-
Batool SR, Sushkevich VL, van Bokhoven JA
Factors affecting the generation and catalytic activity of extra-framework aluminum Lewis acid sites in aluminum-exchanged zeolites
ACS Catalysis. 2024; 14: 678-690. https://doi.org/10.1021/acscatal.3c04195
DORA PSI -
Brenig A, Fischer JWA, Klose D, Jeschke G, van Bokhoven JA, Sushkevich VL
Redox and kinetic properties of composition‐dependent active sites in copper‐exchanged chabazite for direct methane‐to‐methanol oxidation
Angewandte Chemie International Edition. 2024. https://doi.org/10.1002/anie.202411662
DORA PSI -
Devos J, Sushkevich VL, Khalil I, Robijns S, de Oliveira-Silva R, Sakellariou D, et al.
Enhancing the acidity window of zeolites by low-temperature template oxidation with ozone
Journal of the American Chemical Society. 2024; 146(39): 27047-27059. https://doi.org/10.1021/jacs.4c08123
DORA PSI -
Fischer JWA, Buttignol F, Brenig A, Klose D, Ferri D, Sushkevich V, et al.
Design principles of operando ultraviolet-visible and electron paramagnetic resonance spectroscopy setups for active site characterization in ion-exchanged zeolites
Catalysis Today. 2024; 429: 114503 (10 pp.). https://doi.org/10.1016/j.cattod.2023.114503
DORA PSI -
Maggiulli L, Sushkevich VL, Kröcher O, van Bokhoven JA, Ferri D
Correlating the nature of carbenium ions in zeolites to the product distribution in the methanol-to-olefins process
ACS Catalysis. 2024; 14: 11477-11489. https://doi.org/10.1021/acscatal.4c03185
DORA PSI -
Artsiusheuski MA, Verel R, van Bokhoven JA, Sushkevich VL
Mechanism of hydrocarbon formation in methane and methanol conversion over copper-containing mordenite
ACS Catalysis. 2023; 13: 5864-5875. https://doi.org/10.1021/acscatal.2c06312
DORA PSI -
Artsiusheuski MA, Verel R, van Bokhoven JA, Sushkevich VL
Selective oxidative dehydrogenation of ethane and propane over copper-containing mordenite: insights into reaction mechanism and product protection
Angewandte Chemie International Edition. 2023; 62(44): e202309180 (11 pp.). https://doi.org/10.1002/anie.202309180
DORA PSI -
Artsiusheuski MA, Safonova O, Palagin D, van Bokhoven JA, Sushkevich VL
Structural evolution of copper-oxo sites in zeolites upon the reaction with methane investigated by means of Cu K-edge X-ray absorption spectroscopy
Journal of Physical Chemistry C. 2023; 127(20): 9603-9615. https://doi.org/10.1021/acs.jpcc.3c01496
DORA PSI -
Blankenship A, Artsiusheuski M, Sushkevich V, van Bokhoven JA
Recent trends, current challenges and future prospects for syngas-free methane partial oxidation
Nature Catalysis. 2023; 6(9): 748-762. https://doi.org/10.1038/s41929-023-01000-8
DORA PSI -
Fischer JWA, Brenig A, Klose D, van Bokhoven JA, Sushkevich VL, Jeschke G
Methane oxidation over Cu2+/[CuOH]+ pairs and site‐specific kinetics in copper mordenite revealed by operando electron paramagnetic resonance and UV‐visible spectroscopy
Angewandte Chemie International Edition. 2023; 62(34): e202303574 (10 pp.). https://doi.org/10.1002/anie.202303574
DORA PSI -
Sadykov II, Sushkevich VL, Krumeich F, Nuguid RJG, van Bokhoven JA, Nachtegaal M, et al.
Platinum‐iron(II) oxide sites directly responsible for preferential carbon monoxide oxidation at ambient temperature: an operando X‐ray absorption spectroscopy study
Angewandte Chemie International Edition. 2023; 62(1): e202214032 (11 pp.). https://doi.org/10.1002/anie.202214032
DORA PSI -
Semivrazhskaya OO, Salionov D, Clark AH, Casati NPM, Nachtegaal M, Ranocchiari M, et al.
