Dr. Dario Ferreira Sanchez

Dario Ferreira Sanchez

Beamline Scientist @microXAS beamline

Paul Scherrer Institute
Forschungsstrasse 111
5232 Villigen PSI

At the microXAS beamline, Dario Ferreira Sanchez's been responsible for the multimodal tomographic approach. That involves data analysis development, user support and collaboration, and in-line data reduction during and after the experiments as well.  The focus is on development to provide unique capabilities for Imaging Chemistry in Space and Time in an unlimited range of reactive systems at relevant spatial and temporal length scales. Hyperspectral Chemical Imaging allows a broad range of scientific communities to gain unrivaled insights into the chemical complexity of hierarchical, heterogeneous materials, including corresponding chemical reaction pathways and kinetics (reactivity).

    Main activities:

    • Development of synchrotron chemical imaging approaches: imaging chemistry in space and time.
    • Data analysis development.
    • Especial interest on energy related (engineered) materials, and technique analysis development.
      Research activities with especial focus on Solid Oxide Cells and Battery metamaterials.
    • Especial interest in advanced additive manufacturing.
    • Development of the energy-dispersive X-ray absorption spectroscopy scanning tomography (ED-TomoXAS).
    • Development of 3D full-field X-ray absorption spectroscopy computed tomography (FF-TomoXAS); 
    • User support at microXAS beamline. That includes: (i) proposal, experiment strategy development; (ii) experiment assistance; (iii) data processing and analysis; (iv) user 'coaching program' on data analysis, contribution to synchrotron schools; organization of workshops (and hands-on training); (v) post doctorate fellows, PhD and master students supervision; (vi) manuscript elaboration for publication.
    • Synchrotron instrumentation and experimental setup commissioning and development.

    Master´s in Physics . Universidade Federal do Paraná, UFPR, Brazil. Year of degree: 2009.

    Master degree obtained at the Department of Physics of UFPR (Brazil), supervised by Kleber Daum Machado, was focused on the investigation of the structural and optical properties of a class of amorphous alloy systems: chalcogenide glasses. Combined analysis of X-ray diffraction (XRD), EXAFS, Reverse Monte Carlo (RMC) method, and Raman spectroscopy was applied. RMC was applied using XRD data alone and XRD+EXAFS data simultaneously in order to investigate structural information such as mean interatomic distances and coordination numbers.

    Related publications:

    • MACHADO, K., SANCHEZ, D., DELIMA, J., & GRANDI, T. (2008). Modeling the atomic structure of an amorphous Co57Ti43 alloy produced by mechanical alloying using RMC simulations. Solid State Communications, 148(1–2), 46–49. https://doi.org/10.1016/j.ssc.2008.07.027 
    • Machado, K. D., Sanchez, D. F., MacIel, G. A., Brunatto, S. F., Mangrich, A. S., & Stolf, S. F. (2009). Vibrational, optical and structural studies of an amorphous Se9S1 alloy produced by mechanical alloying. Journal of Physics Condensed Matter, 21(19). https://doi.org/10.1088/0953-8984/21/19/195406
    • Machado, K. D., Maciel, G. A., Sanchez, D. F., de Lima, J. C., & Jóvári, P. (2010). Structural study of an amorphous Cu64Ti36 alloy produced by mechanical alloying using XRD, EXAFS and RMC simulations. Solid State Communications, 150(35–36), 1674–1678. https://doi.org/10.1016/j.ssc.2010.06.027
    • Machado, K. D., Sanchez, D. F., & Brunatto, S. F. (2010). Reverse Monte Carlo simulations of an amorphous Se0.90S0.10 alloy produced by mechanical alloying combining XRD and EXAFS data. Journal of Non-Crystalline Solids, 356(50–51), 2865–2868. https://doi.org/10.1016/j.jnoncrysol.2010.09.076
    • Machado, K. D., Dubiel, A. S., Deflon, E., Kostrzepa, I. M., Stolf, S. F., Sanchez, D. F., & Jóvári, P. (2010). Investigation on vibrational and structural properties of amorphous Se1−xSx alloys produced by mechanical alloying by Raman spectroscopy, X-ray diffraction, EXAFS and RMC simulations. Solid State Communications, 150(29–30), 1359–1363. https://doi.org/10.1016/j.ssc.2010.04.037
    • Kostrzepa, I. M., Siqueira, M. C., Machado, K. D., Maciel, G. A., Sanchez, D. F., & Brunatto, S. F. (2012). Structural investigations on an amorphous Se90Te10 alloy produced by mechanical alloying using EXAFS, cumulant expansion and RMC simulations. Journal of Physics. Condensed Matter : An Institute of Physics Journal, 24(12), 125401. https://doi.org/10.1088/0953-8984/24/12/125401

