Scientific Highlights

Multiresolution X-ray tomography, getting a clear view of the interior

Researchers at PSI have developed a technique that combines tomography measurements at different resolution levels to allow quantitative interpretation for nanoscale tomography on an interior region of interest of the sample. In collaboration with researchers of the institute AMOLF in the Netherlands and ETH Zurich in Switzerland they showcase their technique by studying the porous structure within a section of an avian eggshell. The detailed measurements of the interior of the sample allowed the researchers to quantify the ordering and distribution of an intricate network of pores within the shell.

Left: Structure of BaFe2As2 with the motion pattern of the A1g phonon mode (red arrows). 
Right: Pump-induced change of diffraction intensity of the (1 0 5) reflection

Ultrafast structural dynamics of the Fe-pnictide parent compound BaFe2As2

Understanding the interplay of the various degrees of freedom such as the electrons, spins and lattice is essential for many complex materials, including the high-temperature superconductors.

Magnetization dynamics inside a 5 µm x 5 µm structure.(a) Time-resolved PEEM images using XMCD as a magnetic contrast mechanism recorded at a given time delay t after the laser pulse and (b) extracted XMCD contrast as a function of the time delay t for three different ROI, defined in the inset image by the coloured area superimposed on the non-dichroic X-ray absorption of the structure. The 0° incoming laser direction with respect to the structure edge is indicated in the inset by the laser in-plane wave v…

Nanoscale sub-100 picosecond all-optical magnetization switching in GdFeCo microstructure

Ultrafast magnetization reversal driven by femtosecond laser pulses has been shown to be a promising way to write information. Seeking to improve the recording density has raised intriguing fundamental questions about the feasibility of combining ultrafast temporal resolution with sub-wavelength spatial resolution for magnetic recording. Here we report on the experimental demonstration of nanoscale sub-100 ps all-optical magnetization switching, providing a path to sub-wavelength magnetic recording.

ARPES spectra revealing the electronic structure of a metallic surface state on SrTiO3.

A revealing mixture: The surface of an oxide insulator can host two distinct types of conducting electrons

Strontium titanate, SrTiO3, is an important material for the realization of next-generation electronic devices. A famous example is the interface of LaAlO3 grown on SrTiO3, which is metallic and magnetic at its interface, even though the individual compounds are insulating and nonmagnetic in bulk form. The physics behind how novel interface states form on SrTiO3 - and how they become endowed with such surprising properties - is not well understood.

Square dance of the atoms: Shedding light on ultrafast phase transitions

The exploration of the interaction of structural and electronic degrees of freedom in strongly correlated electron systems on the femtosecond time scale is an emerging area of research. One goal of these studies is to advance our understanding of the underlying correlations, another to find ways to control the exciting properties of these materials on an ultrafast time scale.

The vacuum chamber in which the sample was located during the experiment. (Photo: Teresa Kubacka)

Observed live with x-ray laser: electricity controls magnetism

Researchers from ETH Zurich and the Paul Scherrer Institute PSI demonstrate how the magnetic structure can be altered quickly in novel materials. The effect could be used in efficient hard drives of the future.

Elemental and magnetic contrast images in the initial state before the magnetic field is applied

Direct Observation of Magnetic Metastability in Individual Iron Nanoparticles

Studying the magnetization of individual iron (Fe) nanoparticles by magnetic spectromicroscopy reveals that superparamagnetic (SPM) and ferromagnetic blocked (FM) nanoparticles can coexist in the investigated size range of 8-20 nm.

An illustration of ARPES in an antiferromagnetic order state

Comprehensive study of the spin-charge interplay in antiferromagnetic La2-xSrxCuO4

The origin of the pseudogap and its relationship with superconductivity in the cuprates remains vague. In particular, the interplay between the pseudogap and magnetism is mysterious. Recent low-temperature angle-resolved photoemission spectroscopy (ARPES) experiments on the underdoped cuprate superconductors indicate the presence of a fully gapped Fermi surface (FS); even in the antiferromagnetic phase.

(top) 3D rendering of density distribution within carbon fibers, where high- and low-density regions are shown in black and in a semitransparent gray tone, respectively. On the left we show a fiber of 25 µm diameter, and on the right a 10 µm-diameter fiber made from a different precursor. Remarkable differences are observed between the two fibers.

