Multiphase Chemistry Group

The Multiphase Chemistry group performs laboratory studies related to the chemistry, photochemistry and kinetics of atmospheric multiphase processes involving organic, halogen, nitrogen oxide and odd oxygen species on substrates relevant for aerosol particles, cirrus ice, ocean surface, soil surfaces, snow and sea ice. Understanding these processes is relevant for the assessment of the human impact on atmospheric composition, climate, human and ecosystem health.
We use a combination of in-situ spectroscopy, flow tube and chamber techniques to cover scales from molecular level world of interfaces to the microstructure in aerosol particles and to the mesosopic medium of snow.
We educate young scientists in laboratory atmospheric chemistry within the frame of the Institute of Atmospheric and Climate Sciences (IAC) at ETH Zürich (Department of Environmental Systems Sciences, D-USYS).

Aerosol Multiphase Photochemistry

Multiphase Photochemistry

The interplay between reactive oxygen species and the multiphase chemistry of nitrogen, halogen and secondary organic species in aerosol particles. Reactive oxygen species are at the origin of redox processes within the aqueous phase of aerosol particles containing secondary organic and inorganic species. The consequences are halogen and nitrogen oxides recycling, formation and loss of organics, which are all implicated in atmospheric oxidation capacity as well as the burden and health impact of aerosol particles. 

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AcidBaseIce

Interfacial Ice Chemistry

Interfacial Ice Chemistry: Photolysis and Acid-Base Equilibria in the QLL and Brine. Dissociation and photochemistry of nitric acid and nitrous acid at frozen and liquid air-water interfaces have since long attracted scientific interest, most notably due to the pivotal role that this surface chemistry plays in modifying the nitrogen oxide budget and thus the oxidative capacity of the atmosphere.

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Confinement

Chemistry of confined water

The hydrogen bonding network of interfacial nano-confinements in clay. Clays are composed of crystalline aluminosilicate layers that may be held together by hydrogen bonds of embedded water. This project investigates the local chemical environment of ions in the interlayer space of clay and the structure of the hydrogen-bonding network at subfreezing temperatures.

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Napp

X-ray excited photoelectron spectroscopy for environmental science

We investigate multiphase chemistry of atmospheric relevance at the air-water and air-solid interfaces using X-ray excited electron spectroscopy  at the SIM & Phoenix & ISS endstations at the Swiss Light Source (SLS) and the ALS at the Lawrence Berkeley National Laboratory.

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Evolution of a research project

FAIR data visualization

IVDAV : Instant and versatile data visualization during the current dark period of the life cycle of FAIR research. This project develops changes to current data treatment exploring and prototyping processes to foster teamwork, effective communication, and improved data visualization to the benefit of the entire atmospheric chemistry research community. 

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A complete publication list is available at the institutional repository (DORA PSI).