    Ph.D. in Physics . Universidade Federal do Rio Grande do Sul, UFRGS, Brazil. Year of degree: 2013. 

    Work of thesis (2009-2012) at the Physics Institute of UFRGS (Brazil), supervised by Paulo F. P. Fichtner and Pedro L. Grande, was focused on the microstructural, morphological and compositional characterization of nanostructured systems through the combination of several complementary techniques, which includes Medium Energy Ion Scattering (MEIS), Transmission Electron Microscopy (TEM), Grazing Incidence Small Angle X-Rays Scattering (GISAXS) and Rutherford Backscattering Spectrometry (RBS). The main focus of the thesis’ work was on the development and understanding of the MEIS technique applied in the modelling of buried nanostructured systems close to the surface. 

    Related publications:

    • Sanchez, D. F., Marmitt, G., Marin, C., Baptista, D. L., de M Azevedo, G., Grande, P. L., & Fichtner, P. F. P. (2013). New approach for structural characterization of planar sets of nanoparticles embedded into a solid matrix. Scientific Reports, 3, 3414. https://doi.org/10.1038/srep03414
    • Dario F. Sanchez, Raquel Moiraghi, Fernando P. Cometto, Manuel A. Peréz, Paulo F. P. Fichtner, Pedro L. Grande (2015). Morphological and compositional characteristics of bimetallic core@shell nanoparticles revealed by MEIS. Applied Surface Science, 330, 164–171. http://dx.doi.org/10.1016/j.apsusc.2014.12.198
    • D.F. Sanchez, F. Rodrigues, F.P. Luce, Z.E. Fabrim, G. de M. Azevedo, G. Kellermann, D.L. Baptista, P.L. Grande, P.F.P. Fichtner (2014). MEIS, TEM and GISAXS investigation of buried Pb nanoislands in SiO2/Si interface, Applied Surface Science, 321, 80–85. http://dx.doi.org/10.1016/j.apsusc.2014.09.190
    • Sanchez, D. F., Luce, F. P., Fabrim, Z. E., Sortica, M. A., Fichtner, P. F. P., & Grande, P. L. (2011). Structural characterization of Pb nanoislands in SiO2/Si interface synthesized by ion implantation through MEIS analysis. Surface Science, 605(7–8), 654–658. https://doi.org/10.1016/j.susc.2010.12.011
    • Leveneur, J., Sanchez, D. F., Kennedy, J., Grande, P. L., Williams, G. V. M., Metson, J. B., & Cowie, B. C. C. (2012). Iron-based bimagnetic core/shell nanostructures in SiO2: a TEM, MEIS, and energy-resolved XPS analysis. Journal of Nanoparticle Research, 14(10), 1149. https://doi.org/10.1007/s11051-012-1149-1
    • Luce, F. P., Kremer, F., Reboh, S., Fabrim, Z. E., Sanchez, D. F., Zawislak, F. C., & Fichtner, P. F. P. (2011). Aging effects on the nucleation of Pb nanoparticles in silica. Journal of Applied Physics, 109(1). https://doi.org/10.1063/1.3530844

    Postdoctorate. Commissariat à l'Energie Atomique - Grenoble, CEA/GRENOBLE, France (2013 - 2015).