Unique insight into carbon fibers on the nanoscale

Novel carbon materials are promising candidates for light and robust low-cost materials of the future. Understanding their mechanical properties benefits from highly resolved three-dimensional (3D) maps of their porosity and density fluctuations in uninterrupted representative volumes, but these are difficult to obtain with conventional imaging methods.

Section of the tomogram, parallel to the rotation axis. Three distinct gray levels are visible for air (black), glass (gray), and Ta2O5 (white).

X-ray tomography reaches 16 nm isotropic 3D resolution

Tomographic microscopy has become an invaluable imaging method in both life and materials sciences. Oftentimes, high resolving power is required simultaneously with the ability to characterize large, statistically representative sample volumes. To this task, researchers at the Paul Scherrer Institut have established ptychographic computed tomography.

© 2014 J Hugo Dil/EPFL

Spintronics: deciphering a material for future electronics

Topological insulators are the key to future spintronics technologies. EPFL scientists have unraveled how these strange materials work, overcoming one of the biggest obstacles on the way to next-generation applications.Read the full story

The ash formations in La Garita Caldera in Colorado, USA, are the result of eruptions of a supervolcano approximately 25 million years ago. (Photo: Courtesy of www.danielmcvey.com)

Supervolcano eruptions driven by melt buoyancy in large silicic magma chambers

Super-eruptions that dwarf all historical volcanic episodes in erupted volume and environmental impact are abundant in the geological record. Such eruptions of silica-rich magmas form large calderas. The mechanisms that trigger these supereruptions are elusive because the processes occurring in conventional volcanic systems cannot simply be scaled up to the much larger magma chambers beneath super volcanoes.

(top) Schematic view of the X-PEEM experiment with in-situ applied electric fields performed at the SIM beamline of the Swiss Light Source. (bottom) X-PEEM images of an array of nickel nanoislands showing a uniform 90° in-plane magnetization reorientation (highlighted with blue circles).

Single Domain Spin Manipulation by Electric Fields in Strain Coupled Artificial Multiferroic Nanostructures

Encoding information by the application of an electric field has a key role in the development of novel memory devices that can operate at high speed while keeping low energy consumption. In magnetoelectric multiferroics, magnetic and ferroelectric ordering coexist and are coupled together so that it is possible to manipulate the material's magnetic structure by applying an electric field with a negligible current flow.

Magnetic nano-rods, arranged on the sides of a hexagon (bottom) or several hexagons (middle and top), form the ring systems studied by the scientists. Several linked rings serve as a model for a frustrated system: regardless of how the magnetisation of the central rod is oriented, energetically unfavourable conditions always arise, i.e. two north poles or two south poles will inevitably meet one another - marked in yellow.

Tiny Magnets as a Model System

Scientists use nano-rods to investigate how matter assembles

In the microscopic world, everything is in motion: atoms and molecules vibrate, proteins fold, even glass is a slow flowing liquid. And during each movement there are interactions between the smallest elements - for example, the atoms - and their neighbours. To make these movements visible, scientists at the Paul Scherrer Institute PSI have developed a special model system.

Schematic view of the femtosecond laser pump/x-ray probe
experiment performed at the FEMTO slicing source identifying the atomic motion coupled to the charge and orbital order in a manganite.

Atomic motions untangled

The pursuit of capturing motion in a movie bears an obvious fascination irrespective of the time scales involved. In the atomic and molecular world where the masses are so light and the distances small the relevant time scale shifts to the subpicosecond range and the motions become frantic especially for larger molecular systems.

Artistic view of the interface between the LaAlO3 (layer on top: La atoms are yellow Al atoms are purple and O atoms are in green) and the SrTiO3 single crystal (Sr atoms are red, Ti atoms are in blue) probed with photoemission.

Soft x-ray photoelectron spectroscopy on buried complex oxide interfaces: a new method to diagnose authentic protected electronic structures

Exotic phenomena at interfaces of complex oxides are highly promising for future solid-state electronics applications. A prominent example is the interface of two wide band gap insulators formed by growing a LaAlO3 layer on TiO2-terminated SrTiO3 substrate. When the LaAlO3 thickness exceeds 3 unit cells this system undergoes a sharp insulator-to-metal transition with a two-dimensional electron gas (2DEG) appearing at the interface.

A schematic of the setup employed for the experimental demonstration. X rays are focused and scatter off a test sample that can be displaced laterally with nanometer precision. The diffraction pattern produced by the scattered X rays is collected by a detector. The sample is reconstructed on a computer from the diffraction data (see other images).