  • Bartels-Rausch T, Ammann M
    It is time to introduce the next generation of chemists to FAIR and open science
    Chimia. 2023; 77(10): 694-696. https://doi.org/10.2533/chimia.2023.694
    DORA PSI
  • Bartels-Rausch T, Gabathuler JP, Yang H, Manoharan Y, Artiglia L, Ammann M
    Removing gas-phase features in near ambient pressure partial Auger-Meitner electron yield oxygen K-edge NEXAFS spectra
    Journal of Electron Spectroscopy and Related Phenomena. 2023; 264: 147320 (7 pp.). https://doi.org/10.1016/j.elspec.2023.147320
    DORA PSI
  • Chen J, Jiang H, Chen X, Wang J, Huang D, Lian C, et al.
    A novel mechanism for NO2-to-HONO conversion on soot: synergistic effect of elemental carbon and organic carbon
    Environmental Science and Technology Letters. 2023; 10(10): 878-884. https://doi.org/10.1021/acs.estlett.3c00624
    DORA PSI
  • Fauré N, Chen J, Artiglia L, Ammann M, Bartels-Rausch T, Li J, et al.
    Unexpected behavior of chloride and sulfate ions upon surface solvation of Martian salt analogue
    ACS Earth and Space Chemistry. 2023; 7(2): 350-359. https://doi.org/10.1021/acsearthspacechem.2c00204
    DORA PSI
  • Hong AC, Ulrich T, Thomson ES, Trachsel J, Riche F, Murphy JG, et al.
    Uptake of hydrogen peroxide from the gas phase to grain boundaries: a source in snow and ice
    Environmental Science and Technology. 2023; 57(31): 11626-11633. https://doi.org/10.1021/acs.est.3c01457
    DORA PSI
  • Kiland KJ, Mahrt F, Peng L, Nikkho S, Zaks J, Crescenzo GV, et al.
    Viscosity, glass formation, and mixing times within secondary organic aerosol from biomass burning phenolics
    ACS Earth and Space Chemistry. 2023; 7(7): 1388-1400. https://doi.org/10.1021/acsearthspacechem.3c00039
    DORA PSI
  • Knopf DA, Alpert PA
    Atmospheric ice nucleation
    Nature Reviews Physics. 2023; 5: 203-217. https://doi.org/10.1038/s42254-023-00570-7
    DORA PSI
  • Kong X, Gladich I, Fauré N, Thomson ES, Chen J, Artiglia L, et al.
    Adsorbed water promotes chemically active environments on the surface of sodium chloride
    Journal of Physical Chemistry Letters. 2023; 14(26): 6151-6156. https://doi.org/10.1021/acs.jpclett.3c00980
    DORA PSI
  • Kärcher B, Marcolli C, Mahrt F
    The role of mineral dust aerosol particles in aviation soot-cirrus interactions
    Journal of Geophysical Research D: Atmospheres. 2023; 128(3): e2022JD037881 (15 pp.). https://doi.org/10.1029/2022JD037881
    DORA PSI
  • Mahrt F, Rosch C, Gao K, Dreimol CH, Zawadowicz MA, Kanji ZA
    Physicochemical properties of charcoal aerosols derived from biomass pyrolysis affect their ice-nucleating abilities at cirrus and mixed-phase cloud conditions
    Atmospheric Chemistry and Physics. 2023; 23(2): 1285-1308. https://doi.org/10.5194/acp-23-1285-2023
    DORA PSI
  • Mallet MD, Humphries RS, Fiddes SL, Alexander SP, Altieri K, Angot H, et al.
    Untangling the influence of Antarctic and Southern Ocean life on clouds
    Elementa: Science of the Anthropocene. 2023; 11(1): 00130 (18 pp.). https://doi.org/10.1525/elementa.2022.00130
    DORA PSI
  • Yao Y, Alpert PA, Zuend A, Wang B
    Does liquid-liquid phase separation impact ice nucleation in mixed polyethylene glycol and ammonium sulfate droplets?
    Physical Chemistry Chemical Physics. 2023; 25(1): 80-95. https://doi.org/10.1039/d2cp04407b
    DORA PSI
  • Alpert PA, Boucly A, Yang S, Yang H, Kilchhofer K, Luo Z, et al.
    Ice nucleation imaged with X-ray spectro-microscopy
    Environmental Science: Atmospheres. 2022; 2(3): 335-351. https://doi.org/10.1039/D1EA00077B
    DORA PSI
  • Alpert PA, Kilthau WP, O'Brien RE, Moffet RC, Gilles MK, Wang B, et al.
    Ice-nucleating agents in sea spray aerosol identified and quantified with a holistic multimodal freezing model
    Science Advances. 2022; 8(44): eabq6842 (11 pp.). https://doi.org/10.1126/sciadv.abq6842
    DORA PSI
  • Ammann M, Artiglia L
    Solvation, surface propensity, and chemical reactions of solutes at atmospheric liquid-vapor interfaces
    Accounts of Chemical Research. 2022; 55(24): 3641-3651. https://doi.org/10.1021/acs.accounts.2c00604
    DORA PSI
  • Baboomian VJ, Crescenzo GV, Huang Y, Mahrt F, Shiraiwa M, Bertram AK, et al.
    Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts
    Proceedings of the National Academy of Sciences of the United States of America PNAS. 2022; 119(43): e2208121119 (10 pp.). https://doi.org/10.1073/pnas.2208121119
