Skip to main content
  • Paul Scherrer Institut PSI
  • PSI Research, Labs & User Services

Digital User Office

  • Digital User Office
  • DE
  • EN
  • FR
Paul Scherrer Institut (PSI)
Search
Paul Scherrer Institut (PSI)

Hauptnavigation

  • Research at PSIOpen mainmenu item
    • Research Initiatives
    • Ethics and Research integrity
    • Scientific Highlights
    • Scientific Events
    • Scientific Career
    • PSI-FELLOW
    • PSI Data Policy
  • Research Divisions and LabsOpen mainmenu item
    • Overview
    • Research with Neutrons and Muons
    • Photon Science
    • Energy and Environment
    • Nuclear Energy and Safety
    • Biology and Chemistry
    • Scientific Computing, Theory and Data
    • Large Research Facilities
  • Facilities and InstrumentsOpen mainmenu item
    • Overview
    • Large Research Facilities
    • Facilities
    • PSI Facility Newsletter
  • PSI User ServicesOpen mainmenu item
    • User Office
    • Methods at the PSI User Facilities
    • Proposals for beam time
    • Proposal Deadlines
    • Data Analysis Service (PSD)
    • EU support programmes
  • New ProjectsOpen mainmenu item
    • SLS 2.0
    • IMPACT
  • DE
  • EN
  • FR

Digital User Office (mobile)

  • Digital User Office

You are here:

  1. PSI Home
  2. Labs & User Services
  3. PSD
  4. SLS
  5. Super_XAS
  6. Taking a snapshot of the triplet excited state of an OLED organometallic luminop

Secondary navigation

SuperXAS

  • People
  • User Information
    • Operation Schedule
    • Useful Phone numbers
  • Ex Situ Sample Measurements
  • Beamline Layout
    • Source
    • Optics
  • Sample environments
    • Pump-Probe XAS
    • Johann XES spectrometer
    • von Hamos XES spectrometer
    • Capillary reactor setup
  • Publications
  • Scientific Highlights
1 May 2020

Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays

OLED technology beyond small or expensive devices requires light-emitters, luminophores, based on earth-abundant elements. Understanding and experimental verification of charge transfer in luminophores are needed for this development. An organometallic multicore Cu complex comprising Cu–C and Cu–P bonds represents an underexplored type of luminophore. To investigate the charge transfer and structural rearrangements in this material, we apply complementary pump-probe X-ray techniques: absorption, emission, and scattering including pump-probe measurements at the X-ray free-electron laser SwissFEL. We find that the excitation leads to charge movement from C- and P- coordinated Cu sites and from the phosphorus atoms to phenyl rings; the Cu core slightly rearranges with 0.05 Å increase of the shortest Cu–Cu distance. The use of a Cu cluster bonded to the ligands through C and P atoms is an efficient way to keep structural rigidity of luminophores. Obtained data can be used to verify computational methods for the development of luminophores.

Additional information

Link to the media release

Contact

Dr. Grigory Smolentsev
SuperXAS beamline
Operando spectroscopy group & Laboratory for Synchrotron Radiation and Femtochemistry (LSF)
Swiss Light Source, Paul Scherrer Intitute
5232 Villigen-PSI, Switzerland
Telephone: +41 56 310 58 05
E-mail: grigory.smolentsev@psi.ch

Original Publication

Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays

G. Smolentsev, C. J. Milne, A. Guda, K. Haldrup, J. Szlachetko, N. Azzaroli, C. Cirelli, G. Knopp, R. Bohinc, S. Menzi, G. Pamfilidis, D. Gashi, M. Beck, A. Mozzanica, D. James,C. Bacellar, G. F. Mancini, A. Tereshchenko, V. Shapovalov, W. M. Kwiatek, J. Czapla-Masztafiak,A. Cannizzo, M. Gazzetto, M. Sander, M. Levantino, V. Kabanova, E. Rychagova,S. Ketkov, M. Olaru, J. Beckmann, M. Vogt

Nature Communications, 1 May 2020
DOI: 10.1038/s41467-020-15998-z

Sidebar

top

Footer

Paul Scherrer Institut

Forschungsstrasse 111
5232 Villigen PSI
Switzerland

Telephone: +41 56 310 21 11
Telefax: +41 56 310 21 99

How to find us
Contact

Visitor Centre psi forum
School Lab iLab (in German)
Center for Proton Therapy
PSI Education Centre
PSI Guest House
PSI Gastronomie (in German)
psi forum shop

Service & Support

  • Phone Book
  • User Office
  • Accelerator Status
  • PSI Publications
  • Suppliers
  • E-Billing
  • Computing
  • Safety (in German)

Career

  • Working at PSI
  • Job Opportunities
  • Training and further education
  • Career Center
  • Vocational Training (in German)
  • PSI Education Center

For the media

  • PSI in brief
  • Facts and Figures
  • Media corner
  • Media Releases
  • Social Media

Follow us: Twitter (in English) LinkedIn Youtube Facebook Instagram Issuu RSS

Footer legal

  • Imprint
  • Terms and Conditions
  • Editors' login