At the hot surface of a fuel rod cladding in the reactor water, the water is partially dissociated in hydrogen and oxygen, leading to corrosion of the cladding and to the uptake of a part of the created hydrogen. Hydrogen in solid solution and in precipitated form changes the mechanical properties of the cladding tube. The uptake of the hydrogen through the dense oxide layer is unclear. The structure and physical properties of the oxide near the metal-interface is critical The resistivity of the oxide increases with distance from the interface. Nb-containing alloys show lower resistivity in the oxide close to the metal interface, and exhibit a lower hydrogen pick-up. The time in the reactor is an important factor, leading to increasing resistivity in the oxide close to the metal interface, and a higher hydrogen uptake late in life.
Relevance of the findings: considering resistivity, the model of hydrogen uptake is better understood, revealing hints for further cladding development.