Publications 2015

Publications 2015

Electrode engineering of conversion-based negative electrodes for Na-ion batteries L.O. Vogt, C. Marino, C. Villevieille
Chimia 69 (12), 729-733 (2015).
DOI: 10.2533/chimia.2015.729OG-5411
 
Visualization of 0-0 peroxo-like dimers in high-capacity layered oxides for Li-ion batteries E. McCalla, A.M. Abakumov, M. Saubanère, D. Foix, E.J. Berg, G. Rousse, M.-L. Doublet, D. Gonbeau, P. Novák, G. van Tendeloo, R. Dominko, J.-M. Tarascon
Science 350 (6267), 1516-1521 (2015).
DOI: 10.1126/science.aac8260OG-5410 , OG-5412
 
Rechargeable batteries: Grasping for the limits of chemistry E.J. Berg, C. Villevieille, D. Streich, S. Trabesinger, P. Novák
J. Electrochem. Soc. 162 (14), A2468-A2475 (2015).
DOI: 10.1149/2.0081514jesOG-5410 , OG-5411 , OG-5412 , OG-5413
 
Lithium chromium pyrophosphate as an insertion material for Li-ion batteries M. Reichardt, S. Sallard, P. Novák, C. Villevieille
Acta Cryst. B71, 661-667 (2015).
DOI: 10.1107/S2052520615017539OG-5410 , OG-5411
 
Lithium iron methylenediphosphonate: A model material for new organic–inorganic hybrid positive electrode materials for Li ion batteries S. Schmidt, D. Sheptiakov, J.-C. Jumas, M. Medarde, P. Benedek, P. Novák, S. Sallard, C. Villevieille
Chem. Mater. 27 (23), 7889–7895 (2015).
DOI: 10.1021/acs.chemmater.5b02595OG-5410 , OG-5411
 
Radiation-grafted polymer electrolyte membranes for water electrolysis cells: Evaluation of key membrane properties A. Albert, A.O. Barnett, M.S. Thomassen, T.J. Schmidt, L. Gubler
ACS Appl. Mater. Interfaces 7, 40, 22203-22212 (2015).
DOI: 10.1021/acsami.5b04618OG-5421
 
Effects of temperature and catalyst type on chemical degradation of radiation grafted membranes in PEFCs Z. Zhang, Y. Buchmüller, L. Bonorand, A. Wokaun, T.J. Schmidt, L. Gubler
Fuel Cells 15, 4, 610-618 (2015).
DOI: 10.1002/fuce.201500019OG-5421
 
Concentration effects on the entropy of electrochemical lithium deposition: implications for Li+ solvation M.J. Schmid, J. Xu, J. Lindner, P. Novák, R. Schuster
J. Phys. Chem. B 119, 13385-13390 (2015).
DOI: 10.1021/acs.jpcb.5b07670OG-5410 , OG-5412 , OG-5413
 
Combined operando X-ray diffraction-electrochemical impedance spectroscopy detecting solid solution reactions of LiFePO4 in batteries M. Hess, T. Sasaki, C. Villevielle, P. Novák
Nature Commun. 6, 8169 (2015).
DOI: 10.1038/NCOMMS9169OG-5410 , OG-5411 , OG-5413
 
Engineered water highways in fuel cells: Radiation grafting of gas diffusion layers A. Forner-Cuenca, J. Biesdorf, L. Gubler, P.M. Kristiansen, T.J. Schmidt, P. Boillat
Adv. Mater. 27, 6317–6322 (2015).
DOI: 10.1002/adma.201503557OG-5420
 
Correlating electrolyte inventory and lifetime of HT-PEFC by accelerated stress testing S.H. Eberhardt, T. Lochner, F.N. Büchi, T.J. Schmidt
J. Electrochem. Soc. 162, F1367–F1372 (2015).
DOI: 10.1149/2.0591512jesOG-5422
 
Taming the polysulphide shuttle in Li–S batteries by plasma-induced asymmetric functionalisation of the separator J. Conder, S. Urbonaite, D. Streich, P. Novák, L. Gubler
RSC Adv. 5, 79654 (2015).
DOI: 10.1039/C5ra13197aOG-5410 , OG-5413 , OG-5421
 
Impact of hydrophobic coating on mass transport losses
in PEFCs
J. Biesdorf, A. Forner-Cuenca, T.J. Schmidt, P. Boillat
J. Electrochem. Soc. 162 (10), F1243-F1252 (2015).
DOI: 10.1149/2.0861510jesOG-5420
 