Imaging fluctuations with X-ray microscopy

X-rays allow an inside look at structures that cannot be imaged using visible light. They are used to investigate nanoscale structures of objects as varied as single cells or magnetic storage media. Yet, high-resolution images impose extreme constraints on both the X ray microscope and the samples under investigation.

Magnetic nano-chessboard. Upper part: Visualisation of the molecule using a scanning tunnel microscope; the molecular structure is indicated for two of the molecules. Lower part: Schematic representation of the self-assembly of the molecules; they fit together like pieces of a jigsaw puzzle and arrange themselves in a continuously alternating pattern.

Magnetic nano-chessboard puts itself together

Researchers from the Paul Scherrer Institute and the Indian Institute of Science Education and Research (Pune, India) have managed to ‘turn off’ the magnetization of every second molecule in an array of magnetized molecules and thereby create a ‘magnetic chessboard’. The magnetic molecules were so constructed that they were able to find their places in the nano-chessboard by themselves.

Example of skeletonization techniques used to measure bubble and pore throat sizes. a) The topology preserving skeleton with nodes shown in red at the intersections of the branches.  b) The maximal inscribed spheres used to calculate the bubble volumes. c) The maximal inscribed spheres used to calculate the pore throat diameters.  Wall thicknesses were also determined using maximal inscribed spheres. (Graphic: J. Fife/PSI; D. Baker/McGill University)Please note: all images are for single use only to illust…

X-rays provide insights into volcanic processes

Experiments performed at the Paul Scherrer Institute (PSI) investigate processes inside volcanic materials that determine whether a volcano will erupt violently or mildly.

Brookhaven’s Mark Dean and PSI’s Thorsten Schmitt at the ADRESS beamline at the Swiss Light Source. (Photo: PSI / M. Fischer)

New Insights into Superconducting Materials

An American-Swiss research team has used a new X-ray technique at Swiss Light Source (SLS) of the Paul Scherrer Institute (PSI) to investigate the magnetic properties of atomically thin layers of a parent compound of a high-temperature superconductor. It turns out that the magnetic properties of such thin films differ by only a surprisingly small degree from those of macroscopically thick samples.

Experimental Fermi surface of VSe2 sliced in three planes in 3D k-space. The FS anisotropy reflects the highly anisotropic macroscopic properties of this material. The experiment is in excellent agreement with the DFT predictions (blue contours).

Three-Dimensional Electron Realm in Crystalline Solids Revealed with Soft-X-Rays

The electronic band structure E(k) as energy E of the electrons depending on its wavevector k is the cornerstone concept of the quantum solid state theory. The main experimental method to investigate E(k) is the angle-resolved photoelectron spectroscopy (ARPES). However, a small photoelectron escape depth of a few Å largely restricts the applications of ARPES to two-dimensonal crystals.

Simon Rutishauser assembles phase and absorption gratings into the grating interferometer structure (Photo: PSI/M. Fischer)

Ultra-short X-ray laser pulses precisely surveyed for the first time

X-ray lasers belong to a modern generation of light sources from which scientists in widely different disciplines expect to obtain new knowledge about the structure and function of materials at the atomic level. On the basis of this new knowledge, it could then be possible one day to develop better medicines, more powerful computers or more efficient catalysts for energy transformation.

The researchers Claudia Cancellieri (left) and Mathilde Reinle-Schmitt at an apparatus that produces thin layers of different materials with the aid of a laser (Paul Scherrer Institute/M. Fischer)

Controversy clarified: Why two insulators together can transport electricity

How can two materials which do not conduct electricity create an electrically conducting layer when they are joined together? Since this effect was discovered in 2004, researchers have developed various hypotheses to answer this question – each with its own advocates, who defend it and try to prove its validity. Now, an international team under the leadership of researchers at the Paul Scherrer Institute has probably settled the controversy.

3D view of the spin-vector orientation as determined by SARPES

Three-Dimensional Spin Rotations in a Monolayer Electron System

In the emerging field of spintronics, the generation, injection, and in particular the control of highly spin polarized currents are main issues to be solved. Lifting of spin degeneracy by the spin-orbit interaction at surfaces, known as Rashba effect, represents a promising approach, since it generates two spin-polarized bands without the necessity of an external field. In our recent study, we realize such a system for a metallic surface layer on a semiconductor: Au/Ge(111).

PSI Scientific Reports

Archive 2006-2012. The Scientific Reports – containing accounts of research topics from all the different areas – provide an impression of the variety of subjects researched at PSI.