    Postdoctoral fellow in CEA/LETI department, with Pierre Bleuet and Patrice Gergaud. The main project consisted on the development of the micro-Laue diffraction tomography analysis technique, and the application of it in the study of Through Silicon vias (TSVs) and Solid Oxide Fuel Cells (SOFCs). Experimental development at the BM32 beamline, ESRF.

    Related publications:

    • Ferreira Sanchez, D., Villanova, J., Laurencin, J., Micha, J.-S., Montani, A., Gergaud, P., & Bleuet, P. (2015). X-ray micro Laue diffraction tomography analysis of a solid oxide fuel cell. Journal of Applied Crystallography, 48(2), 357–364. https://doi.org/10.1107/S1600576715002447
    • Dario Ferreira Sanchez, David Laloum , Monica-Larissa Djomeni-Weleguela , Olivier Ulrich , Guillaume Audoit , Adeline Grenier , Jean-Sebastien Micha , Odile Robach , Frederic Lorut , Patrice Gergaud , Pierre Bleuet (2014). X-ray µ-Laue diffraction analysis of Cu through-silicon vias: A two-dimensional and three-dimensional study, Journal of Applied Physics, 116, 163509. http://dx.doi.org/10.1063/1.489931
    • Sanchez, D. F., Reboh, S., Weleguela, M. L. D., Micha, J. S., Robach, O., Mourier, T., … Bleuet, P. (2016). In-situ X-ray µLaue diffraction study of copper through-silicon vias. Microelectronics Reliability, 56, 78–84. https://doi.org/10.1016/j.microrel.2015.10.008
    • Khamidy NI, Laurencin J, Ferreira Sanchez D, Monaco F, Charlot F, Djurado E
      Durability of nanostructured LaPrNiO4+δ electrode for solid oxide cells: electrochemical, microstructural, and structural investigation
      Journal of Power Sources. 2020; 450: 227724 (10 pp.). https://doi.org/10.1016/j.jpowsour.2020.227724
      DORA PSI
    • Li X, Zweiacker K, Grolimund D, Ferreira Sanchez D, Spierings AB, Leinenbach C, et al.
      In situ and ex situ characterization of the microstructure formation in Ni-Cr-Si alloys during rapid solidification - toward alloy design for laser additive manufacturing
      Materials. 2020; 13(9): 2192 (14 pp.). https://doi.org/10.3390/ma13092192
      DORA PSI
    • Makowska M, Sasikumar PVW, Hagelüken L, Ferreira Sanchez D, Casati N, Marone F, et al.
      Cracks, porosity and microstructure of Ti modified polymer-derived SiOC revealed by absorption-, XRD- and XRF-contrast 2D and 3D imaging
      Acta Materialia. 2020; 198: 134-144. https://doi.org/10.1016/j.actamat.2020.07.067
      DORA PSI
    • Pfeiffer S, Makowska M, Kevin Florio, Ferreira Sanchez D, Marone F, Zhang X, et al.
      Selective laser melting of thermal pre-treated METAL oxide doped aluminum oxide granules
      Open Ceramics. 2020: 100007 (48 pp.). https://doi.org/10.1016/j.oceram.2020.100007
      DORA PSI
    • Weibo H, Wang K, Knapp M, Schwarz B, Wang S, Liu H, et al.
      Chemical and structural evolution during the synthesis of layered Li(Ni,Co,Mn)O2 oxides
      Chemistry of Materials. 2020. https://doi.org/10.1021/acs.chemmater.9b05279
      DORA PSI
    • Bower WR, Morris K, Livens FR, Mosselmans JFW, Fallon CM, Fuller AJ, et al.
      Metaschoepite dissolution in sediment column systems—implications for uranium speciation and transport
      Environmental Science and Technology. 2019; 53(16): 9915-9925. https://doi.org/10.1021/acs.est.9b02292
      DORA PSI
    • Cannelli O, Bacellar C, Ingle RA, Bohinc R, Kinschel D, Bauer B, et al.
      Toward time-resolved laser T-jump/X-ray probe spectroscopy in aqueous solutions