Deciphering the mechanism of crystallization of UiO-66 metal-organic framework
Small. 2023; 19(52): 2305771 (11 pp.). https://doi.org/10.1002/smll.202305771
DORA PSI -
Yousefzadeh H, Bozbag SE, Sushkevich V, van Bokhoven JA, Erkey C
Stepwise conversion of methane to methanol over Cu-mordenite prepared by supercritical and aqueous ion exchange routes and quantification of active Cu species by H2-TPR
Catalysis Communications. 2023; 174: 106574 (8 pp.). https://doi.org/10.1016/j.catcom.2022.106574
DORA PSI -
Artsiusheuski MA, van Bokhoven JA, Sushkevich VL
Structure of selective and nonselective dicopper (II) sites in CuMFI for methane oxidation to methanol
ACS Catalysis. 2022; 12(24): 15626-15637. https://doi.org/10.1021/acscatal.2c05299
DORA PSI -
Batool SR, Sushkevich VL, van Bokhoven JA
Correlating Lewis acid activity to extra-framework aluminum species in zeolite Y introduced by ion-exchange
Journal of Catalysis. 2022; 408: 24-35. https://doi.org/10.1016/j.jcat.2022.02.010
DORA PSI -
Nuguid RJG, Ortino-Ghini L, Suskevich VL, Yang J, Lietti L, Kröcher O, et al.
Interconversion between Lewis and Brønsted-Lowry acid sites on vanadia-based catalysts
Physical Chemistry Chemical Physics. 2022; 24(7): 4555-4561. https://doi.org/10.1039/d1cp05261f
DORA PSI -
Paunović V, Sushkevich V, Rzepka P, Artiglia L, Hauert R, Lee SS, et al.
Reactivation of catalysts for methanol-to-hydrocarbons conversion with hydrogen
Journal of Catalysis. 2022; 407: 54-64. https://doi.org/10.1016/j.jcat.2022.01.018
DORA PSI -
Salionov D, Semivrazhskaya OO, Casati NPM, Ranocchiari M, Bjelić S, Verel R, et al.
Unraveling the molecular mechanism of MIL-53(Al) crystallization
Nature Communications. 2022; 13(1): 3762 (9 pp.). https://doi.org/10.1038/s41467-022-31294-4
DORA PSI -
Yakimov AV, Sushkevich VL, van Bokhoven JA, Copéret C
Probing acid sites in MOR zeolite using low-temperature 13C solid-state NMR spectroscopy of adsorbed carbon monoxide
Journal of Physical Chemistry C. 2022; 126(7): 3681-3687. https://doi.org/10.1021/acs.jpcc.1c10026
DORA PSI -
Yakimov AV, Ravi M, Verel R, Sushkevich VL, van Bokhoven JA, Copéret C
Structure and framework association of Lewis acid sites in MOR zeolite
Journal of the American Chemical Society. 2022; 144(23): 10377-10385. https://doi.org/10.1021/jacs.2c02212
DORA PSI -
Artsiusheuski MA, Verel R, van Bokhoven JA, Sushkevich VL
Methane transformation over copper-exchanged zeolites: from partial oxidation to C-C coupling and formation of hydrocarbons
ACS Catalysis. 2021; 11(20): 12543-12556. https://doi.org/10.1021/acscatal.1c02547
DORA PSI -
Artsiusheuski MA, van Bokhoven JA, Sushkevich VL
Modeling and experiment for oxygen isotope exchange over copper-containing mordenite
Journal of Physical Chemistry C. 2021; 125(22): 12366-12373. https://doi.org/10.1021/acs.jpcc.1c02531
DORA PSI -
Artsiusheuski MA, van Bokhoven JA, Sushkevich VL
Oxygen isotope exchange over copper-containing mordenite: the effect of copper loading and Si/Al ratio
Journal of Physical Chemistry C. 2021; 125(48): 26512-26521. https://doi.org/10.1021/acs.jpcc.1c08529
DORA PSI -
Kopelent R, Tereshchenko A, Guda A, Smolentsev G, Artiglia L, Sushkevich VL, et al.
