Letters. 2023; 14(13): 3132-3138. https://doi.org/10.1021/acs.jpclett.2c03788
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Brovchenko V, Merkulova M, Sittner J, Shilovskih V, Borca C, Huthwelker T, et al.
X-ray absorption spectroscopic study of Pd2+ on Ni site in pentlandite
American Mineralogist. 2023; 108(11): 2086-2095. https://doi.org/10.2138/am-2022-8704
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Diklić N, Clark AH, Herranz J, Aegerter D, Diercks JS, Beard A, et al.
Surface Ir+5 formation as a universal prerequisite for O2 evolution on Ir oxides
ACS Catalysis. 2023; 13(16): 11069-11079. https://doi.org/10.1021/acscatal.3c01448
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Furcas FE, Lothenbach B, Mundra S, Borca CN, Albert CC, Isgor OB, et al.
Transformation of 2-line ferrihydrite to goethite at alkaline pH
Environmental Science and Technology. 2023; 57(42): 16097-16108. https://doi.org/10.1021/acs.est.3c05260
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Jay RM, Banerjee A, Leitner T, Wang R-P, Harich J, Stefanuik R, et al.
Tracking C-H activation with orbital resolution
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Self-organization of 1-propanol at H-ZSM-5 Brønsted acid sites
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Machado Ferreira de Araujo F, Duarte-Ruiz D, Saßnick HD, Gentzmann MC, Huthwelker T, Cocchi C
Electronic structure and core spectroscopy of scandium fluoride polymorphs
Inorganic Chemistry. 2023; 62(10): 4238-4247. https://doi.org/10.1021/acs.inorgchem.2c04357
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Morasso C, Vanna R, Piccotti F, Frizzi L, Truffi M, Albasini S, et al.
Whitlockite has a characteristic distribution in mammary microcalcifications and it is not associated with breast cancer
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Rekhtina M, Bugaev A, Dunstan MT, Dal Pozzo A, Nadjafi M, Borca C, et al.
Probing the local structure of Na in NaNO3-promoted, MgO-based CO2 sorbents via X-ray absorption spectroscopy
Chemistry of Materials. 2023; 35(23): 10060-10069. https://doi.org/10.1021/acs.chemmater.3c02077
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Roesch P, Vogel C, Wittwer P, Huthwelker T, Borca CN, Sommerfeld T, et al.
Taking a look at the surface: μ-XRF mapping and fluorine K-edge μ-XANES spectroscopy of organofluorinated compounds in environmental samples and consumer products
Environmental Science: Processes and Impacts. 2023; 25(7): 1213-1223. https://doi.org/10.1039/d3em00107e
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Tao L, Khramenkova E, Lee I, Ikuno T, Khare R, Jentys A, et al.
Speciation and reactivity control of Cu-Oxo clusters via extraframework Al in mordenite for methane oxidation
Journal of the American Chemical Society. 2023; 145(32): 17710-17719. https://doi.org/10.1021/jacs.3c04328
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Vogel C, Roesch P, Wittwer P, Piechotta C, Lisec J, Sommerfeld T, et al.
Levels of per- and polyfluoroalkyl substances (PFAS) in various wastewater-derived fertilizers - analytical investigations from different perspectives
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Direct evidence of cobalt oxyhydroxide formation on a La0.2Sr0.8CoO3 perovskite water splitting catalyst
Journal of Materials Chemistry A. 2022; 10(5): 2434-2444. https://doi.org/10.1039/D1TA04957G
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Brenker J, Henzler K, Borca CN, Huthwelker T, Alan T
X-ray compatible microfluidics for in situ studies of chemical state, transport and reaction of light elements in an aqueous environment using synchrotron radiation
Lab on a Chip. 2022; 22(6): 1214-1230. https://doi.org/10.1039/d1lc00996f
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Highly selective Suzuki reaction catalysed by a molecular Pd-P-MOF catalyst under mild conditions: role of ligands and palladium speciation
Catalysis Science and Technology. 2022; 12(3): 954-961. https://doi.org/10.1039/D1CY01351C
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Fantin A, Cakir CT, Kasatikov S, Schumacher G, Manzoni AM
Effects of heat treatment on microstructure, hardness and local structure in a compositionally complex alloy
Materials Chemistry and Physics. 2022; 276: 125432 (6 pp.). https://doi.org/10.1016/j.matchemphys.2021.125432
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Geng G, Shi Z, Lothenbach B, Leemann A, Wieland E, Dähn R
A micro-XAS and XRD study of the crystalline alkali-silica reaction products
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Jay RM, Banerjee A, Leitner T, Stefanuik R, Wang R-P, Harich J, et al.
