Scientific Highlights
Coupled multiferroic domain switching in the canted conical spin spiral system Mn2GeO4
Despite remarkable progress in developing multifunctional materials, spin-driven ferro-electrics featuring both spontaneous magnetization and electric polarization are still rare. Among such ferromagnetic ferroelectrics are conical spin spiral magnets with a simultaneous reversal of magnetization and electric polarization that is still little understood. Such materials can feature various multiferroic domains that complicates their study.
SPS Award in Applied Physics awarded to Waiz Karim
The SPS 2017 Prize in Applied Physics is awarded to former member of the van Bokhoven Group Waiz Karim for his PhD thesis entitled "Metal nanostructures and their catalytic properties using top-down nanofabrication and single particle spectroscopy" which was honored with his 1st author publication "Catalyst support effects on hydrogen spillover" by W. Karim, C. Spreafico, A. Kleibert, J. Gobrecht, J. VandeVondele, Y. Ekinci, J. A. van Bokhoven, Nature, 2017, 541, 68–71.
Isomer-Selective Generation and Spectroscopic Characterization of Biofuel Intermediates
Online combustion analysis relies heavily on spectral data to detect reactive intermediates isomer-selectively to establish e.g. kinetic flame models. Due to the difficulty to generate these species cleanly, spectral data are rather scarce. Here we report on the selective generation of three picolyl radical isomers (C5H4N-CH2*) by deamination of aminomethylpyridines. Picolyl radicals are relevant in biofuel combustion, and could now be characterized by threshold photoelectron spectroscopy using synchrotron radiation. Vibrationally resolved bands and distinct ionization energies allow for isomer-specific detection of these elusive species in complex environments and permit us to explore new avenues in soot- and NOx formation kinetics.
Fate of Plutonium through a Geological Reactive Barrier
Natural geological and engineered barriers play a key role in protecting the environment and the anthroposphere from the hazardous impact of deposited waste or spreading contaminants. Such natural geological and engineered barrier materials are commonly complex and heterogeneous. In-situ multimodal microscopic studies under conditions relevant to deep geological formations are crucial to identify the reactive components and reaction pathways or to validate proposed immobilization mechanisms. The present study demonstrated that a simplistic description by a sole reactive component is not an adequate representation of the geochemical reactivity responsible for the immobilization of plutonium within a natural Clay Rock barrier. Multimodal chemical imaging studies on intact, undisturbed systems are absolutely essential to ascertain the geochemical reactivity for relevant geochemical conditions and settings.
Observing switching of Molecules using Free Electron Lasers
Free electron lasers (FELs) like SwissFEL help scientists to understand the mechanisms that switch properties of materials which are the basis for functions in electronics, solar cells, chemistry and biology. By using ultrashort X-ray pulses it becomes possible to visualize the ultrafast rearrangements of electrons and atoms that enable the properties to switch in molecules or crystals. An international consortium of researchers lead by Paul Scherrer Institute, Université de Rennes, and SLAC National Laboratory has now visualized the entire cascade of processes that lead to a change of the magnetic moment of electrons in a molecule within one trillionth of a second (10-12 s = 1 picosecond), using the FEL at Stanford, California (LCLS).
Additive Nanofabrication with Focused X-rays
Metal nanostructures can be fabricated by irradiation of suitable metal organic precursor molecules with a focused X-ray beam. This novel techniques offer the advantage of energy-selective deposition by switching of the incident photon energy due to the non-linear photon absorption cross-section of the precursor molecules for resonant excitation.
Observing switching of Molecules using Free Electron Lasers
Free electron lasers (FELs) like SwissFEL help scientists to understand the mechanisms that switch properties of materials which are the basis for functions in electronics, solar cells, chemistry and biology. By using ultrashort X-ray pulses it becomes possible to visualize the ultrafast rearrangements of electrons and atoms that enable the properties to switch in molecules or crystals.
Towards understanding of human betacoronavirus HKU1 life cycle
Researchers from China and USA join forces with Swiss Light Source (SLS) macromolecular crystallography (MX) beamline scientists in a study, which aims at understanding an important step in the life cycle of the human betacoronavirus HKU1.
Monte Carlo Simulation of Scintillation Detector for Spent Fuel Characterization in a Hot Cell
Spent fuel characterization is necessary to improve nuclear fuel design, optimize core refueling patterns and manage the handling, transport and storage of spent fuel assemblies. The experimental characterization of spent fuels includes measuring their gamma and neutron emissions typically with high-purity Germanium and He-3 detectors. In the past few years, however, efforts to develop efficient and low-cost, fast and thermal, neutron detectors have guided the research to the development of new scintillation detectors. These scintillators offer good efficiency, fast-timing properties, and good pulse shape discrimination capabilities for dual gamma and neutron detection. Within the Laboratory for Reactor Physics and Thermal-Hydraulics (LRT), a preliminary analysis was performed through Monte Carlo simulations to design a measurement unit at the HOTLAB based on new scintillators for the detection of fast neutrons emitted by spent fuel. This semester work of Marianna Papadionysiou was presented at the ANS Student conference in April and received two awards for "Best Detection and Measurement" and "Best Overall Research".
Wafer-thin Magnetic Materials Developed for Future Quantum Technologies
For the first time, researchers have produced a wafer-thin ferrimagnet, in which molecules with different magnetic centers arrange themselves on a gold surface to form a checkerboard pattern. Scientists at the Paul Scherrer Institute, in collaboration with their research partners, published the findings in the journal Nature Communications.