Freeze-dryed LixMoO3 nanobelts used as cathode materials for lithium-ion batteries: A bulk and interface study C. Villevieille, A. Gorzkowska-Sobas, H. Fjellvåg, P. Novák
J. Power Sources 297, 276-282 (2015).
DOI: 10.1016/j.jpowsour.2015.07.082OG-5410 , OG-5411
 
Imaging phosphoric acid migration in high temperature polymer electrolyte fuel cells by X-ray tomographic microscopy S.H. Eberhardt, F. Marone, M. Stampanoni, F.N. Büchi, T.J. Schmidt
ECS Trans. 69 (17), 591-599 (2015).
DOI: 10.1149/06917.0591ecstOG-5420
 
When size matters: Active Area dependence of PEFC cold start capability J. Biesdorf, P. Stahl, M. Siegwart, T.J. Schmidt, P. Boillat
J. Electrochem. Soc., 162 (10), F1231-F1235 (2015).
DOI: 10.1149/2.0871510jesOG-5420
 
Consequences of electrolyte degradation for the electrochemical performance of Li1+x(NiaCobMn1-a-b)1-xO2 H.-J. Peng, S. Urbonaite, C. Villevieille, H. Wolf, K. Leitner, P. Novák
J. Electrochem. Soc., 162 (13), A7072-A7077 (2015).
DOI: 10.1149/2.0061513jesOG-5410 , OG-5411 , OG-5413
 
A low-temperature benzyl alcohol/Benzyl mercaptan synthesis of iron oxysulfide/iron oxide composite materials for electrodes in Li-ion batteries S. Sallard, E. Castel, C. Villevieille, P. Novák
J. Mater. Chem. A 3, 16112 (2015).
DOI: 10.1039/c5ta03155aOG-5410 , OG-5411
 
_In situ_ X-ray diffraction characterisation of Fe0.5TiOPO4 and Cu0.5TiOPO4 as electrode material for sodium-ion batteries P. Bleith, H. Kaiser, P. Novák, C. Villevieille
Electrochim. Acta 176, 18–21 (2015).
DOI: 10.1016/j.electacta.2015.06.105OG-5410 , OG-5411
 
Investigation of the liquid water distributions in a 50 cm(2) PEM fuel cell: Effects of reactants relative humidity, current density, and cathode stoichiometry A. Iranzo, P. Boillat, J. Biesdorf, A. Salva
J. Energy 82, 914-921 (2015).
DOI: 10.1016/j.energy.2015.01.101OG-5420
 
Thermodynamic explanation of the universal correlation between oxygen evolution activity and corrosion of oxide catalysts T. Binninger, R. Mohamed, K. Waltar, E. Fabbri, P. Levecque, R. Kötz, T.J. Schmidt
Sci. Rep. 5, 12167 (2015).
DOI: 10.1038/ srep12167OG-5423
 
Structural changes and microstrain generated on LiNi0.80Co0.15Al0.05O2 during cycling: Effects on the electrochemical performance R. Robert, P. Novák
J. Electrochem. Soc. 162 (9), A1823-A1828 (2015).
DOI: 10.1149/2.0721509jesOG-5410 , OG-5414
 
Electrochemical study of Si/C composites with particulate and fibrous morphology as negative electrodes for lithium-ion batteries J.L. Gómez-Cámer, H. Thuv, P. Novák
J. Power Sources 294, 128–135 (2015).
DOI: 10.1016/j.jpowsour.2015.06.067OG-5410 , OG-5413
 
Reversible Li-intercalation through oxygen reactivity in Li-rich Li-Fe-Te oxide materials E. McCalla, A.S. Prakash, E. Berg, M. Saubanère, A.M. Abakumov, D. Foix, B. Klobes, M.-T. Sougrati, G. Rousse, F. Lepoivre, S. Mariyappan, D. Foix, B. Klobes, M.-T. Sougrati, G. Rousse, F. Lepoivre, S. Mariyappan, M.-L. Doublet, D. Gonbeau, P. Novak, G. Van Tendeloo, R.P. Hermann, J.-M. Tarascon
J. Electrochem. Soc. 162 (7), A1341-A1351 (2015).
DOI: 10.1149/2.0991507jesOG-5410 , OG-5412
 
Influence of graphite edge crystallographic orientation on the first lithium intercalation in Li-ion battery Ph. Bernardo, J.-M. Le Meins, L. Vidal, J. Dentzer, R. Gadiou, W. Märkle, P. Novák, M.E. Spahr, C. Vix-Guterl
Carbon 91, 458–467 (2015).
DOI: 10.1016/j.carbon.2015.05.001OG-5410 , OG-5413
 