    DORA PSI
  • Boucly A, Artiglia L, Fabbri E, Palagin D, Aegerter D, Pergolesi D, et al.
    Direct evidence of cobalt oxyhydroxide formation on a La0.2Sr0.8CoO3 perovskite water splitting catalyst
    Journal of Materials Chemistry A. 2022; 10(5): 2434-2444. https://doi.org/10.1039/D1TA04957G
    DORA PSI
  • Corral Arroyo P, David G, Alpert PA, Parmentier EA, Ammann M, Signorell R
    Amplification of light within aerosol particles accelerates in-particle photochemistry
    Science. 2022; 376(6590): 293-296. https://doi.org/10.1126/science.abm7915
    DORA PSI
  • Gladich I, Chen S, Yang H, Boucly A, Winter B, van Bokhoven JA, et al.
    Liquid-gas interface of iron aqueous solutions and Fenton reagents
    Journal of Physical Chemistry Letters. 2022; 13(13): 2994-3001. https://doi.org/10.1021/acs.jpclett.2c00380
    DORA PSI
  • Gladich I, Chen S, Yang H, Boucly A, Winter B, Van Bokhoven JA, et al.
    Reply to "comment on 'liquid-gas interface of iron aqueous solutions and fenton reagents'"
    Journal of Physical Chemistry Letters. 2022; 13(29): 6681-6682. https://doi.org/10.1021/acs.jpclett.2c01391
    DORA PSI
  • Kong X, Dou J, Chen S, Wang B, Wu Z
    同步辐射技术在大气科学领域的研究进展. Progress of synchrotron-based research on atmospheric science
    Progress in Chemistry. 2022; 34(4): 963-972. https://doi.org/10.7536/PC210438
    DORA PSI
  • Kulju KD, McNamara SM, Chen Q, Kenagy HS, Edebeli J, Fuentes JD, et al.
    Urban inland wintertime N2O5 and ClNO2 influenced by snow-covered ground, air turbulence, and precipitation
    Atmospheric Chemistry and Physics. 2022; 22(4): 2553-2568. https://doi.org/10.5194/acp-22-2553-2022
    DORA PSI
  • Mahrt F, Peng L, Zaks J, Huang Y, Ohno PE, Smith NR, et al.
    Not all types of secondary organic aerosol mix: two phases observed when mixing different secondary organic aerosol types
    Atmospheric Chemistry and Physics. 2022; 22(20): 13783-13796. https://doi.org/10.5194/acp-22-13783-2022
    DORA PSI
  • Mahrt F, Huang Y, Zaks J, Devi A, Peng L, Ohno PE, et al.
    Phase behavior of internal mixtures of hydrocarbon-like primary organic aerosol and secondary aerosol based on their differences in oxygen-to-carbon ratios
    Environmental Science and Technology. 2022; 56(7): 3960-3973. https://doi.org/10.1021/acs.est.1c07691
    DORA PSI
  • Ohno PE, Wang J, Mahrt F, Varelas JG, Aruffo E, Ye J, et al.
    Gas-Particle uptake and hygroscopic growth by organosulfate particles
    ACS Earth and Space Chemistry. 2022; 6(10): 2481-2490. https://doi.org/10.1021/acsearthspacechem.2c00195
    DORA PSI
  • Uemura Y, Ismail ASM, Park SH, Kwon S, Kim M, Elnaggar H, et al.
    Hole dynamics in photoexcited hematite studied with femtosecond oxygen K-edge X-ray absorption spectroscopy
    Journal of Physical Chemistry Letters. 2022; 13(19): 4207-4214. https://doi.org/10.1021/acs.jpclett.2c00295
    DORA PSI
  • Xu S, Mahrt F, Gregson FKA, Bertram AK
    Possible effects of ozone chemistry on the phase behavior of skin oil and cooking oil films and particles indoors
    ACS Earth and Space Chemistry. 2022; 6(7): 1836-1845. https://doi.org/10.1021/acsearthspacechem.2c00092
    DORA PSI
  • Yang H, Gladich I, Boucly A, Artiglia L, Ammann M
    Orcinol and resorcinol induce local ordering of water molecules near the liquid-vapor interface
    Environmental Science: Atmospheres. 2022; 2(6): 1239-1570. https://doi.org/10.1039/d2ea00015f
    DORA PSI
  • Alpert PA, Dou J, Corral Arroyo P, Schneider F, Xto J, Luo B, et al.
    Photolytic radical persistence due to anoxia in viscous aerosol particles
    Nature Communications. 2021; 12(1): 1769 (8 pp.). https://doi.org/10.1038/s41467-021-21913-x
    DORA PSI
  • Anthony Cox R, Ammann M, Crowley JN, Griffiths PT, Herrmann H, Hoffmann EH, et al.
    Opinion: the germicidal effect of ambient air (open-air factor) revisited
    Atmospheric Chemistry and Physics. 2021; 21(17): 13011-13018. https://doi.org/10.5194/acp-21-13011-2021
    DORA PSI
  • Bartels-Rausch T, Kong X, Orlando F, Artiglia L, Waldner A, Huthwelker T, et al.
    Interfacial supercooling and the precipitation of hydrohalite in frozen NaCl solutions as seen by X-ray absorption spectroscopy
    Cryosphere. 2021; 15(4): 2001-2020. https://doi.org/10.5194/tc-15-2001-2021
    DORA PSI
  • Chen S, Artiglia L, Orlando F, Edebeli J, Kong X, Yang H, et al.
    Impact of tetrabutylammonium on the oxidation of bromide by ozone