From femtosecond excited-state and dissociation dynamics to nanosecond reaction kinetics: following C-H bond activation with X-rays
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Keyes S, van Veelen A, McKay Fletcher D, Scotson C, Koebernick N, Petroselli C, et al.
Multimodal correlative imaging and modelling of phosphorus uptake from soil by hyphae of mycorrhizal fungi
New Phytologist. 2022; 234(2): 688-703. https://doi.org/10.1111/nph.17980
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Kulka A, Hanc A, Walczak K, Płotek J, Sun J, Lu L, et al.
Direct evidence of an unanticipated crystalline phase responsible for the high performance of few-layered-MoS2 anodes for Na-ion batteries
Energy Storage Materials. 2022; 48: 314-324. https://doi.org/10.1016/j.ensm.2022.03.031
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Li J, Zhang W, Sanz-Camacho P, Duttine M, Gardner D, Carraro C, et al.
The nanomechanical properties of non-crosslinked calcium aluminosilicate hydrate: the influences of tetrahedral Al and curing age
Cement and Concrete Research. 2022; 159: 106900 (8 pp.). https://doi.org/10.1016/j.cemconres.2022.106900
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Rashid MH, Borca CN, Xto JM, Huthwelker T
X-Ray absorption spectroscopy on airborne aerosols
Environmental Science: Atmospheres. 2022; 2(6): 1338-1350. https://doi.org/10.1039/d2ea00016d
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Roesch P, Vogel C, Huthwelker T, Wittwer P, Simon F-G
Investigation of per- and polyfluoroalkyl substances (PFAS) in soils and sewage sludges by fluorine K-edge XANES spectroscopy and combustion ion chromatography
Environmental Science and Pollution Research. 2022; 29: 26889-26899. https://doi.org/10.1007/s11356-021-17838-z
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Tuyishime JRM, Adediran GA, Olsson BA, Sahlén Zetterberg T, Högbom L, Spohn M, et al.
Phosphorus speciation in the organic layer of two Swedish forest soils 13-24 years after wood ash and nitrogen application
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Yüzbasi NS, Armutlulu A, Huthwelker T, Abdala PM, Müller CR
Na-β-Al2O3 stabilized Fe2O3 oxygen carriers for chemical looping water splitting: correlating structure with redox stability
Journal of Materials Chemistry A. 2022; 10(19): 10692-10700. https://doi.org/10.1039/d1ta10507h
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Bartels-Rausch T, Kong X, Orlando F, Artiglia L, Waldner A, Huthwelker T, et al.
Interfacial supercooling and the precipitation of hydrohalite in frozen NaCl solutions as seen by X-ray absorption spectroscopy
Cryosphere. 2021; 15(4): 2001-2020. https://doi.org/10.5194/tc-15-2001-2021
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Comini N’, Huthwelker T, Diulus JT, Osterwalder J, Novotny Z
Factors influencing surface carbon contamination in ambient-pressure x-ray photoelectron spectroscopy experiments
Journal of Vacuum Science and Technology A: Vacuum, Surfaces, and Films. 2021; 39(4): 043203 (9 pp.). https://doi.org/10.1116/6.0001013
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Fichtner V, Lange SM, Krause S, Huthwelker T, Borca CN, Schurr SL, et al.
Microbial activity affects sulphur in biogenic aragonite
Depositional Record. 2021; 7(3): 500-519. https://doi.org/10.1002/dep2.133
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Gentzmann MC, Schraut K, Vogel C, Gäbler H-E, Huthwelker T, Adam C
Investigation of scandium in bauxite residues of different origin
Applied Geochemistry. 2021; 126: 104898 (18 pp.). https://doi.org/10.1016/j.apgeochem.2021.104898
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Höltschi L, Borca CN, Huthwelker T, Marone F, Schlepütz CM, Pelé V, et al.
Performance-limiting factors of graphite in sulfide-based all-solid-state lithium-ion batteries
Electrochimica Acta. 2021; 389: 138735 (10 pp.). https://doi.org/10.1016/j.electacta.2021.138735
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Lee I, Lee M-S, Tao L, Ikuno T, Khare R, Jentys A, et al.
Activity of Cu-Al-oxo extra-framework clusters for selective methane oxidation on Cu-exchanged zeolites
JACS Au. 2021; 1(9): 1412-1421. https://doi.org/10.1021/jacsau.1c00196
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Man GJ, Sterling CM, Kamal C, Simonov KA, Svanström S, Acharya J, et al.
Electronic coupling between the unoccupied states of the organic and inorganic sublattices of methylammonium lead iodide: a hybrid organic-inorganic perovskite single crystal
Physical Review B. 2021; 104(4): L041302 (6 pp.). https://doi.org/10.1103/PhysRevB.104.L041302
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Pinar AB, Rzepka P, Knorpp AJ, McCusker LB, Baerlocher C, Huthwelker T, et al.