      Structural Dynamics. 2019; 6(6): 064303 (8 pp.). https://doi.org/10.1063/1.5129626
      DORA PSI
    • Deillon L, Verheyden S, Ferreira Sanchez D, Van Petegem S, Van Swygenhoven H, Mortensen A
      Laue microdiffraction characterisation of as-cast and tensile deformed Al microwires
      Philosophical Magazine. 2019; 99(15): 1866-1880. https://doi.org/10.1080/14786435.2019.1605220
      DORA PSI
    • Gambino M, Veselý M, Filez M, Oord R, Ferreira Sanchez D, Grolimund D, et al.
      Nickel poisoning of a cracking catalyst unravelled by single particle X-ray fluorescence-diffraction-absorption tomography
      Angewandte Chemie International Edition. 2019. https://doi.org/10.1002/anie.201914950
      DORA PSI
    • Gervilla F, Asta MP, Fanlo I, Grolimund D, Ferreira-Sánchez D, Samson VA, et al.
      Diffusion pathways of Fe2+ and Fe3+ during the formation of ferrian chromite: a µXANES study
      Contributions to Mineralogy and Petrology. 2019; 174(8): 65 (16 pp.). https://doi.org/10.1007/s00410-019-1605-3
      DORA PSI
    • Hocine S, Van Swygenhoven H, Van Petegem S, Chang CST, Maimaitiyili T, Tinti G, et al.
      Operando X-ray diffraction during laser 3D printing
      Materials Today. 2019. https://doi.org/10.1016/j.mattod.2019.10.001
      DORA PSI
    • Pfeiffer S, Florio K, Makowska M, Ferreira Sanchez D, Van Swygenhoven H, Aneziris CG, et al.
      Iron oxide doped spray dried aluminum oxide granules for selective laser sintering and melting of ceramic parts
      Advanced Engineering Materials. 2019; 21(6): 1801351. https://doi.org/10.1002/adem.201801351
      DORA PSI
    • Trombini H, Guterres Marmitt G, Alencar I, Lorscheitter Baptista D, Reboh S, Mazen F, et al.
      Unraveling structural and compositional information in 3D FinFET electronic devices
      Scientific Reports. 2019; 9(1): 11629 (7 pp.). https://doi.org/10.1038/s41598-019-48117-0
      DORA PSI
    • Tsai EHR, Billaud J, F. Sanchez D, Ihli J, Odstrčil M, Holler M, et al.
      Correlated X-ray 3D ptychography and diffraction microscopy visualize links between morphology and crystal structure of lithium-rich cathode materials
      iScience. 2019; 11: 356-365. https://doi.org/10.1016/j.isci.2018.12.028
      DORA PSI
    • Birri M, Samson VA, F. Sanchez D, Grolimund D, Willimann M
      Fast X-Ray beam intensity stabilization for absorption spectroscopy and spectromicroscopic imaging
      In: Schaa VRW, Tavakoli K, Tilmont M, eds. Proceedings of the 10th mechanical engineering design of synchrotron radiation equipment and instrumentation. Vol. 10. Mechanical engineering design of synchrotron radiation equipment and instrumentation. Geneva, Switzerland: JACoW Publishing; 2018:343-345. https://doi.org/10.18429/JACoW-MEDSI2018-THPH04
      DORA PSI
    • Lebugle M, Dworkowski F, Pauluhn A, Guzenko VA, Romano L, Meier N, et al.
      High-intensity x-ray microbeam for macromolecular crystallography using silicon kinoform diffractive lenses
      Applied Optics. 2018; 57(30): 9032-9039. https://doi.org/10.1364/AO.57.009032
      DORA PSI
    • Neumeier S, Middendorp R, Knott A, Dürr M, Klinkenberg M, Pointurier F, et al.
      Microparticle production as reference materials for particle analysis methods in safeguards
      In: Scientific basis for nuclear waste management XLI. Vol. 3. MRS advances. Materials Research Society; 2018:1005-1012. https://doi.org/10.1557/adv.2018.166
      DORA PSI