Understanding inhomogeneous reactions in li-ion batteries: Operando synchrotron X-Ray diffraction on two-layer electrodes T. Sasaki, C. Villevieille, Y. Takeuchi, P. Novák
Adv. Sci. 1500083 (2015).
DOI: 10.1002/advs.201500083OG-5410 , OG-5411
 
Understanding the roles of anionic redox and oxygen release during electrochemical cycling of lithium-rich layered Li4FeSbO6 E. McCalla, M.T. Sougrati, G. Rousse, E. Jämstorp Berg, A. Abakumov, N. Recham, K. Ramesha, M. Sathiya, R. Dominko, G. Van Tendeloo, P. Novák, J.-M. Tarascon
J. Am. Chem. Soc. 137 (14), 4804–4814 (2015).
DOI: 10.1021/jacs.5b01424OG-5410 , OG-5412
 
Progress towards commercially viable Li-S battery cells S. Urbonaite, T. Poux, P. Novák
Adv. Energy Mater. 1500118 (2015).
DOI: 10.1002/aenm.201500118OG-5410 , OG-5413
 
Surface/Interface study on full xLi2MnO3{middle dot}(1 - x)LiMO2 (M = Ni, Mn, Co)/graphite cells L. Boulet-Roblin, M. El Kazzi, P. Novák, C. Villevieille
J. Electrochem. Soc. 162, 7, A1297-A1300 (2015).
DOI: 10.1149/2.0491507jesOG-5410 , OG-5411 , OG-5414
 
High-resolution and large-area nanoparticle arrays using EUV interference lithography K. Waiz, S.A. Tschupp, M. Oezaslan, T.J. Schmidt, J. Gobrecht, J.A. van Bokhoven, Y. Ekinci
Nanoscale, 7, 7386-7393 (2015).
DOI: 10.1039/c5nr00565eOG-5423
 
Water distribution analysis in the outer perimeter region of technical PEFC based on neutron radiography P. Stahl, J. Biesdorf, P. Boillat, J. Kraft, K.A. Friedrich
J. Electrochem. Soc. 162, 7, F677-F685 (2015).
DOI: 10.1149/2.0351507jesOG-5420
 
Electrocatalysis of perovskites: The influence of carbon on the oxygen evolution activity R. Mohamed, X. Cheng, E. Fabbri, P. Levecque, R. Kötz, O. Conrad, T.J. Schmidt
J. Electrochem. Soc. 162, 6, F579-F586 (2015).
DOI: 10.1149/2.0861506jesOG-5423
 
From electrochemical interface to interphase (2D->3D) on ionomer membranes Y. Buchmüller, R. Hafner, A. Wokaun, T.J. Schmidt, L. Gubler
ChemElectroChem 2, 338–342 (2015).
DOI: 10.1002/celc.201402332OG-5421
 
Understanding the interaction of the carbonates and binder in Na-Ion batteries: A combined bulk and surface study L.O. Vogt, M. El Kazzi, E. Jämstorp Berg, S. Pérez Villar, P. Novák, C. Villevieille
Chem. Mater. 27, 1210-1216 (2015).
DOI: 10.1021/cm5039649OG-5410 , OG-5411 , OG-5412 , OG-5414
 
Simultaneous in situ x‑ray absorption spectroscopy and x‑ray diffraction studies on battery materials: The case of Fe0.5TiOPO4 P. Bleith, W. van Beek, H. Kaiser, P. Novák, C. Villevieille
J. Phys. Chem. C 119, 3466-3471 (2015).
DOI: 10.1021/jp511042xOG-5410 , OG-5411
 
Influence of conversion material morphology on electrochemistry studied with operando x-ray tomography and diffraction C. Villevieille, M. Ebner, J.L. Gómez-Cámer, F. Marone, P. Novák, V. Wood
Adv. Mater. 27, 1676-1681 (2015).
DOI: 10.1002/adma.201403792OG-5410 , OG-5411 , OG-5413
 
Particle-Support interferences in small-angle x-ray scattering from supported-catalyst materials T. Binninger, M. Garganourakis, J. Han, A. Patru, E. Fabbri, O. Sereda, R. Kötz, A. Menzel, T.J. Schmidt
Phys. Rev. Applied 3, 024012 (2015).
DOI: 10.1103/PhysRevApplied.3.024012OG-5423
 
Noble metal aerogels-synthesis, characterization, and application as electrocatalysts W. Liu, A.K. Herrmann, N.C. Bigall, P. Rodriguez, D. Wen, M. Oezaslan, T.J. Schmidt, N. Gaponik, A. Eychmüller
Acc. Chem. Res. 48, 154-162 (2015).
DOI: 10.1021/ar500237cOG-5423
 