Pinpointing and quantifying the aluminum distribution in zeolite catalysts using anomalous scattering at the Al absorption edge
Journal of the American Chemical Society. 2021; 143(43): 17926-17930. https://doi.org/10.1021/jacs.1c06925
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Probst J, Borca CN, Newton MA, van Bokhoven J, Huthwelker T, Stavrakis S, et al.
In situ X-ray absorption spectroscopy and droplet-based microfluidics: an analysis of calcium carbonate precipitation
ACS Measurement Science Au. 2021; 1(1): 27-34. https://doi.org/10.1021/acsmeasuresciau.1c00005
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Späth A, Meyer M, Huthwelker T, Borca CN, Meßlinger K, Bieber M, et al.
X-ray microscopy reveals the outstanding craftsmanship of Siberian Iron Age textile dyers
Scientific Reports. 2021; 11: 5141 (7 pp.). https://doi.org/10.1038/s41598-021-84747-z
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Sterling CM, Kamal C, Man GJ, Nayak PK, Simonov KA, Svanström S, et al.
Sensitivity of Nitrogen K-edge X-ray absorption to halide substitution and thermal fluctuations in methylammonium lead-halide perovskites
Journal of Physical Chemistry C. 2021; 125(15): 8360-8368. https://doi.org/10.1021/acs.jpcc.1c02017
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Su CK, Chen SY, Chung JH, Li GC, Brandmair B, Huthwelker T, et al.
Materials engineering of violin soundboards by Stradivari and Guarneri
Angewandte Chemie International Edition. 2021; 60(35): 19144-19154. https://doi.org/10.1002/anie.202105252
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Bowker M, Hellier P, Decarolis D, Gianolio D, Mohammed KMH, Stenner A, et al.
Al-doped Fe2O3as a support for molybdenum oxide methanol oxidation catalysts
Physical Chemistry Chemical Physics. 2020; 22(34): 18911-18918. https://doi.org/10.1039/d0cp01192d
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Du H, Courrégelongue C, Xto J, Böhlen A, Steinacher M, Borca CN, et al.
Additives: their influence on the humidity- and pressure-induced crystallization of amorphous CaCO3
Chemistry of Materials. 2020; 32(10): 4282-4291. https://doi.org/10.1021/acs.chemmater.0c00975
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Duignan TT, Schenter GK, Fulton JL, Huthwelker T, Balasubramanian M, Galib M, et al.
Quantifying the hydration structure of sodium and potassium ions: taking additional steps on Jacob's Ladder
Physical Chemistry Chemical Physics. 2020; 22(19): 10641-10652. https://doi.org/10.1039/C9CP06161D
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Fantin A, Lepore GO, Manzoni AM, Kasatikov S, Scherb T, Huthwelker T, et al.
Short-range chemical order and local lattice distortion in a compositionally complex alloy
Acta Materialia. 2020; 193: 329-337. https://doi.org/10.1016/j.actamat.2020.04.034
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Geng G, Shi Z, Leemann A, Borca C, Huthwelker T, Glazyrin K, et al.
Atomistic structure of alkali-silica reaction products refined from X-ray diffraction and micro X-ray absorption data
Cement and Concrete Research. 2020; 129: 105958 (11 pp.). https://doi.org/10.1016/j.cemconres.2019.105958
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Höltschi L, Jud F, Borca C, Huthwelker T, Villevieille C, Pelé V, et al.
Study of graphite cycling in sulfide solid electrolytes
Journal of the Electrochemical Society. 2020; 167(11): 110558 (10 pp.). https://doi.org/10.1149/1945-7111/aba36f
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Kulka A, Marino C, Walczak K, Borca C, Bolli C, Novák P, et al.
Influence of Na/Mn arrangements and P2/P'2 phase ratio on the electrochemical performance of NaxMnO2 cathodes for sodium-ion batteries
Journal of Materials Chemistry A. 2020; 8(12): 6022-6033. https://doi.org/10.1039/C9TA12176E
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Kurlov A, Kierzkowska AM, Huthwelker T, Abdala PM, Müller CR
Na2CO3-modified CaO-based CO2 sorbents: the effects of structure and morphology on CO2 uptake
Physical Chemistry Chemical Physics. 2020; 22(42): 24697-24703. https://doi.org/10.1039/d0cp04410e
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Menzi S, Knopp G, Al Haddad A, Augustin S, Borca C, Gashi D, et al.
