Dr. Patrick Hemberger
Beamline scientist and principal investigator
5232 Villigen PSI
I am happy to announce that I will be receiving the Ruzicka Prize in Chemistry from the Department of Chemistry and Applied Biosciences at ETH. You are all cordially invited to join the ceremony and my lecture about "How can we capture reactive and elusive intermediates in catalysis to unveil reaction mechanisms?"
Tuesday, November 24 at 5pm https://video.ethz.ch/live/events/ruzicka.html
Patrick Hemberger is currently principal investigator and beamline scientist at the VUV (x04db) beamline at the Swiss Light Source. He graduated in chemistry from University of Würzburg (Germany) in 09/2008 and received his PhD in physical chemistry in 06/2011. Patrick was awarded a Mercator Fellowship from the German Science Foundation (DFG) and has co-authored more than 100 publications in peer-reviewed journals. He is lecturer and local organizer of the Hercules School (2020-2022) in the field of Synchrotron Radiation and supervises PhD students and postdocs. Besides peer-reviewing activities for different journals and funding agencies he is a member of the Proposal Review Panel at Elettra Synchrotron, Trieste (Italy).
At PSI he is responsible for further developing and application of the technologies at the vacuum ultraviolet beamline for chemical reaction dynamics research. This includes development of sources for the generation of elusive and reactive intermediates (free radicals). With the ultimate goal to elucidate reaction mechanism in reactive flows, Patrick refines the instrumentation at the VUV beamline (spectrometers & sampling environment) to enable combination with novel reactors. He is heading the user chemistry laboratory at the Swiss Light Source, successfully applies for funding and is supervising PhD students and users.
Patrick’s research interests are elucidating reaction mechanisms in reactive environments in all states, phases and time-scales. To unveil these insights, Patrick applies and develops methods to probe elusive and reactive molecules isomer-selectively utilizing vacuum ultraviolet synchrotron radiation, ultrafast lasers, photoelectron spectroscopy and mass spectrometric techniques. Currently he is principal investigator in two projects with the goal to elucidate reaction mechanisms at interfaces including heterogenic catalytic processes as well as in processes involving the liquid phase. Besides projects with VUV synchrotron radiation, Patrick also applies time-resolved photoelectron spectroscopy and mass spectrometry to study the femtochemistry of free radicals.
Isomer-Selective Threshold Photoelectron Spectra of Phenylnitrene and Its Thermal Rearrangement Products
Photoionization of triplet phenylnitrene was studied by photoion mass-selected threshold photoelectron spectroscopy (TPES) in the gas phase using vacuum UV synchrotron radiation. The doublet and quartet spin states of the radical cation are probed with TPES, and the three isomeric cyanocyclopentadienes are detected, solving the puzzle of the thermal rearrangement of phenylnitrene.
E. Mendez-Vega, W. Sander*, P. Hemberger* J. Phys. Chem. A 2020, 124, 19, 3836-3843.
Operando spectroscopy techniques can distinguish surface and gas‐phase processes in alkane oxyhalogenation. In their Communication on page 5877, J. Pérez‐Ramírez et al. unravel the mechanistic origin of the halogen effect steering catalysis. Selective alkane conversion into olefins is driven by surface‐confined chlorine. A colony of bats depicts the unselective gas‐phase radical‐chain mechanism with bromine. An angel views the selectivity control on earth.
G. Zichittella, M. Scharfe, B. Puértolas, V. Paunović, P. Hemberger, A. Bodi, L. Szentmiklósi, N. López, J. Pérez‐Ramírez, Angew.Chem. Int.Ed. 2019, 58,5877 –5881.
New analytical tools for advanced mechanistic studies in catalysis: photoionization and photoelectron photoion coincidence spectroscopy
How can we detect reactive and elusive intermediates in catalysis to unveil reaction mechanisms? In this mini review, we discuss novel photoionization tools to support this quest.
P. Hemberger*, J. A. van Bokhoven, J. Pérez-Ramírez, A. Bodi Catal. Sci. Technol., 2020,10, 1975-1990.
The resonantly stabilized xylyl radicals (C8H9•) distinctively influence the combustion chemistry and, therefore, ultimately determine the performance of combustion engines. At that, the three different isomers (methyl group in ortho, para or meta position) exhibit notable differences at elevated temperatures. We have tracked down these dynamics on a femtosecond timescale by monitoring the response to preparation of a well-defined electronic and vibrational state.
M. Steglich, G. Knopp, P. Hemberger*, Phys. Chem. Chem. Phys., 2019,21, 581-588
Metamorphic meta isomer: carbon dioxide and ketenes are formed via retro-Diels–Alder reactions in the decomposition of meta-benzenediol
Deoxygenation of the lignin model compound resorcinol was investigated using VUV synchrotron radiation: Formation of two reactive ketenes and decarboxylation are the dominating pathways, much different from the other two benzenediol isomers.
M. Gerlach, A. Bodi, P. Hemberger*, Phys. Chem. Chem. Phys., 2019,21, 19480-19487.
Awards and Grants
- 2018/10: Cross Proposal: "Detecting reactive intermediates to understand the hydrothermal depolymerization mechanism of lignin", 540 kCHF
- 2018/04: SNSF Grant: "Disentangling the Reaction Mechanism in Catalytic Fast Pyrolysis of Lignin by Detecting Reactive Intermediates", 282 kCHF
- 2017: Poster Prize (Runner up) SCS Fall Meeting 2017 (Category: Catalysis Science & Engineering): "Understanding Reaction Mechanisms in Heterogeneously Catalyzed Reactions: The Case of Catalytic Fast Pyrolysis" link
- 2015: Grant: Swiss Federal Office of Energy (SFOE) Grant: "Disentangling soot formation processes applying VUV synchrotron radiation and ultrafast laser spectroscopy" 320 kCHF
- 2015: Mercator Fellow of the German Science Foundation "PEPICO in der Flammenforschung"
- 2012: SYN Budget Proposal for 2013, 100 kCHF
- 2008: Poster Prize Chem-SyStM 2008
- Swiss Chemical Society SCS
- German Bunsen Society for Physical Chemistry
- German Chemical Society GDCh