Publications 2003

BRADBURY M.H., BAEYENS B. (2003)
Near field sorption data bases for compacted MX-80 bentonite for performance assessment of a high-level radioactive waste repository in Opalinus clay host rock
PSI Bericht Nr. 03-07, Nagra NTB 02-18


BRADBURY M.H., BAEYENS B. (2003)
Far field sorption data bases for performance assessment of a high-level radioactive waste repository in an undistrubed Opalinus clay host rock
PSI Bericht Nr. 03-08, Nagra NTB 02-19


BAEYENS B., BRADBURY M.H., HUMMEL W.
Determination of aqueous Nickel-Carbonate and Nickel-Oxalate complexation constants
Journal of Solution Chemistry, Vol. 32, No. 4, (2003)

BONHOURE I., WIELAND E., SCHEIDEGGER A., OCHS M., KUNZ D.
EXAFS Study of Sn(IV) immobilization by hardened cement paste and calcium silicate hydrates
Environ. Sci. Technol. 37, 2184-2191 (2003)

BRADBURY M.H, BAEYENS B. (2003)
A comparison of apparent diffusion coefficients measured in compacted kunigel V1 bentonite with those calculated from batch sorption measurments and De (HTO) Data: A case study for Cs(I), Ni(II), Sm(III), Am(III), Zr(IV) and Np(V)
PSI Bericht Nr. 03-02, Nagra NTB 02-17


CURTI E. (2003)
Glass dissolution parameters: update for "Entsorgungsnachweis"
PSI Bericht Nr. 03-18, Nagra NTB 02-21


DAEHN R., SCHEIDEGGER A.M., MANCEAU A., SCHLEGEL M. L., BAEYENS B., BRADBURY M. H., CHATEIGNER D. (2003)
Structural evidence for the sorption of Ni(II) atoms on the edges of montmorillonite clay minerals. A polarized X-ray absorption fine structure study.
Geochim. Cosmochim. Acta 67 (1), 1-15.


DEGUELDRE C., SCHOLTIS A., LAUBE A., TURRERO M.J., THOMAS B.
Study of the pore water chemistry through an argillaceous formation: a paleohydrochemical approach
Applied Geochemistry 18, 55-73 (2003)

DEGUELDRE C., FAVARGER P.-Y.
Colloid analysis by single particle inductively coupled plasma-mass spectroscopy: a feasibility study
Colloids and Surfaces A: Physicochem. Eng. Aspects 217, 137-142 (2003)

HUMMEL W.
The influence of cyanide complexation on the speciation and solubility of radionuclides in a geological repository
Environmental Geology *45:*633-646 DOI 10.1007/s00254-003-0928-5 (2003).

HUMMEL W., CURTI E.
Nickel aqueous speciation and solubility at ambient conditions: a thermodynamic elegy
Monatshefte für Chemie 134, 941-973 DOI 10.1007/s00706-003-0010-8 (2003).

JAKOB A., MAZUREK M., HEER W.
Solute transport in crystalline rocks at Äspö - II: Blind predictions, inverse modelling and lessons learnt from test STT1
Journal of Contaminant Hydrology 61, 175-190 (2003).


MAZUREK M., JAKOB A., BOSSART P.
Solute transport in crystalline rocks at Äspö - I: Geological basis and model calibration
Journal of Contaminant Hydrology 61, 157-174 (2003)


MÖRI A., ALEXANDER W.R., GECKEIS H., HAUSER W., SCHÄFER T. EIKENBERG J., FIERZ TH., DEGUELDRE C., MISSANA T.
The colloid and radionuclide retardation experiment at the Grimsel Test Site: influence of bentonite colloids on radionuclide migration in a fractured rock
Colloids and Surfaces A: Physicochem. Eng. Aspects 217, 33-47 (2003)

PARK Y.-J., LEE K.-K., KOSAKOWSKI G., BERKOWITZ B.
Transport behavior in three-dimensional fracture intersections
Water Resour. Res., 39(8), 1215, doi:10.1029/2002WR001801 (2003)


PFINGSTEN W., SOLER J.M.
Modelling of nonreactive tracer dipole tests in a shear zone at the Grimsel test site
Journal of Contaminant Hydrology 61, 387-403 (2003)


RAI D., HESS N.J., XIA Y., Rao L., CHO H.M., MOPORE R.C., VAN LOON L.
Comprehensive thermodynamic model applicable to highly acidic to basic conditions for isosaccharinate reactions with Ca(II) and Np(IV)
Journal of Solution Chemistry, Vol. 32, No. 8 (2003)

SOLER J.M.
Reactive transport modeling of the interaction between a high-pH plume and a fractured marl: the case of Wellenberg
Applied Geochemistry 18, 1555-1571 doi:10.1016/S0883-2927(03)00048-9 (2003)


TITS J., STUMPF TH., RABUNG TH., WIELAND E., FANGHÄNEL TH.,
Uptake of Cm(III) and Eu(III) by calcium silicate hydrates: a solution chemistry and time-resolved laser fluorescence spectroscopy study
Environ. Sci. Technol. 37, 3568-3573 (2003).

TITS J., JAKOB A., WIELAND E., SPIELER P.
Diffusion of tritiated water and 22Na+ through nondegraded hardened cement pastes
Journal of Contaminant Hydrology 61, 45-62 (2003).


VAN LOON L.R, SOLER J. & BRADBURY M.H. (2003)
Diffusion of HTO, 36Cl– and 125I– in Opalinus Clay from Mont Terri: Effect of confining pressure.
Journal of Contaminant Hydrology 61, 73-83.

VAN LOON L. R., SOLER J. M., JAKOB A., BRADBURY M.H. (2003)
Effect of Confining Pressure on the Diffusion of HTO, 36Cl- and 125I- in a Layered Argillaceous Rock (Opalinus Clay): Diffusion Perpendicular to the Fabric.
Applied Geochemistry 18, 1653-1662.


WIELAND E., VAN LOON L.R. (2003)
Cementitious near field sorption data base for performance assessment of an ILW repository in Opalinus clay
PSI Bericht Nr. 03-06, Nagra NTB 02-20


WIELAND E., BRADBURY M.H. & VAN LOON L.R. (2003)
Development of a sorption data base for the cementitious near-field of a repository for radioactive waste.
Czech. J. Phys. 53, A629-A638.