Generation and simple characterization of flat, liquid jets
Review of Scientific Instruments. 2020; 91(10): 105109 (10 pp.). https://doi.org/10.1063/5.0007228
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Novotny Z, Aegerter D, Comini N, Tobler B, Artiglia L, Maier U, et al.
Probing the solid-liquid interface with tender x rays: a new ambient-pressure x-ray photoelectron spectroscopy endstation at the Swiss Light Source
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Redel K, Kulka A, Walczak K, Plewa A, Borca CN, Molenda J
The impact of oxygen evolution and cation migration on the cycling stability of a Li-rich Li[Li0.2Mn0.6Ni0.1Co0.1]O2 positive electrode
Journal of Materials Chemistry A. 2020; 8(35): 18143-18153. https://doi.org/10.1039/D0TA05556E
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Vespa M, Borca C, Huthwelker T, Lothenbach B, Dähn R, Wieland E
Structural characterisation of magnesium (sodium) aluminium silicate hydrate (M-(N)-A-S-H) phases by X-ray absorption near-edge spectroscopy
Applied Geochemistry. 2020; 123: 104750 (8 pp.). https://doi.org/10.1016/j.apgeochem.2020.104750
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Vogel C, Sekine R, Huang J, Steckenmesser D, Steffens D, Huthwelker T, et al.
Effects of a nitrification inhibitor on nitrogen species in the soil and the yield and phosphorus uptake of maize
Science of the Total Environment. 2020; 715: 136895 (8 pp.). https://doi.org/10.1016/j.scitotenv.2020.136895
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van Veelen A, Koebernick N, Scotson CS, McKay‐Fletcher D, Huthwelker T, Borca CN, et al.
Root induced soil deformation influences Fe, S and P: rhizosphere chemistry investigated using synchrotron XRF and XAS
New Phytologist. 2020; 225: 1476-1490. https://doi.org/10.1111/nph.16242
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Andrä M, Zhang J, Bergamaschi A, Barten R, Borca C, Borghi G, et al.
Development of low-energy X-ray detectors using LGAD sensors
Journal of Synchrotron Radiation. 2019; 26: 1226-1237. https://doi.org/10.1107/S1600577519005393
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Curti E, Xto J, Borca CN, Henzler K, Huthwelker T, Prasianakis NI
Modelling Ra-bearing baryte nucleation/precipitation kinetics at the pore scale: application to radioactive waste disposal
European Journal of Mineralogy. 2019; 31(2): 247-262. https://doi.org/10.1127/ejm/2019/0031-2818
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Li T, Roy K, Krumeich F, Artiglia L, Huthwelker T, van Bokhoven JA
Variation of aluminum distribution in small‐sized ZSM‐5 crystals during desilication
Chemistry: A European Journal. 2019; 25(69): 15879-15886. https://doi.org/10.1002/chem.201903852
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Plakhova TV, Romanchuk AY, Butorin SM, Konyukhova AD, Egorov AV, Shiryaev AA, et al.
Towards the surface hydroxyl species in CeO2 nanoparticles
Nanoscale. 2019; 11(39): 18142-18149. https://doi.org/10.1039/C9NR06032D
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Sava F, Borca CN, Galca AC, Socol G, Grolimund D, Mihai C, et al.
Structural characterisation and thermal stability of SnSe\GaSb stacked films
Philosophical Magazine. 2019; 99(1): 55-72. https://doi.org/10.1080/14786435.2018.1529442
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Steiger P, Burnat D, Madi H, Mai A, Holzer L, Van Herle J, et al.
Sulfur poisoning recovery on a solid oxide fuel cell anode material through reversible segregation of nickel
Chemistry of Materials. 2019; 31(3): 748-758. https://doi.org/10.1021/acs.chemmater.8b03669
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Strand Ferrer J, Sandu ICA, Syversen T, Cardoso AM, Candeias A, Borca C
Investigating colour changes in red and blue paints - a preliminary study of art materials and techniques in Edvard Munch's Old Man in Warnemünde (1907)
In: van den Berg KJ, Bonaduce I, Burnstock A, Ormsby B, Scharff M, Carlyle L, et al., eds. Conservation of modern oil paintings. Cham: Springer; 2019:209-218. https://doi.org/10.1007/978-3-030-19254-9_15
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Xto JM, Borca CN, van Bokhoven JA, Huthwelker T
Aerosol-based synthesis of pure and stable amorphous calcium carbonate
Chemical Communications. 2019; 55(72): 10725-10728. https://doi.org/10.1039/C9CC03749G
DORA PSI -
Xto J, Wetter R, Borca CN, Frieh C, van Bokhoven JA, Huthwelker T
Droplet-based in situ X-ray absorption spectroscopy cell for studying crystallization processes at the tender X-ray energy range
RSC Advances. 2019; 9(58): 34004-34010. https://doi.org/10.1039/C9RA06084G
DORA PSI -
Xto JM, Du H, Borca CN, Amstad E, van Bokhoven JA, Huthwelker T
Tuning the incorporation of magnesium into calcite during its crystallization from additive-free aqueous solution
Crystal Growth and Design. 2019; 19(8): 4385-4394. https://doi.org/10.1021/acs.cgd.9b00179
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Bergamaschi A, Andrä M, Barten R, Borca C, Brückner M, Chiriotti S, et al.