    ACS Earth and Space Chemistry. 2021; 5(11): 3008-3021. https://doi.org/10.1021/acsearthspacechem.1c00233
    DORA PSI
  • Dou J, Alpert PA, Corral Arroyo P, Luo B, Schneider F, Xto J, et al.
    Photochemical degradation of iron(III) citrate/citric acid aerosol quantified with the combination of three complementary experimental techniques and a kinetic process model
    Atmospheric Chemistry and Physics. 2021; 21(1): 315-338. https://doi.org/10.5194/acp-21-315-2021
    DORA PSI
  • Garofalo LA, He Y, Jathar SH, Pierce JR, Fredrickson CD, Palm BB, et al.
    Heterogeneous nucleation drives particle size segregation in sequential ozone and nitrate radical oxidation of catechol
    Environmental Science and Technology. 2021; 55(23): 15637-15645. https://doi.org/10.1021/acs.est.1c02984
    DORA PSI
  • Huang Y, Mahrt F, Xu S, Shiraiwa M, Zuend A, Bertram AK
    Coexistence of three liquid phases in individual atmospheric aerosol particles
    Proceedings of the National Academy of Sciences of the United States of America PNAS. 2021; 118(16): e2102512118 (9 pp.). https://doi.org/10.1073/pnas.2102512118
    DORA PSI
  • Karagodin-Doyennel A, Rozanov E, Sukhodolov T, Egorova T, Saiz-Lopez A, Cuevas CA, et al.
    Iodine chemistry in the chemistry-climate model SOCOL-AERv2-I
    Geoscientific Model Development. 2021; 14(10): 6623-6645. https://doi.org/10.5194/gmd-14-6623-2021
    DORA PSI
  • Kilchhofer K, Mahrt F, Kanji ZA
    The role of cloud processing for the ice nucleating ability of organic aerosol and coal fly ash particles
    Journal of Geophysical Research D: Atmospheres. 2021; 126(10): e2020JD033338 (21 pp.). https://doi.org/10.1029/2020JD033338
    DORA PSI
  • Knopf DA, Barry KR, Brubaker TA, Jahl LG, Jankowski KA, Li J, et al.
    Aerosol–ice formation closure: a Southern Great Plains field campaign
    Bulletin of the American Meteorological Society. 2021; 102(10): E1952-E1971. https://doi.org/10.1175/BAMS-D-20-0151.1
    DORA PSI
  • Knopf DA, Ammann M
    Technical note: adsorption and desorption equilibria from statistical thermodynamics and rates from transition state theory
    Atmospheric Chemistry and Physics. 2021; 21(20): 15725-15753. https://doi.org/10.5194/acp-21-15725-2021
    DORA PSI
  • Kong X, Castarède D, Thomson ES, Boucly A, Artiglia L, Ammann M, et al.
    A surface-promoted redox reaction occurs spontaneously on solvating inorganic aerosol surfaces
    Science. 2021; 374(6568): 747-752. https://doi.org/10.1126/science.abc5311
    DORA PSI
  • Kärcher B, Mahrt F, Marcolli C
    Process-oriented analysis of aircraft soot-cirrus interactions constrains the climate impact of aviation
    Communications Earth & Environment. 2021; 2(1): 113 (9 pp.). https://doi.org/10.1038/s43247-021-00175-x
    DORA PSI
  • Mahrt F, Newman E, Huang Y, Ammann M, Bertram AK
    Phase behavior of hydrocarbon-like primary organic aerosol and secondary organic aerosol proxies based on their elemental oxygen-to-carbon ratio
    Environmental Science and Technology. 2021; 55(18): 12202-12214. https://doi.org/10.1021/acs.est.1c02697
    DORA PSI
  • Marcolli C, Mahrt F, Kärcher B
    Soot PCF: pore condensation and freezing framework for soot aggregates
    Atmospheric Chemistry and Physics. 2021; 21(10): 7791-7843. https://doi.org/10.5194/acp-21-7791-2021
    DORA PSI
  • McNamara SM, Chen Q, Edebeli J, Kulju KD, Mumpfield J, Fuentes JD, et al.
    Observation of N2O5 deposition and ClNO2 production on the saline snowpack
    ACS Earth and Space Chemistry. 2021; 5(5): 1020-1031. https://doi.org/10.1021/acsearthspacechem.0c00317
    DORA PSI
  • Mellouki A, Ammann M, Cox RA, Crowley JN, Herrmann H, Jenkin ME, et al.
    Evaluated kinetic and photochemical data for atmospheric chemistry: volume VIII - gas-phase reactions of organic species with four, or more, carbon atoms (≥C4)
    Atmospheric Chemistry and Physics. 2021; 21(6): 4797-4808. https://doi.org/10.5194/acp-21-4797-2021
    DORA PSI
  • Yang H, Boucly A, Gabathuler JP, Bartels-Rausch T, Artiglia L, Ammann M
    Ordered hydrogen bonding structure of water molecules adsorbed on silver iodide particles under subsaturated conditions
    Journal of Physical Chemistry C. 2021; 125(21): 11628-11635. https://doi.org/10.1021/acs.jpcc.1c01767
    DORA PSI

Contact

Prof. Dr. Markus Ammann
Head of Multiphase Chemistry Group

Telephone: +41 56 310 40 49
E-mail: markus.ammann@psi.ch