Enhanced reducibility of the ceria-tin oxide solid solution modifies the CO oxidation mechanism at the platinum-oxide interface
ACS Catalysis. 2021; 11: 9435-9449. https://doi.org/10.1021/acscatal.1c01685
DORA PSI -
Li T, Beck A, Krumeich F, Artiglia L, Ghosalya MK, Roger M, et al.
Stable palladium oxide clusters encapsulated in silicalite-1 for complete methane oxidation
ACS Catalysis. 2021; 11(12): 7371-7382. https://doi.org/10.1021/acscatal.0c04868
DORA PSI -
Palagin D, Sushkevich VL, Knorpp AJ, Ranocchiari M, van Bokhoven JA
Mapping vibrational spectra to the structures of copper species in zeolites based on calculated stretching frequencies of adsorbed nitrogen and carbon monoxides
Journal of Physical Chemistry C. 2021; 125(22): 12094-12106. https://doi.org/10.1021/acs.jpcc.1c01649
DORA PSI -
Ravi M, Sushkevich VL, van Bokhoven JA
On the location of Lewis acidic aluminum in zeolite mordenite and the role of framework-associated aluminum in mediating the switch between Brønsted and Lewis acidity
Chemical Science. 2021; 12(11): 4094-4103. https://doi.org/10.1039/d0sc06130a
DORA PSI -
Sadykov II, Zabilskiy M, Clark AH, Krumeich F, Sushkevich V, van Bokhoven JA, et al.
Time-resolved XAS provides direct evidence for oxygen activation on cationic iron in a bimetallic Pt-FeOx/Al2O3 catalyst
ACS Catalysis. 2021; 11(18): 11793-11805. https://doi.org/10.1021/acscatal.1c02795
DORA PSI -
Sushkevich VL, Artsiusheuski M, Klose D, Jeschke G, van Bokhoven JA
Identification of kinetic and spectroscopic signatures of copper sites for direct oxidation of methane to methanol
Angewandte Chemie International Edition. 2021; 60(29): 15944-15953. https://doi.org/10.1002/anie.202101628
DORA PSI -
Zabilskiy M, Sushkevich VL, Newton MA, Krumeich F, Nachtegaal M, van Bokhoven JA
Mechanistic study of carbon dioxide hydrogenation over Pd/ZnO‐based catalysts: the role of palladium‐zinc alloy in selective methanol synthesis
Angewandte Chemie International Edition. 2021; 60(31): 17053-17059. https://doi.org/10.1002/anie.202103087
DORA PSI -
Jovanovic ZR, Lange J-P, Ravi M, Knorpp AJ, Sushkevich VL, Newton MA, et al.
Oxidation of methane to methanol over Cu-exchanged zeolites: Scientia gratia scientiae or paradigm shift in natural gas valorization?
Journal of Catalysis. 2020; 385: 238-245. https://doi.org/10.1016/j.jcat.2020.02.001
DORA PSI -
Newton MA, Knorpp AJ, Sushkevich VL, Palagin D, van Bokhoven JA
Active sites and mechanisms in the direct conversion of methane to methanol using Cu in zeolitic hosts: a critical examination
Chemical Society Reviews. 2020; 49(5): 1449-1486. https://doi.org/10.1039/C7CS00709D
DORA PSI -
Newton MA, Knorpp AJ, Meyet J, Stoian D, Nachtegaal M, Clark AH, et al.
