Scientific Highlights
Johannes Ihli and co-researchers made it into Nature Communications
Nature Communications will be publishing the paper of Johannes Ihli et al., "A three-dimensional view of structural changes caused by deactivation of fluid catalytic cracking catalysts", in issue 8, article number 809. The paper has already gone online on October 9, 2017.
Tracking the Chemical Transformations at a Zeolite Brønsted Acid Site with Al K-edge XANES
Al T-sites are of crucial importance for the function of zeolite catalysts. These T-sites, which serve as Brønsted acid reaction centers, interact strongly with water. The location of these T-sites and their chemical state in the presence of water were elucidated using x-ray absorption spectroscopy (XAS) at the PHOENIX beamline at the Swiss Light Source of the PSI.
Pt nanoparticles: The key to improved stress corrosion cracking mitigation in boiling water reactors
The formation and growth of cracks by stress corrosion cracking (SCC)in reactor internals and recirculation pipes due to the highly oxidising environment is a serious issue in boiling water reactors. At first, SCC mitigation was attempted by injecting H2 into the feed water, where the injected H2 recombines with the H2O2 and O2 to water and reduces the electrochemical corrosion potential, and consequently the SCC susceptibility. Several disadvantages of the injection of high amounts of H2, have led to the development of noble metal additions to the reactor feed water. With injection of a much smaller amount of H2, the noble metal particles of a few nanometres in size, formed in-situ, work as catalysts for the efficient reduction of the oxidizing species formed by radiolysis, and thus lower the ECP and SCC susceptibility.
Best publication
A team of GFA and CPT physicists has worked out a novel achromatic beam optics concept for a proton therapy gantry. The article on the concept in the journal Zeitschrift für Medizinische Physik has been awarded a prize for the best publication in 2016. The jury states: „The paper of Alexander Gerbershagen et al. entitled „A novel beam optics concept in a particle therapy gantry utilizing the advantages of superconducting magnets” describes a new concept of a first order design of the beam optics of a superconducting proton therapy gantry beam. The jury was impressed by the well-structured experimental work with clear improvement of large momentum acceptance in the gantry which opens the possibility of implementation new and faster dose application techniques in proton therapy.”
Light from the particle accelerator helps to understand ozone decomposition
PSI researchers have developed an experimental chamber in which they can recreate atmospheric processes and probe them with unprecedented precision, using X-ray light from the Swiss Light Source SLS. In the initial experiments, they have studied the production of bromine, which plays an essential role in the decomposition of ozone in the lower layers of the atmosphere. In the future, the new experiment chamber will also be available for use by researchers from other scientific fields.
Coexistence of Physisorbed and Solvated HCl at Warm Ice Surfaces
The interfacial ionization of strong acids is an essential factor of multiphase and heterogeneous chemistry in environmental science, cryospheric science, catalysis research and material science. Using Near Ambient Pressure X-ray Photoelectron (NAPP) spectroscopy, we directly detected a low surface coverage of adsorbed HCl at 253 K in both molecular and dissociated states and interpret the results as physisorbed molecular HCl at the outermost ice surface and dissociation occurring upon solvation deeper in the interfacial region. This study gives clear evidence for nonuniformity across the air−ice interface and questions the use of acid−base concepts in interfacial processes.
Commissioning and first performance studies of the new CMS pixel detector
In the previous months the new CMS pixel detector was brought into operation. The detector was moved from PSI to CERN and installed in February, followed by an intensive period of commissioning and calibration. This process mostly involved the adjustment of many operational parameters which influence the detector performance, e.g.
ATHOS Conceptual Design Report (CDR)
The ATHOS Conceptual Design Report has recently been completed and describes the ATHOS project in detail. The CDR starts with a summary of the characteristics of the ATHOS undulator line. Especially the design parameters of the different ATHOS operation modes are explained and illustrated by simulation results. The core part of the report is a description of all key components, i.e. from the electron bunch extraction kicker down to the ATHOS experimental stations.Download the full report Athos CDR .
ATHOS Conceptual Design Report (CDR)
The ATHOS Conceptual Design Report has recently been completed and describes the ATHOS project in detail. The CDR starts with a summary of the characteristics of the ATHOS undulator line. Especially the design parameters of the different ATHOS operation modes are explained and illustrated by simulation results. The core part of the report is a description of all key components, i.e. from the electron bunch extraction kicker down to the ATHOS experimental stations.
Sorption of trivalent lanthanides and actinides onto montmorillonite
The credibility of long-term safety assessments of radioactive waste repositories may be greatly enhanced by a molecular level understanding of the sorption processes onto individual minerals present in the near- and far-fields. A study conducted at LES in collaboration with the Helmholtz Zentrum Dresden Rossendorf used extended X-ray absorption fine structure (EXAFS) and time-resolved laser fluorescence spectroscopies (TRLFS) to elucidate the uptake mechanism of trivalent lanthanides and actinides (Ln/AnIII) by the clay mineral montmorillonite.The excellent agreement between the thermodynamic model parameters obtained by fitting the macroscopic data, and the spectroscopically identified mechanisms, demonstrates the mature state of the 2SPNE SC/CE sorption model developed at LES for predicting and quantifying the retention of Ln/AnIII elements by montmorillonite-rich clay rocks.