CrystMAS Publications

  • Artsiusheuski M, Casati N, Clark A, Nachtegaal M, Verel R, van Bokhoven J, et al.
    Controlling the mechanism of nucleation and growth enables synthesis of UiO‐66 metal‐organic framework with desired macroscopic properties
    Angewandte Chemie International Edition. 2025; 64(4): e202415919 (13 pp.). https://doi.org/10.1002/anie.202415919
    DORA PSI
  • Artsiusheuski MA, Guo J, Kulkarni AR, van Bokhoven JA, Sushkevich VL
    Low-temperature nonoxidative dehydrogenation of short-chain alkanes over copper(I) mordenite via chemical looping
    Journal of the American Chemical Society. 2025; 147(18): 15880-15889. https://doi.org/10.1021/jacs.5c04229
    DORA PSI
  • Brenig A, Fischer JWA, Klose D, Jeschke G, van Bokhoven JA, Sushkevich VL
    Tracking active site formation during oxidative activation of copper‐exchanged zeolites for methane‐to‐methanol conversion
    Advanced Science. 2025; 12(13): 2413870 (13 pp.). https://doi.org/10.1002/advs.202413870
    DORA PSI
  • Leidinger PM, Panighel M, Sushkevich VL, Piseri P, Podestà A, van Bokhoven JA, et al.
    Influence of zinc oxide nanoparticles on the carbon accumulation on silver exposed to carbon dioxide hydrogenation reaction conditions
    Nanoscale. 2025; 17(5): 2608-2615. https://doi.org/10.1039/d4nr03766a
    DORA PSI
  • Toussaint V, Bachmann S, Pöppler AC, Sushkevich VL, Friedbacher G, Konegger T, et al.
    Binuclear and mononuclear active sites of porous tin-organic frameworks for selective epimerization of D-glucose into D-mannose
    Journal of Catalysis. 2025; 447: 116130 (13 pp.). https://doi.org/10.1016/j.jcat.2025.116130
    DORA PSI
  • Batool SR, Sushkevich VL, van Bokhoven JA
    Factors affecting the generation and catalytic activity of extra-framework aluminum Lewis acid sites in aluminum-exchanged zeolites
    ACS Catalysis. 2024; 14: 678-690. https://doi.org/10.1021/acscatal.3c04195
    DORA PSI
  • Brenig A, Fischer JWA, Klose D, Jeschke G, van Bokhoven JA, Sushkevich VL
    Redox and kinetic properties of composition‐dependent active sites in copper‐exchanged chabazite for direct methane‐to‐methanol oxidation
    Angewandte Chemie International Edition. 2024; 63(45): e202411662 (12 pp.). https://doi.org/10.1002/anie.202411662
    DORA PSI
  • Devos J, Sushkevich VL, Khalil I, Robijns S, de Oliveira-Silva R, Sakellariou D, et al.
    Enhancing the acidity window of zeolites by low-temperature template oxidation with ozone
    Journal of the American Chemical Society. 2024; 146(39): 27047-27059. https://doi.org/10.1021/jacs.4c08123
    DORA PSI
  • Fischer JWA, Buttignol F, Brenig A, Klose D, Ferri D, Sushkevich V, et al.
    Design principles of operando ultraviolet-visible and electron paramagnetic resonance spectroscopy setups for active site characterization in ion-exchanged zeolites
    Catalysis Today. 2024; 429: 114503 (10 pp.). https://doi.org/10.1016/j.cattod.2023.114503
    DORA PSI
  • Leidinger PM, Sushkevich VL, Pischetola C, Krumeich F, van Bokhoven JA, Artiglia L
    Influence of alumina on the performance of Ag/ZnO based catalysts for carbon dioxide hydrogenation
    Journal of Catalysis. 2024; 440: 115837 (9 pp.). https://doi.org/10.1016/j.jcat.2024.115837
    DORA PSI
  • Maggiulli L, Sushkevich VL, Kröcher O, van Bokhoven JA, Ferri D
    Correlating the nature of carbenium ions in zeolites to the product distribution in the methanol-to-olefins process
    ACS Catalysis. 2024; 14: 11477-11489. https://doi.org/10.1021/acscatal.4c03185
    DORA PSI
  • Artsiusheuski MA, Verel R, van Bokhoven JA, Sushkevich VL
    Mechanism of hydrocarbon formation in methane and methanol conversion over copper-containing mordenite