The MÖNCH detector for soft X-ray, high-resolution, and energy resolved applications
Synchrotron Radiation News. 2018; 31(6): 11-15. https://doi.org/10.1080/08940886.2018.1528428
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Du H, Steinacher M, Borca C, Huthwelker T, Murello A, Stellacci F, et al.
Amorphous CaCO3: influence of the formation time on its degree of hydration and stability
Journal of the American Chemical Society. 2018; 140(43): 14289-14299. https://doi.org/10.1021/jacs.8b08298
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Fichtner V, Strauss H, Mavromatis V, Dietzel M, Huthwelker T, Borca CN, et al.
Incorporation and subsequent diagenetic alteration of sulfur in Arctica islandica
Chemical Geology. 2018; 482: 72-90. https://doi.org/10.1016/j.chemgeo.2018.01.035
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Henzler K, Fetisov EO, Galib M, Baer MD, Legg BA, Borca C, et al.
Supersaturated calcium carbonate solutions are classical
Science Advances. 2018; 4(1): eaao6283 (11 pp.). https://doi.org/10.1126/sciadv.aao6283
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Hiller D, Göttlicher J, Steininger R, Huthwelker T, Julin J, Munnik F, et al.
Structural properties of Al-O monolayers in SiO2 on silicon and the maximization of their negative fixed charge density
ACS Applied Materials and Interfaces. 2018; 10(36): 30495-30505. https://doi.org/10.1021/acsami.8b06098
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Lange SM, Krause S, Ritter A-C, Fichtner V, Immenhauser A, Strauss H, et al.
Anaerobic microbial activity affects earliest diagenetic pathways of bivalve shells
Sedimentology. 2018; 65(4): 1390-1411. https://doi.org/10.1111/sed.12428
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Meyer M, Huthwelker T, Borca CN, Meßlinger K, Bieber M, Fink RH, et al.
In-situ spectroscopic analysis of the traditional dyeing pigment Turkey red inside textile matrix
Journal of Instrumentation. 2018; 13(3): C03007 (6 pp.). https://doi.org/10.1088/1748-0221/13/03/C03007
DORA PSI -
Rehanek J, Milne CJ, Szlachetko J, Czapla-Masztafiak J, Schneider J, Huthwelker T, et al.
A compact and versatile tender X-ray single-shot spectrometer for online XFEL diagnostics
Journal of Synchrotron Radiation. 2018; 25(1): 16-19. https://doi.org/10.1107/S1600577517012796
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Schmidt S, Sallard S, Borca C, Huthwelker T, Novák P, Villevieille C
Phosphorus anionic redox activity revealed by operando P K-edge X-ray absorption spectroscopy on diphosphonate-based conversion materials in Li-ion batteries
Chemical Communications. 2018; 54(39): 4939-4942. https://doi.org/10.1039/c8cc01350k
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Vespa M, Lothenbach B, Dähn R, Huthwelker T, Wieland E
Characterisation of magnesium silicate hydrate phases (M-S-H): a combined approach using synchrotron-based absorption-spectroscopy and ab initio calculations
Cement and Concrete Research. 2018; 109: 175-183. https://doi.org/10.1016/j.cemconres.2018.03.011
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Waldner A, Artiglia L, Kong X, Orlando F, Huthwelker T, Ammann M, et al.
Pre-melting and the adsorption of formic acid at the air-ice interface at 253 K as seen by NEXAFS and XPS
Physical Chemistry Chemical Physics. 2018; 20(37): 24408-24417. https://doi.org/10.1039/C8CP03621G
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Artiglia L, Orlando F, Roy K, Kopelent R, Safonova O, Nachtegaal M, et al.
Introducing time resolution to detect Ce3+ catalytically active sites at the Pt/CeO2 interface through ambient pressure X-ray photoelectron spectroscopy
Journal of Physical Chemistry Letters. 2017; 8(1): 102-108. https://doi.org/10.1021/acs.jpclett.6b02314
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Bohinc R, Hoszowska J, Dousse J-C, Błachucki W, Zeeshan F, Kayser Y, et al.
