Scientific Highlights
Dosing Differential Electrochemical Mass Spectrometry (D-DEMS) for Li-O2 Batteries
The high-energy rechargeable Li-O2 battery has been subject to intensive research worldwide during the past years. The Li-O2 cell mainly comprises a negative (e.g. Li metal) and positive (e.g. porous carbon) electrode separated by an electronically insulating, but Li+ conducting electrolyte layer. In order to study the cell chemistry, a differential electrochemical mass spectrometry setup based on a set of valves, a pressure sensor and a quadrupole mass spectrometer has been developed.
RF Pulse compressor for the SwissFEL
The SwissFEL C-band (5.712 GHz) linac consists of 26 RF modules. Each module is composed of a single 50 MW klystron feeding a pulse compressor and four two meter long accelerating structures. The pulse compressor is a passive device that compresses in time the 3 μs pulse from klystron into a 330 ns pulse. The compressed power is then guided to the four accelerating structures. The pulse compressor is based on a single Barrel Open Cavity (BOC). The BOC makes use of a “whispering gallery” mode which has an intrinsically high quality factor and operates in resonant rotating wave regime (Figure 1); moreover, and contrary to the conventional SLED scheme, a single cavity is sufficient to define the pulse compressor, without the need for two cavities. A prototype has been manufactured by the Dutch company VDL (Figure 2) and successfully power tested in PSI reaching a peak power of 300 MW.
MEGAPIE samples delivered to partners for post irradiation investigation
The MEGAWatt Pilot Experiment was operated for neutron generation with the PSI high intensity proton beam in 2006. The experiment utilized liquid target material, a lead bismuth eutectic. This marked a major milestone towards Accelerator Driven Systems (ADS), which are intended to be used for the incineration of nuclear waste.
Tiny Magnets as a Model System
Scientists use nano-rods to investigate how matter assembles
In the microscopic world, everything is in motion: atoms and molecules vibrate, proteins fold, even glass is a slow flowing liquid. And during each movement there are interactions between the smallest elements - for example, the atoms - and their neighbours. To make these movements visible, scientists at the Paul Scherrer Institute PSI have developed a special model system.
Atomic motions untangled
The pursuit of capturing motion in a movie bears an obvious fascination irrespective of the time scales involved. In the atomic and molecular world where the masses are so light and the distances small the relevant time scale shifts to the ubpicosecond range and the motions become frantic especially for larger molecular systems
Atomic motions untangled
The pursuit of capturing motion in a movie bears an obvious fascination irrespective of the time scales involved. In the atomic and molecular world where the masses are so light and the distances small the relevant time scale shifts to the subpicosecond range and the motions become frantic especially for larger molecular systems.
Effect of surface charge density on the affinity of oxide nanoparticles for the vapor–water interface
Using in-situ X-ray photoelectron spectroscopy at the vapor-water interface, the affinity of nanometer-sized silica colloids to adsorb at the interface is shown to depend on colloid surface charge density. In aqueous suspensions at pH 10 corrected Debye-Hückel theory for surface complexation calculations predict that smaller silica colloids have increased negative surface charge density that originates from enhanced screening of deprotonated silanol groups by counterions in the condensed ion layer.
Radiation grafted membranes developed at PSI outlast state-of-the art commercial membranes in the fuel cell
Components for the polymer electrolyte fuel cell (PEFC) are required to show high performance and durability under application relevant conditions. Furthermore, for commercial viability the materials and processes for component fabrication need to be of los cost. The polymer electrolyte membrane developed at PSI on the basis of the radiation grafting technique has the potential of being produced in cost-effective manner. In recent years, we have collaborated with the Belenos Clean Power to further develop the membrane to commercial competitiveness.
On Proton Conductivity in Porous and Dense Yttria Stabilized Zirconia at Low Temperature
The electrical conductivity of dense and nanoporous zirconia-based thin films is compared to results obtained on bulk yttria stabilized zirconia (YSZ) ceramics. Different thin film preparation methods are used in order to vary grain size, grain shape, and porosity of the thin films. In porous films, a rather high conductivity is found at room temperature which decreases with increasing temperature to 120 °C. This conductivity is attributed to proton conduction along physisorbed water (Grotthuss mechanism) at the inner surfaces.
Applications of laser printing for organic electronics
The development of organic electronic requires a non contact digital printing process. The European funded e-LIFT project investigated the possibility of using the Laser Induced Forward Transfer (LIFT) technique to address this field of applications. This process has been optimized for the deposition of functional organic and inorganic materials in liquid and solid phase, and a set of polymer dynamic release layer (DRL) has been developed to allow a safe transfer of a large range of thin films.