_In situ_ gas analysis of Li4Ti5O12 based electrodes at elevated temperatures M. He, E. Castel, A. Laumann, G. Nuspl, P. Novák, E.J. Berg
J. Electrochem. Soc. 162, 6, A870-A876 (2015).
DOI: 10.1149/2.0311506jes]OG-5410 , OG-5411 , OG-5412
 
Activation mechanism of LiNi0.80Co0.15Al0.05O2: Surface and bulk operando electrochemical, differential electrochemical mass spectrometry, and X‑ray diffraction analyses R. Robert, Ch. Bünzli, E.J. Berg, P. Novák
Chem. Mater. 27, 526−536 (2015).
DOI: 10.1021/cm503833bOG-5410 , OG-5412 , OG-5413 , OG-5414
 
Towards a stable organic electrolyte for the Lithium oxygen battery B.D. Adams, R. Black, Z. Williams, R. Fernandes, M. Cuisinier, E. Jaemstorp Berg, P. Novák, G.K. Murphy, L.F. Nazar
Adv. Energy Mater. 5, 1400867 (2015).
DOI: 10.1002/aenm.201400867OG-5410 , OG-5412
 
MoS2 coating on MoO3 nanobelts: A novel approach for a high specific charge electrode for rechargeable Li-ion batteries C. Villevieille, X.-J. Wang, F. Krumeich, R. Nesper, P. Novák
J. Power Sources 279, 636-644 (2015).
DOI: 10.1016/j.jpowsour.2014.12.129OG-5410 , OG-5411
 
Methyl phosphate formation as a major degradation mode of direct methanol fuel cells with phosphoric acid based electrolytes D. Aili, A. Vasiliev, J.O. Jensen, T.J. Schmidt, Q. Li
J. Power Sources 279, 517-521 (2015).
DOI: 10.1016/j.jpowsour.2015.01.010OG-5423
 
Dynamic operation of HT-PEFC: In-operando imaging of phosphoric acid profiles and (Re)distribution S.H. Eberhardt, M. Toulec, F. Marone, M. Stampanoni, F.N. Büchi, T.J. Schmidt
J. Electrochem. Soc. 162, 3, F310-F316 (2015).
DOI: 10.1149/2.0751503jesOG-5422
 
Think Different! Carbon corrosion mitigation strategy in high temperature PEFC: A rapid aging study T. Engl, L. Gubler, T.J. Schmidt
J. Electrochem. Soc. 162, 3, F291-F297 (2015).
DOI: 10.1149/2.0681503jesOG-5421
 
MSnS2 (M = Cu, Fe) electrode family as dual-performance electrodes for Li–S and Li–Ion batteries C. Villevieille, P. Novák
J. Electrochem. Soc. 162, 3, A284-A287 (2015).
DOI: 10.1149/2.0121503jesOG-5410 , OG-5411
 
Important aspects for reliable electrochemical impedance spectroscopy measurements of Li-Ion battery electrodes Ch. Bünzli, H. Kaiser, P. Novák
J. Electrochem. Soc. 162, 1, A218-A222 (2015).
DOI: 10.1149/2.1061501jesOG-5410 , OG-5413
 
Polyacrylate bound TiSb2 electrodes for Li-ion batteries J.L. Gómez-Cámer, P. Novák
J. Power Sources 273, 174–179 (2015)..
DOI: 10.1016/j.jpowsour.2014.09.087OG-5410 , OG-5413
 
One-pot polyol synthesis of Pt/CeO2 and Au/CeO2 nanopowders as catalysts for CO oxidation F. Pilger, A. Testino, M.A. Lucchini, A. Kambolis, M. Tarik, M. El Kazzi, Y. Arroyo, M.D. Rossell, Ch. Ludwig
J. Nanoscience and Nanotechnology 15, 5 (10), 3530-3539 (2015).
DOI: 10.1166/jnn.2015.9861OG-5410 , OG-5414
 
Oxygen Evolution Reaction on La1-xSrxCoO3 Perovskites: A Combined Experimental and Theoretical Study of Their Structural, Electronic, and Electrochemical Properties X. Cheng, E. Fabbri, M. Nachtegaal, I. Castelli, M. El Kazzi, R. Haumont, N. Marzari, T.J. Schmidt
Chem. Mater. 27, 7662-7672 (2015).
DOI: 10.1021/acs.chemmater.5b03138OG-5414 , OG-5423
 
Silicone Nanofilament Supported Nickel Oxide: A New Concept for Oxygen Evolution Catalysts in Water Electrolyzers G.R. Meseck, E. Fabbri, T.J. Schmidt, S. Seeger
Adv. Mater. Interfaces 2, 1500216/1-1500216/5 (2015).
DOI: 10.1002/admi.201500216OG-5423