Publications 2015

Publications 2015

Electrode engineering of conversion-based negative electrodes for Na-ion batteries L.O. Vogt, C. Marino, C. Villevieille

Chimia 69 (12), 729-733 (2015).

DOI: 10.2533/chimia.2015.729OG-5411
 

Visualization of 0-0 peroxo-like dimers in high-capacity layered oxides for Li-ion batteries E. McCalla, A.M. Abakumov, M. Saubanère, D. Foix, E.J. Berg, G. Rousse, M.-L. Doublet, D. Gonbeau, P. Novák, G. van Tendeloo, R. Dominko, J.-M. Tarascon

Science 350 (6267), 1516-1521 (2015).

DOI: 10.1126/science.aac8260OG-5410 , OG-5412
 

Rechargeable batteries: Grasping for the limits of chemistry E.J. Berg, C. Villevieille, D. Streich, S. Trabesinger, P. Novák

J. Electrochem. Soc. 162 (14), A2468-A2475 (2015).

DOI: 10.1149/2.0081514jesOG-5410 , OG-5411 , OG-5412 , OG-5413
 

Lithium chromium pyrophosphate as an insertion material for Li-ion batteries M. Reichardt, S. Sallard, P. Novák, C. Villevieille

Acta Cryst. B71, 661-667 (2015).

DOI: 10.1107/S2052520615017539OG-5410 , OG-5411
 

Lithium iron methylenediphosphonate: A model material for new organic–inorganic hybrid positive electrode materials for Li ion batteries S. Schmidt, D. Sheptiakov, J.-C. Jumas, M. Medarde, P. Benedek, P. Novák, S. Sallard, C. Villevieille

Chem. Mater. 27 (23), 7889–7895 (2015).

DOI: 10.1021/acs.chemmater.5b02595OG-5410 , OG-5411
 

Radiation-grafted polymer electrolyte membranes for water electrolysis cells: Evaluation of key membrane properties A. Albert, A.O. Barnett, M.S. Thomassen, T.J. Schmidt, L. Gubler

ACS Appl. Mater. Interfaces 7, 40, 22203-22212 (2015).

DOI: 10.1021/acsami.5b04618OG-5421
 

Effects of temperature and catalyst type on chemical degradation of radiation grafted membranes in PEFCs Z. Zhang, Y. Buchmüller, L. Bonorand, A. Wokaun, T.J. Schmidt, L. Gubler

Fuel Cells 15, 4, 610-618 (2015).

DOI: 10.1002/fuce.201500019OG-5421
 

Concentration effects on the entropy of electrochemical lithium deposition: implications for Li+ solvation M.J. Schmid, J. Xu, J. Lindner, P. Novák, R. Schuster

J. Phys. Chem. B 119, 13385-13390 (2015).

DOI: 10.1021/acs.jpcb.5b07670OG-5410 , OG-5412 , OG-5413
 

Combined operando X-ray diffraction-electrochemical impedance spectroscopy detecting solid solution reactions of LiFePO4 in batteries M. Hess, T. Sasaki, C. Villevielle, P. Novák

Nature Commun. 6, 8169 (2015).

DOI: 10.1038/NCOMMS9169OG-5410 , OG-5411 , OG-5413
 

Engineered water highways in fuel cells: Radiation grafting of gas diffusion layers A. Forner-Cuenca, J. Biesdorf, L. Gubler, P.M. Kristiansen, T.J. Schmidt, P. Boillat

Adv. Mater. 27, 6317–6322 (2015).

DOI: 10.1002/adma.201503557OG-5420
 

Correlating electrolyte inventory and lifetime of HT-PEFC by accelerated stress testing S.H. Eberhardt, T. Lochner, F.N. Büchi, T.J. Schmidt

J. Electrochem. Soc. 162, F1367–F1372 (2015).

DOI: 10.1149/2.0591512jesOG-5422
 

Taming the polysulphide shuttle in Li–S batteries by plasma-induced asymmetric functionalisation of the separator J. Conder, S. Urbonaite, D. Streich, P. Novák, L. Gubler

RSC Adv. 5, 79654 (2015).

DOI: 10.1039/C5ra13197aOG-5410 , OG-5413 , OG-5421
 

Impact of hydrophobic coating on mass transport losses
in PEFCs J. Biesdorf, A. Forner-Cuenca, T.J. Schmidt, P. Boillat

J. Electrochem. Soc. 162 (10), F1243-F1252 (2015).

DOI: 10.1149/2.0861510jesOG-5420
 

Freeze-dryed LixMoO3 nanobelts used as cathode materials for lithium-ion batteries: A bulk and interface study C. Villevieille, A. Gorzkowska-Sobas, H. Fjellvåg, P. Novák

J. Power Sources 297, 276-282 (2015).

DOI: 10.1016/j.jpowsour.2015.07.082OG-5410 , OG-5411
 

Imaging phosphoric acid migration in high temperature polymer electrolyte fuel cells by X-ray tomographic microscopy S.H. Eberhardt, F. Marone, M. Stampanoni, F.N. Büchi, T.J. Schmidt

ECS Trans. 69 (17), 591-599 (2015).