    ACS Catalysis. 2023; 13: 5864-5875. https://doi.org/10.1021/acscatal.2c06312
    DORA PSI
  • Artsiusheuski MA, Verel R, van Bokhoven JA, Sushkevich VL
    Selective oxidative dehydrogenation of ethane and propane over copper-containing mordenite: insights into reaction mechanism and product protection
    Angewandte Chemie International Edition. 2023; 62(44): e202309180 (11 pp.). https://doi.org/10.1002/anie.202309180
    DORA PSI
  • Artsiusheuski MA, Safonova O, Palagin D, van Bokhoven JA, Sushkevich VL
    Structural evolution of copper-oxo sites in zeolites upon the reaction with methane investigated by means of Cu K-edge X-ray absorption spectroscopy
    Journal of Physical Chemistry C. 2023; 127(20): 9603-9615. https://doi.org/10.1021/acs.jpcc.3c01496
    DORA PSI
  • Blankenship A, Artsiusheuski M, Sushkevich V, van Bokhoven JA
    Recent trends, current challenges and future prospects for syngas-free methane partial oxidation
    Nature Catalysis. 2023; 6(9): 748-762. https://doi.org/10.1038/s41929-023-01000-8
    DORA PSI
  • Fischer JWA, Brenig A, Klose D, van Bokhoven JA, Sushkevich VL, Jeschke G
    Methane oxidation over Cu2+/[CuOH]+ pairs and site‐specific kinetics in copper mordenite revealed by operando electron paramagnetic resonance and UV‐visible spectroscopy
    Angewandte Chemie International Edition. 2023; 62(34): e202303574 (10 pp.). https://doi.org/10.1002/anie.202303574
    DORA PSI
  • Sadykov II, Sushkevich VL, Krumeich F, Nuguid RJG, van Bokhoven JA, Nachtegaal M, et al.
    Platinum‐iron(II) oxide sites directly responsible for preferential carbon monoxide oxidation at ambient temperature: an operando X‐ray absorption spectroscopy study
    Angewandte Chemie International Edition. 2023; 62(1): e202214032 (11 pp.). https://doi.org/10.1002/anie.202214032
    DORA PSI
  • Semivrazhskaya OO, Salionov D, Clark AH, Casati NPM, Nachtegaal M, Ranocchiari M, et al.
    Deciphering the mechanism of crystallization of UiO-66 metal-organic framework
    Small. 2023; 19(52): 2305771 (11 pp.). https://doi.org/10.1002/smll.202305771
    DORA PSI
  • Yousefzadeh H, Bozbag SE, Sushkevich V, van Bokhoven JA, Erkey C
    Stepwise conversion of methane to methanol over Cu-mordenite prepared by supercritical and aqueous ion exchange routes and quantification of active Cu species by H2-TPR
    Catalysis Communications. 2023; 174: 106574 (8 pp.). https://doi.org/10.1016/j.catcom.2022.106574
    DORA PSI
  • Artsiusheuski MA, van Bokhoven JA, Sushkevich VL
    Structure of selective and nonselective dicopper (II) sites in CuMFI for methane oxidation to methanol
    ACS Catalysis. 2022; 12(24): 15626-15637. https://doi.org/10.1021/acscatal.2c05299
    DORA PSI
  • Batool SR, Sushkevich VL, van Bokhoven JA
    Correlating Lewis acid activity to extra-framework aluminum species in zeolite Y introduced by ion-exchange
    Journal of Catalysis. 2022; 408: 24-35. https://doi.org/10.1016/j.jcat.2022.02.010
    DORA PSI
  • Nuguid RJG, Ortino-Ghini L, Suskevich VL, Yang J, Lietti L, Kröcher O, et al.
    Interconversion between Lewis and Brønsted-Lowry acid sites on vanadia-based catalysts
    Physical Chemistry Chemical Physics. 2022; 24(7): 4555-4561. https://doi.org/10.1039/d1cp05261f
    DORA PSI
  • Paunović V, Sushkevich V, Rzepka P, Artiglia L, Hauert R, Lee SS, et al.
    Reactivation of catalysts for methanol-to-hydrocarbons conversion with hydrogen
    Journal of Catalysis. 2022; 407: 54-64. https://doi.org/10.1016/j.jcat.2022.01.018
    DORA PSI
  • Salionov D, Semivrazhskaya OO, Casati NPM, Ranocchiari M, Bjelić S, Verel R, et al.