Distribution of aluminum over different T-sites in ferrierite zeolites studied with aluminum valence to core X-ray emission spectroscopy
Physical Chemistry Chemical Physics. 2017; 19(43): 29271-29277. https://doi.org/10.1039/c7cp05001a
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Budarz J, Santomauro FG, Rittmann-Frank MH, Milne CJ, Huthwelker T, Grolimund D, et al.
Time-resolved element-selective probing of charge carriers in solar materials
Chimia. 2017; 71(11): 768-772. https://doi.org/10.2533/chimia.2017.768
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Galib M, Baer MD, Skinner LB, Mundy CJ, Huthwelker T, Schenter GK, et al.
Revisiting the hydration structure of aqueous Na+
Journal of Chemical Physics. 2017; 146(8): 84504. https://doi.org/10.1063/1.4975608
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Ihli J, Ferreira Sanchez D, Jacob RR, Cuartero V, Mathon O, Krumeich F, et al.
Localization and speciation of iron impurities within a fluid catalytic cracking catalyst
Angewandte Chemie International Edition. 2017; 56(45): 14031-14035. https://doi.org/10.1002/anie.201707154
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Kong X, Waldner A, Orlando F, Artiglia L, Huthwelker T, Ammann M, et al.
Coexistence of physisorbed and solvated HCl at warm ice surfaces
Journal of Physical Chemistry Letters. 2017; 8(19): 4757-4762. https://doi.org/10.1021/acs.jpclett.7b01573
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Merkulova MV, Muñoz M, Brunet F, Vidal O, Hattori K, Vantelon D, et al.
Experimental insight into redox transfer by iron- and sulfur-bearing serpentinite dehydration in subduction zones
Earth and Planetary Sciences Letters. 2017; 479: 133-143. https://doi.org/10.1016/j.epsl.2017.09.009
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Meyer M, Borca CN, Huthwelker T, Bieber M, Meßlinger K, Fink RH, et al.
μ-XRF studies on the colour brilliance in ancient wool carpets
Scanning. 2017; 2017: 6346212 (7 pp.). https://doi.org/10.1155/2017/6346212
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Mostrou S, Büchel R, Pratsinis SE, van Bokhoven JA
Improving the ceria-mediated water and carbon dioxide splitting through the addition of chromium
Applied Catalysis A: General. 2017; 537: 40-49. https://doi.org/10.1016/j.apcata.2017.03.001
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Olivieri G, Giorgi JB, Green RG, Brown MA
5 years of ambient pressure photoelectron spectroscopy (APPES) at the Swiss Light Source (SLS)
Journal of Electron Spectroscopy and Related Phenomena. 2017; 216: 1-16. https://doi.org/10.1016/j.elspec.2017.01.003
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Ramilli M, Bergamaschi A, Andrae M, Brückner M, Cartier S, Dinapoli R, et al.
Measurements with MÖNCH, a 25 μm pixel pitch hybrid pixel detector
Journal of Instrumentation. 2017; 12(1): C01071 (8 pp.). https://doi.org/10.1088/1748-0221/12/01/C01071
DORA PSI -
Vespa M, Dähn R, Huthwelker T, Wieland E
Soft X-ray absorption near-edge investigations of Mg-containing mineral phases relevant for cementitious materials
Physics and Chemistry of the Earth. 2017; 99: 168-174. https://doi.org/10.1016/j.pce.2017.03.006
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Vjunov A, Wang M, Govind N, Huthwelker T, Shi H, Mei D, et al.
Tracking the chemical transformations at the Brønsted acid site upon water-induced deprotonation in a zeolite pore
Chemistry of Materials. 2017; 29(21): 9030-9042. https://doi.org/10.1021/acs.chemmater.7b02133
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Cato E, Borca C, Huthwelker T, Ferreira ESB
Aluminium X-ray absorption near-edge spectroscopy analysis of discoloured ultramarine blue in 20th century oil paintings
Microchemical Journal. 2016; 126: 18-24. https://doi.org/10.1016/j.microc.2015.11.021
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Czapla-Masztafiak J, Szlachetko J, Milne CJ, Lipiec E, Sá J, Penfold TJ, et al.
Investigating DNA radiation damage using X-ray absorption spectroscopy
Biophysical Journal. 2016; 110(6): 1304-1311. https://doi.org/10.1016/j.bpj.2016.01.031
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Czapla-Masztafiak J, Okoń K, Gałka M, Huthwelker T, Kwiatek WM
Investigating the distribution of chemical forms of sulfur in prostate cancer tissue using X-ray absorption spectroscopy
Applied Spectroscopy. 2016; 70(2): 264-271. https://doi.org/10.1177/0003702815620128
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Jungmann-Smith JH, Bergamaschi A, Brückner M, Cartier S, Dinapoli R, Greiffenberg D, et al.