DOI: 10.1149/06917.0591ecstOG-5420
 

When size matters: Active Area dependence of PEFC cold start capability J. Biesdorf, P. Stahl, M. Siegwart, T.J. Schmidt, P. Boillat

J. Electrochem. Soc., 162 (10), F1231-F1235 (2015).

DOI: 10.1149/2.0871510jesOG-5420
 

Consequences of electrolyte degradation for the electrochemical performance of Li1+x(NiaCobMn1-a-b)1-xO2 H.-J. Peng, S. Urbonaite, C. Villevieille, H. Wolf, K. Leitner, P. Novák

J. Electrochem. Soc., 162 (13), A7072-A7077 (2015).

DOI: 10.1149/2.0061513jesOG-5410 , OG-5411 , OG-5413
 

A low-temperature benzyl alcohol/Benzyl mercaptan synthesis of iron oxysulfide/iron oxide composite materials for electrodes in Li-ion batteries S. Sallard, E. Castel, C. Villevieille, P. Novák

J. Mater. Chem. A 3, 16112 (2015).

DOI: 10.1039/c5ta03155aOG-5410 , OG-5411
 

_In situ_ X-ray diffraction characterisation of Fe0.5TiOPO4 and Cu0.5TiOPO4 as electrode material for sodium-ion batteries P. Bleith, H. Kaiser, P. Novák, C. Villevieille

Electrochim. Acta 176, 18–21 (2015).

DOI: 10.1016/j.electacta.2015.06.105OG-5410 , OG-5411
 

Investigation of the liquid water distributions in a 50 cm(2) PEM fuel cell: Effects of reactants relative humidity, current density, and cathode stoichiometry A. Iranzo, P. Boillat, J. Biesdorf, A. Salva

J. Energy 82, 914-921 (2015).

DOI: 10.1016/j.energy.2015.01.101OG-5420
 

Thermodynamic explanation of the universal correlation between oxygen evolution activity and corrosion of oxide catalysts T. Binninger, R. Mohamed, K. Waltar, E. Fabbri, P. Levecque, R. Kötz, T.J. Schmidt

Sci. Rep. 5, 12167 (2015).

DOI: 10.1038/ srep12167OG-5423
 

Structural changes and microstrain generated on LiNi0.80Co0.15Al0.05O2 during cycling: Effects on the electrochemical performance R. Robert, P. Novák

J. Electrochem. Soc. 162 (9), A1823-A1828 (2015).

DOI: 10.1149/2.0721509jesOG-5410 , OG-5414
 

Electrochemical study of Si/C composites with particulate and fibrous morphology as negative electrodes for lithium-ion batteries J.L. Gómez-Cámer, H. Thuv, P. Novák

J. Power Sources 294, 128–135 (2015).

DOI: 10.1016/j.jpowsour.2015.06.067OG-5410 , OG-5413
 

Reversible Li-intercalation through oxygen reactivity in Li-rich Li-Fe-Te oxide materials E. McCalla, A.S. Prakash, E. Berg, M. Saubanère, A.M. Abakumov, D. Foix, B. Klobes, M.-T. Sougrati, G. Rousse, F. Lepoivre, S. Mariyappan, D. Foix, B. Klobes, M.-T. Sougrati, G. Rousse, F. Lepoivre, S. Mariyappan, M.-L. Doublet, D. Gonbeau, P. Novak, G. Van Tendeloo, R.P. Hermann, J.-M. Tarascon

J. Electrochem. Soc. 162 (7), A1341-A1351 (2015).

DOI: 10.1149/2.0991507jesOG-5410 , OG-5412
 

Influence of graphite edge crystallographic orientation on the first lithium intercalation in Li-ion battery Ph. Bernardo, J.-M. Le Meins, L. Vidal, J. Dentzer, R. Gadiou, W. Märkle, P. Novák, M.E. Spahr, C. Vix-Guterl

Carbon 91, 458–467 (2015).

DOI: 10.1016/j.carbon.2015.05.001OG-5410 , OG-5413
 

Understanding inhomogeneous reactions in li-ion batteries: Operando synchrotron X-Ray diffraction on two-layer electrodes T. Sasaki, C. Villevieille, Y. Takeuchi, P. Novák

Adv. Sci. 1500083 (2015).