    Unraveling the molecular mechanism of MIL-53(Al) crystallization
    Nature Communications. 2022; 13(1): 3762 (9 pp.). https://doi.org/10.1038/s41467-022-31294-4
    DORA PSI
  • Yakimov AV, Sushkevich VL, van Bokhoven JA, Copéret C
    Probing acid sites in MOR zeolite using low-temperature 13C solid-state NMR spectroscopy of adsorbed carbon monoxide
    Journal of Physical Chemistry C. 2022; 126(7): 3681-3687. https://doi.org/10.1021/acs.jpcc.1c10026
    DORA PSI
  • Yakimov AV, Ravi M, Verel R, Sushkevich VL, van Bokhoven JA, Copéret C
    Structure and framework association of Lewis acid sites in MOR zeolite
    Journal of the American Chemical Society. 2022; 144(23): 10377-10385. https://doi.org/10.1021/jacs.2c02212
    DORA PSI
  • Artsiusheuski MA, Verel R, van Bokhoven JA, Sushkevich VL
    Methane transformation over copper-exchanged zeolites: from partial oxidation to C-C coupling and formation of hydrocarbons
    ACS Catalysis. 2021; 11(20): 12543-12556. https://doi.org/10.1021/acscatal.1c02547
    DORA PSI
  • Artsiusheuski MA, van Bokhoven JA, Sushkevich VL
    Modeling and experiment for oxygen isotope exchange over copper-containing mordenite
    Journal of Physical Chemistry C. 2021; 125(22): 12366-12373. https://doi.org/10.1021/acs.jpcc.1c02531
    DORA PSI
  • Artsiusheuski MA, van Bokhoven JA, Sushkevich VL
    Oxygen isotope exchange over copper-containing mordenite: the effect of copper loading and Si/Al ratio
    Journal of Physical Chemistry C. 2021; 125(48): 26512-26521. https://doi.org/10.1021/acs.jpcc.1c08529
    DORA PSI
  • Kopelent R, Tereshchenko A, Guda A, Smolentsev G, Artiglia L, Sushkevich VL, et al.
    Enhanced reducibility of the ceria-tin oxide solid solution modifies the CO oxidation mechanism at the platinum-oxide interface
    ACS Catalysis. 2021; 11: 9435-9449. https://doi.org/10.1021/acscatal.1c01685
    DORA PSI
  • Li T, Beck A, Krumeich F, Artiglia L, Ghosalya MK, Roger M, et al.
    Stable palladium oxide clusters encapsulated in silicalite-1 for complete methane oxidation
    ACS Catalysis. 2021; 11(12): 7371-7382. https://doi.org/10.1021/acscatal.0c04868
    DORA PSI
  • Palagin D, Sushkevich VL, Knorpp AJ, Ranocchiari M, van Bokhoven JA
    Mapping vibrational spectra to the structures of copper species in zeolites based on calculated stretching frequencies of adsorbed nitrogen and carbon monoxides
    Journal of Physical Chemistry C. 2021; 125(22): 12094-12106. https://doi.org/10.1021/acs.jpcc.1c01649
    DORA PSI
  • Ravi M, Sushkevich VL, van Bokhoven JA
    On the location of Lewis acidic aluminum in zeolite mordenite and the role of framework-associated aluminum in mediating the switch between Brønsted and Lewis acidity
    Chemical Science. 2021; 12(11): 4094-4103. https://doi.org/10.1039/d0sc06130a
    DORA PSI
  • Sadykov II, Zabilskiy M, Clark AH, Krumeich F, Sushkevich V, van Bokhoven JA, et al.
    Time-resolved XAS provides direct evidence for oxygen activation on cationic iron in a bimetallic Pt-FeOx/Al2O3 catalyst
    ACS Catalysis. 2021; 11(18): 11793-11805. https://doi.org/10.1021/acscatal.1c02795
    DORA PSI
  • Sushkevich VL, Artsiusheuski M, Klose D, Jeschke G, van Bokhoven JA
    Identification of kinetic and spectroscopic signatures of copper sites for direct oxidation of methane to methanol
    Angewandte Chemie International Edition. 2021; 60(29): 15944-15953. https://doi.org/10.1002/anie.202101628
    DORA PSI
  • Zabilskiy M, Sushkevich VL, Newton MA, Krumeich F, Nachtegaal M, van Bokhoven JA
    Mechanistic study of carbon dioxide hydrogenation over Pd/ZnO‐based catalysts: the role of palladium‐zinc alloy in selective methanol synthesis
    Angewandte Chemie International Edition. 2021; 60(31): 17053-17059. https://doi.org/10.1002/anie.202103087
    DORA PSI
  • Jovanovic ZR, Lange J-P, Ravi M, Knorpp AJ, Sushkevich VL, Newton MA, et al.
    Oxidation of methane to methanol over Cu-exchanged zeolites: Scientia gratia scientiae or paradigm shift in natural gas valorization?