Unwanted effects of X-rays in surface grafted copper (II) organometallics and copper exchanged zeolites, how they manifest, and what can be done about them
Physical Chemistry Chemical Physics. 2020; 22(13): 6826-6837. https://doi.org/10.1039/D0CP00402B
DORA PSI -
Ravi M, Sushkevich VL, van Bokhoven JA
Towards a better understanding of Lewis acidic aluminium in zeolites
Nature Materials. 2020; 19(10): 1047-1056. https://doi.org/10.1038/s41563-020-0751-3
DORA PSI -
Sushkevich VL, van Bokhoven JA
Kinetic study and effect of water on methane oxidation to methanol over copper-exchanged mordenite
Catalysis Science and Technology. 2020; 10(2): 382-390. https://doi.org/10.1039/c9cy01711a
DORA PSI -
Sushkevich VL, Verel R, van Bokhoven JA
Pathways of methane transformation over copper‐exchanged mordenite as revealed by in situ NMR and IR spectroscopy
Angewandte Chemie International Edition. 2020; 59(2): 910-918. https://doi.org/10.1002/anie.201912668
DORA PSI -
Sushkevich VL, Safonova OV, Palagin D, Newton MA, van Bokhoven JA
Structure of copper sites in zeolites examined by Fourier and wavelet transform analysis of EXAFS
Chemical Science. 2020; 20(11): 5299-5312. https://doi.org/10.1039/D0SC01472A
DORA PSI -
Zabilskiy M, Sushkevich VL, Newton MA, van Bokhoven JA
Copper-zinc alloy-free synthesis of methanol from carbon dioxide over Cu/ZnO/faujasite
ACS Catalysis. 2020; 10: 14240-14244. https://doi.org/10.1021/acscatal.0c03661
DORA PSI -
Zabilskiy M, Sushkevich VL, Palagin D, Newton MA, Krumeich F, van Bokhoven JA
The unique interplay between copper and zinc during catalytic carbon dioxide hydrogenation to methanol
Nature Communications. 2020; 11: 2409 (8 pp.). https://doi.org/10.1038/s41467-020-16342-1
DORA PSI -
Zhu J, Sushkevich VL, Knorpp AJ, Newton MA, Mizuno SCM, Wakihara T, et al.
Cu-erionite zeolite achieves high yield in direct oxidation of methane to methanol by isothermal chemical looping
Chemistry of Materials. 2020; 32(4): 1448-1453. https://doi.org/10.1021/acs.chemmater.9b04223
DORA PSI -
Artiglia L, Sushkevich VL, Palagin D, Knorpp AJ, Roy K, van Bokhoven JA
In situ X-ray photoelectron spectroscopy detects multiple active sites involved in the selective anaerobic oxidation of methane in copper-exchanged zeolites
ACS Catalysis. 2019; 9(8): 6728-6737. https://doi.org/10.1021/acscatal.9b01223
DORA PSI -
Knorpp AJ, Newton MA, Sushkevich VL, Zimmermann PP, Pinar AB, van Bokhoven JA
The influence of zeolite morphology on the conversion of methane to methanol on copper-exchanged omega zeolite (MAZ)
Catalysis Science and Technology. 2019; 9(11): 2806-2811. https://doi.org/10.1039/c9cy00013e
DORA PSI -
Lange J-P, Sushkevich VL, Knorpp AJ, van Bokhoven JA
Methane-to-methanol via chemical looping: economic potential and guidance for future research
Industrial and Engineering Chemistry Research. 2019; 58(20): 8674-8680. https://doi.org/10.1021/acs.iecr.9b01407
DORA PSI -
Palagin D, Sushkevich VL, van Bokhoven JA
Water molecules facilitate hydrogen release in anaerobic oxidation of methane to methanol over Cu/Mordenite
ACS Catalysis. 2019; 9(11): 10365-10374. https://doi.org/10.1021/acscatal.9b02702
DORA PSI -
Ravi M, Sushkevich VL, van Bokhoven JA
Lewis acidity inherent to the framework of zeolite mordenite
Journal of Physical Chemistry C. 2019; 123(24): 15139-15144. https://doi.org/10.1021/acs.jpcc.9b03620
DORA PSI -
Ravi M, Sushkevich VL, Knorpp AJ, Newton MA, Palagin D, Pinar AB, et al.