DOI: 10.1002/advs.201500083OG-5410 , OG-5411
 

Understanding the roles of anionic redox and oxygen release during electrochemical cycling of lithium-rich layered Li4FeSbO6 E. McCalla, M.T. Sougrati, G. Rousse, E. Jämstorp Berg, A. Abakumov, N. Recham, K. Ramesha, M. Sathiya, R. Dominko, G. Van Tendeloo, P. Novák, J.-M. Tarascon

J. Am. Chem. Soc. 137 (14), 4804–4814 (2015).

DOI: 10.1021/jacs.5b01424OG-5410 , OG-5412
 

Progress towards commercially viable Li-S battery cells S. Urbonaite, T. Poux, P. Novák

Adv. Energy Mater. 1500118 (2015).

DOI: 10.1002/aenm.201500118OG-5410 , OG-5413
 

Surface/Interface study on full xLi2MnO3{middle dot}(1 - x)LiMO2 (M = Ni, Mn, Co)/graphite cells L. Boulet-Roblin, M. El Kazzi, P. Novák, C. Villevieille

J. Electrochem. Soc. 162, 7, A1297-A1300 (2015).

DOI: 10.1149/2.0491507jesOG-5410 , OG-5411 , OG-5414
 

High-resolution and large-area nanoparticle arrays using EUV interference lithography K. Waiz, S.A. Tschupp, M. Oezaslan, T.J. Schmidt, J. Gobrecht, J.A. van Bokhoven, Y. Ekinci

Nanoscale, 7, 7386-7393 (2015).

DOI: 10.1039/c5nr00565eOG-5423
 

Water distribution analysis in the outer perimeter region of technical PEFC based on neutron radiography P. Stahl, J. Biesdorf, P. Boillat, J. Kraft, K.A. Friedrich

J. Electrochem. Soc. 162, 7, F677-F685 (2015).

DOI: 10.1149/2.0351507jesOG-5420
 

Electrocatalysis of perovskites: The influence of carbon on the oxygen evolution activity R. Mohamed, X. Cheng, E. Fabbri, P. Levecque, R. Kötz, O. Conrad, T.J. Schmidt

J. Electrochem. Soc. 162, 6, F579-F586 (2015).

DOI: 10.1149/2.0861506jesOG-5423
 

From electrochemical interface to interphase (2D->3D) on ionomer membranes Y. Buchmüller, R. Hafner, A. Wokaun, T.J. Schmidt, L. Gubler

ChemElectroChem 2, 338–342 (2015).

DOI: 10.1002/celc.201402332OG-5421
 

Understanding the interaction of the carbonates and binder in Na-Ion batteries: A combined bulk and surface study L.O. Vogt, M. El Kazzi, E. Jämstorp Berg, S. Pérez Villar, P. Novák, C. Villevieille

Chem. Mater. 27, 1210-1216 (2015).

DOI: 10.1021/cm5039649OG-5410 , OG-5411 , OG-5412 , OG-5414
 

Simultaneous in situ x‑ray absorption spectroscopy and x‑ray diffraction studies on battery materials: The case of Fe0.5TiOPO4 P. Bleith, W. van Beek, H. Kaiser, P. Novák, C. Villevieille

J. Phys. Chem. C 119, 3466-3471 (2015).

DOI: 10.1021/jp511042xOG-5410 , OG-5411
 

Influence of conversion material morphology on electrochemistry studied with operando x-ray tomography and diffraction C. Villevieille, M. Ebner, J.L. Gómez-Cámer, F. Marone, P. Novák, V. Wood

Adv. Mater. 27, 1676-1681 (2015).

DOI: 10.1002/adma.201403792OG-5410 , OG-5411 , OG-5413
 

Particle-Support interferences in small-angle x-ray scattering from supported-catalyst materials T. Binninger, M. Garganourakis, J. Han, A. Patru, E. Fabbri, O. Sereda, R. Kötz, A. Menzel, T.J. Schmidt

Phys. Rev. Applied 3, 024012 (2015).

DOI: 10.1103/PhysRevApplied.3.024012OG-5423
 

Noble metal aerogels-synthesis, characterization, and application as electrocatalysts W. Liu, A.K. Herrmann, N.C. Bigall, P. Rodriguez, D. Wen, M. Oezaslan, T.J. Schmidt, N. Gaponik, A. Eychmüller

Acc. Chem. Res. 48, 154-162 (2015).