    Journal of Catalysis. 2020; 385: 238-245. https://doi.org/10.1016/j.jcat.2020.02.001
    DORA PSI
  • Newton MA, Knorpp AJ, Sushkevich VL, Palagin D, van Bokhoven JA
    Active sites and mechanisms in the direct conversion of methane to methanol using Cu in zeolitic hosts: a critical examination
    Chemical Society Reviews. 2020; 49(5): 1449-1486. https://doi.org/10.1039/C7CS00709D
    DORA PSI
  • Newton MA, Knorpp AJ, Meyet J, Stoian D, Nachtegaal M, Clark AH, et al.
    Unwanted effects of X-rays in surface grafted copper (II) organometallics and copper exchanged zeolites, how they manifest, and what can be done about them
    Physical Chemistry Chemical Physics. 2020; 22(13): 6826-6837. https://doi.org/10.1039/D0CP00402B
    DORA PSI
  • Ravi M, Sushkevich VL, van Bokhoven JA
    Towards a better understanding of Lewis acidic aluminium in zeolites
    Nature Materials. 2020; 19(10): 1047-1056. https://doi.org/10.1038/s41563-020-0751-3
    DORA PSI
  • Sushkevich VL, van Bokhoven JA
    Kinetic study and effect of water on methane oxidation to methanol over copper-exchanged mordenite
    Catalysis Science and Technology. 2020; 10(2): 382-390. https://doi.org/10.1039/c9cy01711a
    DORA PSI
  • Sushkevich VL, Verel R, van Bokhoven JA
    Pathways of methane transformation over copper‐exchanged mordenite as revealed by in situ NMR and IR spectroscopy
    Angewandte Chemie International Edition. 2020; 59(2): 910-918. https://doi.org/10.1002/anie.201912668
    DORA PSI
  • Sushkevich VL, Safonova OV, Palagin D, Newton MA, van Bokhoven JA
    Structure of copper sites in zeolites examined by Fourier and wavelet transform analysis of EXAFS
    Chemical Science. 2020; 11(20): 5299-5312. https://doi.org/10.1039/D0SC01472A
    DORA PSI
  • Zabilskiy M, Sushkevich VL, Newton MA, van Bokhoven JA
    Copper-zinc alloy-free synthesis of methanol from carbon dioxide over Cu/ZnO/faujasite
    ACS Catalysis. 2020; 10: 14240-14244. https://doi.org/10.1021/acscatal.0c03661
    DORA PSI
  • Zabilskiy M, Sushkevich VL, Palagin D, Newton MA, Krumeich F, van Bokhoven JA
    The unique interplay between copper and zinc during catalytic carbon dioxide hydrogenation to methanol
    Nature Communications. 2020; 11: 2409 (8 pp.). https://doi.org/10.1038/s41467-020-16342-1
    DORA PSI
  • Zhu J, Sushkevich VL, Knorpp AJ, Newton MA, Mizuno SCM, Wakihara T, et al.
    Cu-erionite zeolite achieves high yield in direct oxidation of methane to methanol by isothermal chemical looping
    Chemistry of Materials. 2020; 32(4): 1448-1453. https://doi.org/10.1021/acs.chemmater.9b04223
    DORA PSI
  • Artiglia L, Sushkevich VL, Palagin D, Knorpp AJ, Roy K, van Bokhoven JA
    In situ X-ray photoelectron spectroscopy detects multiple active sites involved in the selective anaerobic oxidation of methane in copper-exchanged zeolites
    ACS Catalysis. 2019; 9(8): 6728-6737. https://doi.org/10.1021/acscatal.9b01223
    DORA PSI
  • Knorpp AJ, Newton MA, Sushkevich VL, Zimmermann PP, Pinar AB, van Bokhoven JA
    The influence of zeolite morphology on the conversion of methane to methanol on copper-exchanged omega zeolite (MAZ)
    Catalysis Science and Technology. 2019; 9(11): 2806-2811. https://doi.org/10.1039/c9cy00013e
    DORA PSI
  • Lange J-P, Sushkevich VL, Knorpp AJ, van Bokhoven JA
    Methane-to-methanol via chemical looping: economic potential and guidance for future research
    Industrial and Engineering Chemistry Research. 2019; 58(20): 8674-8680. https://doi.org/10.1021/acs.iecr.9b01407
    DORA PSI
  • Palagin D, Sushkevich VL, van Bokhoven JA
    Water molecules facilitate hydrogen release in anaerobic oxidation of methane to methanol over Cu/Mordenite
    ACS Catalysis. 2019; 9(11): 10365-10374. https://doi.org/10.1021/acscatal.9b02702
    DORA PSI
  • Ravi M, Sushkevich VL, van Bokhoven JA
    Lewis acidity inherent to the framework of zeolite mordenite
    Journal of Physical Chemistry C. 2019; 123(24): 15139-15144. https://doi.org/10.1021/acs.jpcc.9b03620
    DORA PSI
  • Ravi M, Sushkevich VL, Knorpp AJ, Newton MA, Palagin D, Pinar AB, et al.
