Scientific Highlights NES

Heterogeneous and combined hetero/homogeneous chemical processes have attracted increased attention in many energy conversion systems, which include large scale power generation, microreactors for portable power generation, household burners, fuel processing technologies and automotive exhaust gas aftertreatment. Progress in such systems crucially depends on the development of catalysts with enhanced activity and thermal stability and on the comprehensive understanding of the fundamental processes occurring near gas solid reacting interfaces.

MSR research at LSM has 3 main justifications:

1. education purpose (2 PhD & 8 MSc internal students, 3 PhD & 4 other guests)

2. technology monitoring (it is the most revolutionary GIV system)

3. novel research topics (liquid phase of the fuel introduces many challenges)

Two major research objectives in NES:

1. safety: evaluate system behavior in nominal and transient conditions (tight multi‐physics coupling / H2020 SAMOFAR project)

2. sustainability: evaluate if the concept can use legacy nuclear waste as initial fuel, insure a high resource utilization (high burning)

Spent fuel management is becoming one of the major concerns in many countries with a nuclear program. The radiation aspect as well as the safe and economical part of the long-term storage of the spent nuclear fuel has to be evaluated with a high degree of confidence. To assist such project from the neutronic simulation side, a new method is proposed to systematically calculate at the same time canister loading curves and radiation sources, based on the inventory information from an in-core fuel management system.

Two-dimensional magnetic systems with continuous spin degrees of freedom exhibit a rich spectrum of thermal behaviour due to the strong competition between fluctuations and correlations. When such systems incorporate coupling via the anisotropic dipolar interaction, a discrete symmetry emerges, which can be spontaneously broken leading to a low-temperature ordered phase.

Knowledge about the cross sections data of the target materials used for spallation neutron facilities (SNF) and accelerator driven systems (ADS) is essential for the licensing, safe operation and decommissioning of these facilities. In addition, these data are important to evaluate and improve the existing computer simulation codes. Especially the α-emitter ¹⁴⁸Gd has a large contribution to radio-toxicity of spallation target facilities with its 74.6 years of half-life.

The characteristics of low energy electrons accelerated by a laser wakefield (Laser Wakefield Acceleration LWFA) has been studied. The work included understanding the acceleration process, setting up the experiment and measuring properties like charge, divergence and energy of the accelerated electrons. The experiment included diagnostics for the laser and the electrons. In order to make high-resolution energy distribution measurements with relative errors ∆E/E of below 10%, a tunable electron spectrometer has been designed, built and characterized. A tunable permanent magnet quadrupole triplet has been designed for stigmatic focusing in a range of 5 keV to 5 MeV.

Global sensitivity analysis (GSA) is routinely applied in engineering to determine the sensitivity of a simulation output to the input parameters. Typically, GSA methods require the code output to be a scalar. In the context of thermal-hydraulic system code, however, simulation outputs are often not scalar but time-dependent (e.g. temperature profile). How to perform GSA on these outputs?

The Accident at the Fukushima Daiichi Nuclear Power Station, which occurred in March 2011, had a very strong impact on the nuclear community. Three reactors suffered core damage and fission products were released to the environment. Paul Scherrer Institute (PSI) has participated in an Organisation for Economic Cooperation and Development (OECD) project, Benchmark Study of the Accident at the Fukushima (BSAF). The project aimed to evaluate and analyse the accident progression, likely end-state of the reactor core after the accidents, and the release of radioactivity to the environment. PSI has concentrated on the analysis of unit 3 using MELCOR 2.1. Hundreds of calculations have been performed and a plausible scenario which predicted remarkably well the main signatures has been selected.

Hydrogen is at the source of degradation mechanisms affecting mechanical properties of many structural metal materials. In nuclear power plants, zirconium alloy fuel cladding tubes take up a part of the hydrogen from coolant water due to oxidation. Because of the high mobility of hydrogen interstitial atoms down temperature and concentration gradients and up stress gradients, hydrogen distribution in fuel claddings can often be non-uniform, arising the risk for the integrity of spent fuel rods under mechanical load. At the Laboratory of Nuclear Materials (LNM) in collaboration with the Laboratory of Neutron Scattering and Imaging (LNS), hydrogen redistribution in zirconium alloys was quantified by neutron radiography using the state-of-the-art detector of PSI Neutron Microscope, and the concentration was computed based on thermodynamics, to predict hydrogen diffusion and precipitation for used nuclear fuel.

Die Untersuchung von Kernbrennstoff bei sehr hohem Abbrand ist entscheidend für die Bewertung der Sicherheitsmarge des untersuchten Brennstoffs sowohl unter normalen als auch unter Unfallbedingungen. Das PSI ist eines der wenigen heißen Labore, die Zugang zu bestrahltem UO₂-Brennstoff mit sehr hohem Abbrand aus kommerziellen Reaktoren haben. Der Einsatz relevanter Werkzeuge zur Untersuchung, Handhabung und Analyse dieser hoch bestrahlten Materialien unterstreicht die erforderliche Expertise.