Towards hybrid pixel detectors for energy-dispersive or soft X-ray photon science
Journal of Synchrotron Radiation. 2016; 23(2): 385-394. https://doi.org/10.1107/S1600577515023541
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Orlando F, Waldner A, Bartels-Rausch T, Birrer M, Kato S, Lee M-T, et al.
The environmental photochemistry of oxide surfaces and the nature of frozen salt solutions: a new in situ XPS approach
Topics in Catalysis. 2016; 59(5-7): 591-604. https://doi.org/10.1007/s11244-015-0515-5
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Donnelly C, Guizar-Sicairos M, Scagnoli V, Holler M, Huthwelker T, Menzel A, et al.
Element-specific X-ray phase tomography of 3D structures at the nanoscale
Physical Review Letters. 2015; 114(11): 115501 (5 pp.). https://doi.org/10.1103/PhysRevLett.114.115501
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Fulton JL, Govind N, Huthwelker T, Bylaska EJ, Vjunov A, Pin S, et al.
Electronic and chemical state of aluminum from the single- (K) and double-electron excitation (KLII&III, KLI) X-ray absorption near-edge spectra of α-alumina, sodium aluminate, aqueous Al3+·(H2O)6, and aqueous Al(OH)4-
Journal of Physical Chemistry B. 2015; 119(26): 8380-8388. https://doi.org/10.1021/jp511602n
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Gorlin Y, Siebel A, Piana M, Huthwelker T, Jha H, Monsch G, et al.
Operando characterization of intermediates produced in a lithium-sulfur battery
Journal of the Electrochemical Society. 2015; 162(7): A1146-A1155. https://doi.org/10.1149/2.0081507jes
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Guerra M, Sampaio JM, Madeira TI, Parente F, Indelicato P, Marques JP, et al.
Theoretical and experimental determination of L -shell decay rates, line widths, and fluorescence yields in Ge
Physical Review A. 2015; 92(2): 22507 (9 pp.). https://doi.org/10.1103/PhysRevA.92.022507
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Kato S, Ammann M, Huthwelker T, Paun C, Lampimaeki M, Lee M-T, et al.
Quantitative depth profiling of Ce3+ in Pt/CeO2 by in situ high-energy XPS in a hydrogen atmosphere
Physical Chemistry Chemical Physics. 2015; 17(7): 5078-5083. https://doi.org/10.1039/c4cp05643d
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Morel FL, Pin S, Huthwelker T, Ranocchiari M, van Bokhoven JA
Phosphine and phosphine oxide groups in metal-organic frameworks detected by P K-edge XAS
Physical Chemistry Chemical Physics. 2015; 17(5): 3326-3331. https://doi.org/10.1039/c4cp05151c
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Vjunov A, Fulton JL, Camaioni DM, Hu JZ, Burton SD, Arslan I, et al.
Impact of aqueous medium on zeolite framework integrity
Chemistry of Materials. 2015; 27(9): 3533-3545. https://doi.org/10.1021/acs.chemmater.5b01238
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Alessi DS, Lezama-Pacheco JS, Stubbs JE, Janousch M, Bargar JR, Persson P, et al.
The product of microbial uranium reduction includes multiple species with U(IV)-phosphate coordination
Geochimica et Cosmochimica Acta. 2014; 131: 115-127. https://doi.org/10.1016/j.gca.2014.01.005
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Hassler U, Vemooij M, Emmerling E, Pietsch A
Marmorfarben: das Weiss und das Grau der Zürcher Semperaula
In: Hassler U, ed. Maltechnik & Farbmittel der Semperzeit. München: Hirmer; 2014:242-263.
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König CFJ, Schuh P, Huthwelker T, Smolentsev G, Schildhauer TJ, Nachtegaal M
Influence of the support on sulfur poisoning and regeneration of Ru catalysts probed by sulfur K-edge X-ray absorption spectroscopy
Catalysis Today. 2014; 229: 56-63. https://doi.org/10.1016/j.cattod.2013.09.065
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Nanzer S, Oberson A, Huthwelker T, Eggenberger U, Frossard E
The molecular environment of phosphorus in sewage sludge ash: implications for bioavailability
Journal of Environmental Quality. 2014; 43(3): 1050-1060. https://doi.org/10.2134/jeq2013.05.0202
DORA PSI -
Quinsaat JEQ, Testino A, Pin S, Huthwelker T, Nüesch FA, Bowen P, et al.