    Misconceptions and challenges in methane-to-methanol over transition-metal-exchanged zeolites
    Nature Catalysis. 2019; 2(6): 485-494. https://doi.org/10.1038/s41929-019-0273-z
    DORA PSI
  • Sushkevich VL, Smirnov AV, van Bokhoven JA
    Autoreduction of copper in zeolites: role of topology, Si/Al ratio, and copper loading
    Journal of Physical Chemistry C. 2019; 123(15): 9926-9934. https://doi.org/10.1021/acs.jpcc.9b00986
    DORA PSI
  • Sushkevich VL, van Bokhoven JA
    Methane-to-methanol: activity descriptors in copper-exchanged zeolites for the rational design of materials
    ACS Catalysis. 2019; 9(7): 6293-6304. https://doi.org/10.1021/acscatal.9b01534
    DORA PSI
  • Sushkevich VL, Kots PA, Kolyagin YG, Yakimov AV, Marikutsa AV, Ivanova II
    Origin of water-induced Brønsted acid sites in Sn-BEA zeolites
    Journal of Physical Chemistry C. 2019; 123(9): 5540-5548. https://doi.org/10.1021/acs.jpcc.8b12462
    DORA PSI
  • Tomkins P, Mansouri A, Sushkevich VL, van der Wal LI, Bozbag SE, Krumeich F, et al.
    Increasing the activity of copper exchanged mordenite in the direct isothermal conversion of methane to methanol by Pt and Pd doping
    Chemical Science. 2019; 10(1): 167-171. https://doi.org/10.1039/C8SC02795A
    DORA PSI
  • Knorpp AJ, Pinar AB, Newton MA, Sushkevich VL, van Bokhoven JA
    Copper-exchanged omega (MAZ) zeolite: copper-concentration dependent active sites and its unprecedented methane to methanol conversion
    ChemCatChem. 2018; 10(24): 5593-5596. https://doi.org/10.1002/cctc.201801809
    DORA PSI
  • Newton MA, Knorpp AJ, Pinar AB, Sushkevich VL, Palagin D, van Bokhoven JA
    On the mechanism underlying the direct conversion of methane to methanol by copper hosted in zeolites; braiding Cu K-Edge XANES and reactivity studies
    Journal of the American Chemical Society. 2018; 140(32): 10090-10093. https://doi.org/10.1021/jacs.8b05139
    DORA PSI
  • Sushkevich VL, van Bokhoven JA
    Effect of Brønsted acid sites on the direct conversion of methane into methanol over copper-exchanged mordenite
    Catalysis Science and Technology. 2018; 8(16): 4141-4150. https://doi.org/10.1039/c8cy01055b
    DORA PSI
  • Sushkevich VL, van Bokhoven JA
    Revisiting copper reduction in zeolites: the impact of autoreduction and sample synthesis procedure
    Chemical Communications. 2018; 54(54): 7447-7450. https://doi.org/10.1039/c8cc03921f
    DORA PSI
  • Sushkevich VL, Palagin D, van Bokhoven JA
    The effect of the active-site structure on the activity of copper mordenite in the aerobic and anaerobic conversion of methane into methanol
    Angewandte Chemie International Edition. 2018; 57(29): 8906-8910. https://doi.org/10.1002/anie.201802922
    DORA PSI
  • Sushkevich VL, Palagin D, Ranocchiari M, van Bokhoven JA
    Response to comment on "Selective anaerobic oxidation of methane enables direct synthesis of methanol"
    Science. 2017; 358(6360): eaan6083 (3 pp.). https://doi.org/10.1126/science.aan6083
    DORA PSI
  • Sushkevich VL, Palagin D, Ranocchiari M, van Bokhoven JA
    Selective anaerobic oxidation of methane enables direct synthesis of methanol
    Science. 2017; 356(6337): 523-527. https://doi.org/10.1126/science.aam9035
    DORA PSI
  • Sushkevich VL, Popov AG, Ivanova II
    Sulfur-33 isotope tracing of the hydrodesulfurization process: insights into the reaction mechanism, catalyst characterization and improvement
    Angewandte Chemie International Edition. 2017; 56(36): 10872-10876. https://doi.org/10.1002/anie.201704027
    DORA PSI