DOI: 10.1021/ar500237cOG-5423
 

_In situ_ gas analysis of Li4Ti5O12 based electrodes at elevated temperatures M. He, E. Castel, A. Laumann, G. Nuspl, P. Novák, E.J. Berg

J. Electrochem. Soc. 162, 6, A870-A876 (2015).

DOI: 10.1149/2.0311506jes]OG-5410 , OG-5411 , OG-5412
 

Activation mechanism of LiNi0.80Co0.15Al0.05O2: Surface and bulk operando electrochemical, differential electrochemical mass spectrometry, and X‑ray diffraction analyses R. Robert, Ch. Bünzli, E.J. Berg, P. Novák

Chem. Mater. 27, 526−536 (2015).

DOI: 10.1021/cm503833bOG-5410 , OG-5412 , OG-5413 , OG-5414
 

Towards a stable organic electrolyte for the Lithium oxygen battery B.D. Adams, R. Black, Z. Williams, R. Fernandes, M. Cuisinier, E. Jaemstorp Berg, P. Novák, G.K. Murphy, L.F. Nazar

Adv. Energy Mater. 5, 1400867 (2015).

DOI: 10.1002/aenm.201400867OG-5410 , OG-5412
 

MoS2 coating on MoO3 nanobelts: A novel approach for a high specific charge electrode for rechargeable Li-ion batteries C. Villevieille, X.-J. Wang, F. Krumeich, R. Nesper, P. Novák

J. Power Sources 279, 636-644 (2015).

DOI: 10.1016/j.jpowsour.2014.12.129OG-5410 , OG-5411
 

Methyl phosphate formation as a major degradation mode of direct methanol fuel cells with phosphoric acid based electrolytes D. Aili, A. Vasiliev, J.O. Jensen, T.J. Schmidt, Q. Li

J. Power Sources 279, 517-521 (2015).

DOI: 10.1016/j.jpowsour.2015.01.010OG-5423
 

Dynamic operation of HT-PEFC: In-operando imaging of phosphoric acid profiles and (Re)distribution S.H. Eberhardt, M. Toulec, F. Marone, M. Stampanoni, F.N. Büchi, T.J. Schmidt

J. Electrochem. Soc. 162, 3, F310-F316 (2015).

DOI: 10.1149/2.0751503jesOG-5422
 

Think Different! Carbon corrosion mitigation strategy in high temperature PEFC: A rapid aging study T. Engl, L. Gubler, T.J. Schmidt

J. Electrochem. Soc. 162, 3, F291-F297 (2015).

DOI: 10.1149/2.0681503jesOG-5421
 

MSnS2 (M = Cu, Fe) electrode family as dual-performance electrodes for Li–S and Li–Ion batteries C. Villevieille, P. Novák

J. Electrochem. Soc. 162, 3, A284-A287 (2015).

DOI: 10.1149/2.0121503jesOG-5410 , OG-5411
 

Important aspects for reliable electrochemical impedance spectroscopy measurements of Li-Ion battery electrodes Ch. Bünzli, H. Kaiser, P. Novák

J. Electrochem. Soc. 162, 1, A218-A222 (2015).

DOI: 10.1149/2.1061501jesOG-5410 , OG-5413
 

Polyacrylate bound TiSb2 electrodes for Li-ion batteries J.L. Gómez-Cámer, P. Novák

J. Power Sources 273, 174–179 (2015)..

DOI: 10.1016/j.jpowsour.2014.09.087OG-5410 , OG-5413
 

One-pot polyol synthesis of Pt/CeO2 and Au/CeO2 nanopowders as catalysts for CO oxidation F. Pilger, A. Testino, M.A. Lucchini, A. Kambolis, M. Tarik, M. El Kazzi, Y. Arroyo, M.D. Rossell, Ch. Ludwig

J. Nanoscience and Nanotechnology 15, 5 (10), 3530-3539 (2015).

DOI: 10.1166/jnn.2015.9861OG-5410 , OG-5414
 

Oxygen Evolution Reaction on La1-xSrxCoO3 Perovskites: A Combined Experimental and Theoretical Study of Their Structural, Electronic, and Electrochemical Properties X. Cheng, E. Fabbri, M. Nachtegaal, I. Castelli, M. El Kazzi, R. Haumont, N. Marzari, T.J. Schmidt

Chem. Mater. 27, 7662-7672 (2015).

DOI: 10.1021/acs.chemmater.5b03138OG-5414 , OG-5423
 

Silicone Nanofilament Supported Nickel Oxide: A New Concept for Oxygen Evolution Catalysts in Water Electrolyzers G.R. Meseck, E. Fabbri, T.J. Schmidt, S. Seeger

Adv. Mater. Interfaces 2, 1500216/1-1500216/5 (2015).

DOI: 10.1002/admi.201500216OG-5423