Continuous production of tailored silver nanoparticles by polyol synthesis and reaction yield measured by X-ray absorption spectroscopy: toward a growth mechanism
Journal of Physical Chemistry C. 2014; 118(20): 11093-11103. https://doi.org/10.1021/jp500949v
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Rittmann-Frank MH, Milne CJ, Rittmann J, Reinhard M, Penfold TJ, Chergui M
Mapping of the photoinduced electron traps in TiO2 by picosecond x-ray absorption spectroscopy
Angewandte Chemie International Edition. 2014; 53(23): 5858-5862. https://doi.org/10.1002/anie.201310522
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Sternitzke V, Janousch M, Heeb MB, Hering JG, Johnson CA
Strontium hydroxyapatite and strontium carbonate as templates for the precipitation of calcium-phosphates in the absence and presence of fluoride
Journal of Crystal Growth. 2014; 396: 71-78. https://doi.org/10.1016/j.jcrysgro.2014.03.036
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Vjunov A, Fulton JL, Huthwelker T, Pin S, Mei D, Schenter GK, et al.
Quantitatively probing the Al distribution in zeolites
Journal of the American Chemical Society. 2014; 136(23): 8296-8306. https://doi.org/10.1021/ja501361v
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Brown MA, Redondo AB, Jordan I, Duyckaerts N, Lee M-T, Ammann M, et al.
A new endstation at the Swiss Light Source for ultraviolet photoelectron spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy measurements of liquid solutions
Review of Scientific Instruments. 2013; 84(7): 073904 (8 pp.). https://doi.org/10.1063/1.4812786
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Czapla-Masztafiak J, Kwiatek W, Dulinska-Litewka J, Steininger R, Gottlicher J, Huthwelker T
The determination of chemical forms of sulfur in prostate cancer cells and tissue
In: X-RAY OPTICS AND MICROANALYSIS, PROCEEDINGS. Vol. 22. ; 2013:38.
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Nurk G, Huthwelker T, Braun A, Ludwig C, Lust E, Struis RPWJ
Redox dynamics of sulphur with Ni/GDC anode during SOFC operation at mid- and low-range temperatures: an operando S K-edge XANES study
Journal of Power Sources. 2013; 240: 448-457. https://doi.org/10.1016/j.jpowsour.2013.03.187
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Pin S, Huthwelker T, Brown MA, Vogel F
Combined sulfur K-edge XANES-EXAFS study of the effect of protonation on the sulfate tetrahedron in solids and solutions
Journal of Physical Chemistry A. 2013; 117(35): 8368-8376. https://doi.org/10.1021/jp404272e
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Brown MA, Huthwelker T, Beloqui Redondo A, Janousch M, Faubel M, Arrell CA, et al.
Changes in the silanol protonation state measured in situ at the silica-aqueous interface
Journal of Physical Chemistry Letters. 2012; 3(2): 231-235. https://doi.org/10.1021/jz201533w
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Maier SM, Jentys A, Janousch M, van Bokhoven JA, Lercher JA
Unique dynamic changes of Fe cationic species under NH3-SCR conditions
Journal of Physical Chemistry C. 2012; 116(9): 5846-5856. https://doi.org/10.1021/jp300349q
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Tew MW, Nachtegaal M, Janousch M, Huthwelker T, van Bokhoven JA
The irreversible formation of palladium carbide during hydrogenation of 1-pentyne over silica-supported palladium nanoparticles: in situ Pd K and L3 edge XAS
Physical Chemistry Chemical Physics. 2012; 14(16): 5761-5768. https://doi.org/10.1039/c2cp24068h
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Flechsig U, Huthwelker T, Spielmann S, Krempask J
LTP-V with EPICS controls system for efficient quality assessment of KB-bender systems
Nuclear Instruments and Methods in Physics Research, Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. 2011; 635(1 SUPPL.): S64-S68. https://doi.org/10.1016/j.nima.2010.09.114
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Lima FA, Milne CJ, Amarasinghe DCV, Rittmann-Frank MH, van der Veen RM, Reinhard M, et al.
A high-repetition rate scheme for synchrotron-based picosecond laser pump/x-ray probe experiments on chemical and biological systems in solution
Review of Scientific Instruments. 2011; 82(6): 063111 (16 pp.). https://doi.org/10.1063/1.3600616
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Tew MW, Janousch M, Huthwelker T, van Bokhoven JA
The roles of carbide and hydride in oxide-supported palladium nanoparticles for alkyne hydrogenation
Journal of Catalysis. 2011; 283(1): 45-54. https://doi.org/10.1016/j.jcat.2011.06.025
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Andreasson BP, Janousch M, Staub U, Meijer GI, Delley B
Resistive switching in Cr-doped SrTiO3: an X-ray absorption spectroscopy study
Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2007; 144(1-3): 60-63. https://doi.org/10.1016/j.mseb.2007.07.059
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