Misconceptions and challenges in methane-to-methanol over transition-metal-exchanged zeolites
Nature Catalysis. 2019; 2(6): 485-494. https://doi.org/10.1038/s41929-019-0273-z
DORA PSI -
Sushkevich VL, Smirnov AV, van Bokhoven JA
Autoreduction of copper in zeolites: role of topology, Si/Al ratio, and copper loading
Journal of Physical Chemistry C. 2019; 123(15): 9926-9934. https://doi.org/10.1021/acs.jpcc.9b00986
DORA PSI -
Sushkevich VL, van Bokhoven JA
Methane-to-methanol: activity descriptors in copper-exchanged zeolites for the rational design of materials
ACS Catalysis. 2019; 9(7): 6293-6304. https://doi.org/10.1021/acscatal.9b01534
DORA PSI -
Sushkevich VL, Kots PA, Kolyagin YG, Yakimov AV, Marikutsa AV, Ivanova II
Origin of water-induced Brønsted acid sites in Sn-BEA zeolites
Journal of Physical Chemistry C. 2019; 123(9): 5540-5548. https://doi.org/10.1021/acs.jpcc.8b12462
DORA PSI -
Tomkins P, Mansouri A, Sushkevich VL, van der Wal LI, Bozbag SE, Krumeich F, et al.
Increasing the activity of copper exchanged mordenite in the direct isothermal conversion of methane to methanol by Pt and Pd doping
Chemical Science. 2019; 10(1): 167-171. https://doi.org/10.1039/C8SC02795A
DORA PSI -
Knorpp AJ, Pinar AB, Newton MA, Sushkevich VL, van Bokhoven JA
Copper-exchanged omega (MAZ) zeolite: copper-concentration dependent active sites and its unprecedented methane to methanol conversion
ChemCatChem. 2018; 10(24): 5593-5596. https://doi.org/10.1002/cctc.201801809
DORA PSI -
Newton MA, Knorpp AJ, Pinar AB, Sushkevich VL, Palagin D, van Bokhoven JA
On the mechanism underlying the direct conversion of methane to methanol by copper hosted in zeolites; braiding Cu K-Edge XANES and reactivity studies
Journal of the American Chemical Society. 2018; 140(32): 10090-10093. https://doi.org/10.1021/jacs.8b05139
DORA PSI -
Sushkevich VL, van Bokhoven JA
Effect of Brønsted acid sites on the direct conversion of methane into methanol over copper-exchanged mordenite
Catalysis Science and Technology. 2018; 8(16): 4141-4150. https://doi.org/10.1039/c8cy01055b
DORA PSI -
Sushkevich VL, van Bokhoven JA
Revisiting copper reduction in zeolites: the impact of autoreduction and sample synthesis procedure
Chemical Communications. 2018; 54(54): 7447-7450. https://doi.org/10.1039/c8cc03921f
DORA PSI -
Sushkevich VL, Palagin D, van Bokhoven JA
The effect of the active-site structure on the activity of copper mordenite in the aerobic and anaerobic conversion of methane into methanol
Angewandte Chemie International Edition. 2018; 57(29): 8906-8910. https://doi.org/10.1002/anie.201802922
DORA PSI -
Sushkevich VL, Palagin D, Ranocchiari M, van Bokhoven JA
Response to comment on "Selective anaerobic oxidation of methane enables direct synthesis of methanol"
Science. 2017; 358(6360): eaan6083 (3 pp.). https://doi.org/10.1126/science.aan6083
DORA PSI -
Sushkevich VL, Palagin D, Ranocchiari M, van Bokhoven JA
Selective anaerobic oxidation of methane enables direct synthesis of methanol
Science. 2017; 356(6337): 523-527. https://doi.org/10.1126/science.aam9035
DORA PSI -
Sushkevich VL, Popov AG, Ivanova II
Sulfur-33 isotope tracing of the hydrodesulfurization process: insights into the reaction mechanism, catalyst characterization and improvement
Angewandte Chemie International Edition. 2017; 56(36): 10872-10876. https://doi.org/10.1002/anie.201704027
DORA PSI