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Superior Bifunctional Electrocatalytic Activity of Ba0.5Sr0.5Co0.8Fe0.2O3-δ/ Carbon Composite Electrodes: Insight into the Local Electronic Structure
Using XAS it was demonstrated that carbon acts as an activity booster for Ba0.5Sr0.5Co0.8Fe0.2O3 oxygen reduction and evolution electrocatalyst promoting change of cobalt oxidation state.
Catalytically Active and Spectator Ce3+ in Ceria-Supported Metal Catalysts
Using time-resolved resonant X-ray emission spectroscopy, we quantitatively correlated the initial rate of Ce3+ formation under transient conditions to the overall rate of CO oxidation under steady-state conditions and showed that ceria reduction is a kinetically relevant step in CO oxidation, whereas a fraction of Ce3+ was present as spectators.