    • Rodriguez-Fernandez A, Esposito V, Sanchez DF, Finkelstein KD, Juranic P, Staub U, et al.
      Spatial displacement of forward-diffracted X-ray beams by perfect crystals
      Acta Crystallographica Section A: Foundations and Advances. 2018; 74(2): 75-87. https://doi.org/10.1107/S2053273318001419
      DORA PSI
    • Chollet M, Gong W, Ferreira Sanchez D, Samson VA, Bertsch J
      Quantifying the stress field of hydride precipitation by mu-XRD tomography
      Presented at: Water reactor fuel performance meeting 2017 (WRFPM 2017); September 10-14, 2017; Jeju, Korea.
      DORA PSI
    • Ferreira Sanchez D, Simionovici AS, Lemelle L, Cuartero V, Mathon O, Pascarelli S, et al.
      2D/3D microanalysis by energy dispersive X-ray absorption spectroscopy tomography
      Scientific Reports. 2017; 7: 16453 (12 pp.). https://doi.org/10.1038/s41598-017-16345-x
      DORA PSI
    • Ferreira Sanchez D, Grolimund D, Hubert M, Bleuet P, Laurencin J
      A 2D and 3D X-ray μ-diffraction and μ-fluorescence study of a mixed ionic electronic conductor
      International Journal of Hydrogen Energy. 2017; 42(2): 1203-1211. https://doi.org/10.1016/j.ijhydene.2016.11.094
      DORA PSI
    • Ihli J, Jacob RR, Holler M, Guizar-Sicairos M, Diaz A, da Silva JC, et al.
      A three-dimensional view of structural changes caused by deactivation of fluid catalytic cracking catalysts
      Nature Communications. 2017; 8: 809 (10 pp.). https://doi.org/10.1038/s41467-017-00789-w
      DORA PSI
    • Ihli J, Ferreira Sanchez D, Jacob RR, Cuartero V, Mathon O, Krumeich F, et al.
      Localization and speciation of iron impurities within a fluid catalytic cracking catalyst
      Angewandte Chemie International Edition. 2017; 56(45): 14031-14035. https://doi.org/10.1002/anie.201707154
      DORA PSI
    • Ihli J, Ferreira Sanchez D, Jacob RR, Cuartero V, Mathon O, Krumeich F, et al.
      Localization and speciation of iron impurities within a fluid catalytic cracking catalyst
      Angewandte Chemie. 2017; 129(45): 14219-14223. https://doi.org/10.1002/ange.201707154
      DORA PSI
    • Kenel C, Grolimund D, Li X, Panepucci E, Samson VA, Ferreira Sanchez D, et al.
      In situ investigation of phase transformations in Ti-6Al-4V under additive manufacturing conditions combining laser melting and high-speed micro-X-ray diffraction
      Scientific Reports. 2017; 7: 16358 (10 pp.). https://doi.org/10.1038/s41598-017-16760-0
      DORA PSI
    • Laurencin J, Hubert M, Ferreira Sanchez D, Pylypko S, Morales M, Morata A, et al.
      Degradation mechanism of La0.6Sr0.4Co0.2Fe0.8O3-δ/Gd0.1Ce0.9O2-δ composite electrode operated under solid oxide electrolysis and fuel cell conditions
      Electrochimica Acta. 2017; 241: 459-476. https://doi.org/10.1016/j.electacta.2017.05.011
      DORA PSI
    • Middendorp R, Dürr M, Knott A, Pointurier F, Ferreira Sanchez D, Samson V, et al.
      Characterization of the aerosol-based synthesis of uranium particles as a potential reference material for microanalytical methods
      Analytical Chemistry. 2017; 89(8): 4721-4728. https://doi.org/10.1021/acs.analchem.7b00631
      DORA PSI
    • Santomauro FG, Grilj J, Mewes L, Nedelcu G, Yakunin S, Rossi T, et al.
      Localized holes and delocalized electrons in photoexcited inorganic perovskites: Watching each atomic actor by picosecond X-ray absorption spectroscopy
      Structural Dynamics. 2017; 4(4): 44002 (11 pp.). https://doi.org/10.1063/1.4971999
      DORA PSI