Die Implementierung von fokussierten Ionenstrahl-(FIB)-Instrumenten in Materialforschungslaboren im letzten Jahrzehnt hat nicht nur die Präparation sehr dünner Proben für das Transmissionselektronenmikroskop (TEM), insbesondere an Grenzflächen, erheblich verbessert, sondern auch zur Entwicklung neuer Analysemethoden direkt im Instrument selbst geführt. Es hat sich zu einem leistungsstarken Instrument für die Analyse hochradioaktiver Materialien entwickelt, da es die Herstellung und Untersuchung sehr kleiner Proben ermöglicht, die anschließend mit hochsensiblen Detektoren analysiert werden können, ohne dass es zu starken Störungen durch das Strahlungsfeld der Probe selbst kommt.

Noise appears in many areas of science, and commonly has an unwanted and disturbing nature by deteriorating signals’ quality. Therefore, various techniques have been developed over the years for separating noise from pure signals. However, noise has a key role in signal analysis of nuclear reactors as its’ appropriate assessment can be used not only for exploring the normal and dynamic behaviour of nuclear cores, but also for identifying and detecting possible anomalies of reactor systems. State of the art methods have been recently implemented within the well-established signal analysis methodology of the STARS program, at the Laboratory for Reactor Physics and Thermal-Hydraulics (LRT), for investigating nuclear reactor noise and getting a better insight on analysing reactors’ operation.

The formation and growth of cracks by stress corrosion cracking (SCC)in reactor internals and recirculation pipes due to the highly oxidising environment is a serious issue in boiling water reactors. At first, SCC mitigation was attempted by injecting H₂ into the feed water, where the injected H₂ recombines with the H₂O₂ and O₂ to water and reduces the electrochemical corrosion potential, and consequently the SCC susceptibility. Several disadvantages of the injection of high amounts of H₂, have led to the development of noble metal additions to the reactor feed water. With injection of a much smaller amount of H₂, the noble metal particles of a few nanometres in size, formed in-situ, work as catalysts for the efficient reduction of the oxidizing species formed by radiolysis, and thus lower the ECP and SCC susceptibility.

The credibility of long-term safety assessments of radioactive waste repositories may be greatly enhanced by a molecular level understanding of the sorption processes onto individual minerals present in the near- and far-fields. A study conducted at LES in collaboration with the Helmholtz Zentrum Dresden Rossendorf used extended X-ray absorption fine structure (EXAFS) and time-resolved laser fluorescence spectroscopies (TRLFS) to elucidate the uptake mechanism of trivalent lanthanides and actinides (Ln/An^III) by the clay mineral montmorillonite.The excellent agreement between the thermodynamic model parameters obtained by fitting the macroscopic data, and the spectroscopically identified mechanisms, demonstrates the mature state of the 2SPNE SC/CE sorption model developed at LES for predicting and quantifying the retention of Ln/An^III elements by montmorillonite-rich clay rocks.

BKW’s Engineering Division and the Paul Scherrer Institute (PSI) joined forces to provide risk and safety analysis services in the nuclear sector. By combining their expertise, the two companies are able to solve highly complex problems in the field of nuclear safety. The range of joint services is aimed at customers from the power plant sector and supply industry, as well as public and state institutions. The collaboration will focus exclusively on the international (non-Swiss) market.

Nuclear reactor dynamics deals with the transient behaviour of nuclear reactors which mostly refers to time changes of the imbalance between heat production and removal. Since the prediction of the dynamic behaviour is crucial for the safety of a reactor, computational models and methodologies have been developed in the framework of the STARS project, at the Laboratory for Reactor Physics and Thermal-Hydraulics (LRT), with the main goal to simulate the complex behaviours of reactors under various conditions with a high level of fidelity.

One of the long-lasting unsolved problems in Nuclear Astrophysics is the so-called "Cosmological Li Problem", i.e. the large discrepancy between the primordial ⁷Li abundance predicted by models of Big Bang Nucleosynthesis and the one inferred from astronomical observation. The study of the production/destruction rates of the radioactive precursor ⁷Be is one of the clues for solving this problem.

Researcher at PSI (NES/LRT) have brought modern infrared technologies into their large thermal-hydraulic facility, called LINX, to obtain insights into condensation/evaporation process occurring under thermodynamic conditions resembling those of a nuclear power plant containment during a severe accident scenario. In such a scenario, condensation is of prime importance to control the thermodynamic state of the containment. It affects the pressure history, the overall gas (steam, hydrogen) and fission product distribution within this last barrier. Better understanding of these phenomena under accident conditions is essential to properly predict the accident evolution.

An interdisciplinary study conducted at different PSI laboratories (LES, AHL, LRS, SYN) in collaboration with Studsvik AB (Sweden) demonstrates that selenium originating from fission in light water reactors is tightly bound in the crystal lattice of UO₂. This finding has positive consequences for the safety assessment of high-level radioactive waste repository planned in Switzerland, as it implies (contrary to previous assumptions) that the safety-relevant radionuclide ⁷⁹Se will be released at extremely low rates during aqueous corrosion of the waste in a deep-seated repository.