Scientific Highlights
Reaction Conditions of Methane-to-Methanol Conversion Affect the Structure of Active Copper Sites
Determining the structure of the active Cu sites, which are associated with the methane conversion intermediate during stepwise, low-temperature, methane-to-methanol conversion, represents an important step for the upgrade of this reaction route to a viable process. Quick X-ray absorption spectroscopy allowed us to follow the electronic and structural changes to the active Cu sites during reaction with methane and during desorption of the activated intermediate. A large fraction (41%) of the oxygen-activated CuII reacted with methane and underwent reduction to CuI.
Bulk superconductivity in undoped T'-La1.9Y0.1CuO4 probed by muon spin rotation
The Meissner effect has been directly demonstrated by depth-resolved muon spin rotation measurements in high-quality thin films of the T'-structured cup rate, T'-La1.9Y0.1CuO4, to confirm bulk superconductivity (Tc ≈ 21 K) in its undoped state. The gradual expelling of an external magnetic field is observed over a depth range of ∼ 100 nm in films with a thickness of 275(15) nm, from which the penetration depth is deduced to be 466(22) nm. Based on this result, we argue that the true ground state of the “parent” compound of the n-type cuprates is not a Mott insulator but a strongly correlated metal with colossal sensitivity to apical oxygen impurities.
Promises of cyclotron-produced 44Sc as a diagnostic match for trivalent beta - emitters: In vitro and in vivo study of a 44Sc-DOTA-folate conjugate
Research Division Biology and Chemistry (BIO), Folate Receptor Targeting Group, Head Cristina Müller. In recent years, implementation of 68Ga-radiometalated peptides for PET imaging of cancer has attracted the attention of clinicians. Herein, we propose the use of 44Sc (half-life = 3.97 h, average β+ energy [Eβ+av] = 632 keV) as a valuable alternative to 68Ga (half-life = 68 min, Eβ+av = 830 keV) for imaging and dosimetry before 177Lu-based radionuclide therapy.
Unique insight into carbon fibers on the nanoscale
The investigation of the mechanical properties of carbon fibers benefits from highly resolved three-dimensional density maps within representative volumes, but such images are not easily obtained with standard methods. Scientists from the Paul Scherrer Institut in collaboration with Honda R&D in Germany have recently visualized density distributions on the sub-micrometer scale within entire carbon fiber sections, revealing surprising graphite distributions within the fibers. This capability will prove useful for the systematic characterization of fibers, contributing to the development of light and robust materials at lower costs.
Magnetismus im Stress: Gleichzeitiger Anti- und Ferromagnetismus
Die gleichzeitige Existenz von Magnetismus und Ferroelektrizät in einem Material ist selten. Setzt sich dieser Magnetismus aus mehreren unabhängigen, magnetischen Grundzuständen zusammen, ist das ungewöhnlich. Einer schweizerisch-französischen Zusammenarbeit unter Leitung des Paul Scherrer Instituts ist es gelungen, mehrere magnetische Grundzustände in einem Material zu realisieren und detailliert zu untersuchen.
Interface superconductor with gap behaviour like a high-temperature superconductor
The physics of the superconducting state in two-dimensional (2D) electron systems is relevant to understanding the high-transition-temperature copper oxide superconductors and for the development of future superconductors based on interface electron systems. But it is not yet understood how fundamental superconducting parameters, such as the spectral density of states, change when these superconducting electron systems are depleted of charge carriers.
Strain-Induced Ferromagnetism in Antiferromagnetic LuMnO3 Thin Films
Interfaces of transition metal oxides are a fertile ground for new physics, often showing novel electronic and magnetic properties that do not exist in the bulk form of the material. A relatively little-explored direction in this field concerns the interfacial properties of multifunctional materials such as the magnetoelectric multiferroics.
Strain-Induced Ferromagnetism in Antiferromagnetic LuMnO3 Thin Films
Single phase and strained LuMnO3 thin films are discovered to display coexisting ferromagnetic and antiferromagnetic orders. A large moment ferromagnetism (≈1μB), which is absent in bulk samples, is shown to display a magnetic moment distribution that is peaked at the highly strained substrate-film interface. We further show that the strain-induced ferromagnetism and the antiferromagnetic order are coupled via an exchange field, therefore demonstrating strained rare-earth manganite thin films as promising candidate systems for new multifunctional devices.
Single Domain Spin Manipulation by Electric Fields in Strain Coupled Artificial Multiferroic Nanostructures
Encoding information by the application of an electric field has a key role in the development of novel memory devices that can operate at high speed while keeping low energy consumption. In magnetoelectric multiferroics, magnetic and ferroelectric ordering coexist and are coupled together so that it is possible to manipulate the material's magnetic structure by applying an electric field with a negligible current flow.
1D to 2D Na+ Ion Diffusion Inherently Linked to Structural Transitions in Na0.7CoO2
We report the observation of a stepwise "melting" of the low-temperature Na-vacancy order in the layered transition-metal oxide Na0.7CoO2. High-resolution neutron powder diffraction analysis indicates the existence of two first-order structural transitions, one at T1 ≈ 290 K followed by a second at T2 ≈ 400 K. Detailed analysis strongly suggests that both transitions are linked to changes in the Na mobility.