List of Publications Daniel Grolimund (PSI)

S. Kapishnikov, D. Grolimund, G. Schneider, E. Pereiro, J. McNally, J. Als-Nielsen, L. Leiserowitz, Unraveling heme detoxification and crystallization in the malaria parasite by correlative X-ray microscopy, Nature Sci. Rep., in press, (2017).

U. Kaplan, S. Amayri, D.R. Fröhlich, J. Drebert, D. Grolimund, C. Borca, T. Reich, Geochemical Interactions of Plutonium(VI) with Opalinus Clay Studied by Spatially Resolved Synchrotron Radiation Techniques, Env. Sci. Tech., in press, (2017).

R. Middendorp, M. Dürr, A. Knott, F. Pointurier, D. Ferreira Sanchez, V. Samson, D. Grolimund, Characterization of the Aerosol-based Synthesis of Uranium Particles as a Potential Reference Material for Micro Analytical Methods, Anal. Chem., 89, 4721-4728, (2017).

D. Ferreira Sanchez, D. Grolimund, M. Hubert, P. Bleuet, J. Laurencin, A 2D and 3D X-ray μ-diffraction and μ-fluorescence study of a Mixed Ionic Electronic Conductor, Int. J. Hydrogen Energy, 42, 1203-1211, (2017).

M. Chollet, S. Valance, J. Bertsch, S. Abolhassani, G. Stein, D. Grolimund, M. Martin, G. Kuri, Synchrotron X-ray Diffraction Investigations on Strains in the oxide layer of an Irradiated Zircaloy Fuel Cladding, JNM, 488, 181–190, (2017).

D. Bocharov, M. Chollet, M. Krack, J. Bertsch, D. Grolimund, M. Martin, A. Kuzmin, J. Purans, E. Kotomin, Analysis of the U L3-edge X-ray absorption spectra in UO2 using molecular dynamics simulations, Progress in Nuclear Energy, 94, 187-193, (2017).

F.G. Santomauro, J. Grilj, L. Mewes, G. Nedelcu, S. Yakunin, T. Rossi, G. Capano, A. Al Haddad, J. Budarz, D. Kinschel, D.S. Ferreira, G. Rossi, M. Gutierrez Tovar, D. Grolimund, V. Samson, M. Nachtegaal, G. Smolentsev, M.V. Kovalenko, M. Chergui, Localized holes and delocalized electrons in photoexcited inorganic perovskites: a picosecond X-ray absorption study, Structural Dynamics, 4, 44002, (2017).

U. Hartfelder, J. Singh, J. Haase, M. Nachtegaal, D. Grolimund, J.A. van Bokhoven, Detecting and utilizing minority phases in heterogeneous catalysis, NATURE Sci. Rep., 6, 37597, (2016).

D. Grolimund, P. Wersin, J. Brendlé, J. Huve, L. Kiviranta, M. Snellman, Interaction of Titanium with Smectite within the Scope of a Spent Fuel Repository: A Spectroscopic Approach, Clay Minerals, 51/2, 249-266, (2016).

A. Irastorza-Landa; H. Van Swygenhoven, S. Van Petegem, A. Bollhalder, S. Brandstetter, D. Grolimund, Following dislocation patterning during fatigue, Acta Materialia, 112, 184-193, (2016).

L.I. Olsen, T.H. Hansen, C. Larue, J.T. Østerberg, R.D. Hoffmann, J. Liesche, U. Krämer, S. Surble, S. Cadarsi, V.A. Samson, D. Grolimund, S. Husted, M. Palmgren, Mother plant-mediated pumping of zinc into the developing seed, NATURE Plants, 16036, (2016).

J. Poonoosamy, E. Curti, G. Kosakowski, L. R. Van Loon, D. Grolimund & U. Mäder, Barite precipitation following celestite dissolution in reactive transport experiments: a SEM/BSE and µ-XRD/XRF study, Geochim. Cosmochim. Acta, 182, 131-144, (2016).

F. Lin, V.A. Samson, A. Wismer, D. Grolimund, A. Wokaunc, I. Alxneita, Zn-modified ceria as redox material for thermochemical H2O and CO2 splitting cycles ― Effect of a secodary ZnO phase on its thermochemical activity, Cryst. Eng. Comm., 18, 2559-2569, (2016).

L. Nowack, D. Grolimund, V. Samson, F. Marone, V. Wood, Rapid Mapping of Lithiation Dynamics in Transition Metal Oxides using Operando X-Ray Absorption Spectroscopy, NATURE Sci. Rep., 6, 21479, (2016).

C. Kenel, S. Van Petegem, P. Schloth, J.L. Fife, D. Grolimund, A. Menzel, H. Van Swygenhoven, C. Leinenbach, In situ synchrotron microXRD and SAXS studies on rapidly heated and cooled Ti-Al and Al-Cu-Mg alloys using high power laser radiation, J. Min. Met. Mat., 114, 117-120, (2016).

T. Lombardo, D. Grolimund, A. Kienholz, V. Hubert, M. Wörle, The use of flint-stone fragments as “fire-strikers” during the Neolithic period: Complementary micro-analytical evidences, Microchemical Journal, 125, 254-259, (2016).

R. Dähn, A. Arakcheeva, Ph. Schaub, P. Pattison, G. Chapuis, D. Grolimund, E. Wieland, A. Leemann, Application of micro X-ray diffraction to investigate the reaction products formed by the alkali-silica reaction in concrete structures, Cement and Concrete Research, 79, 49-56, (2016).

C. Kenel, P. Schloth, S. Van Petegem, J.F. Fife, D. Grolimund, A. Menzel, H. Van Swygenhoven, C. Leinenbach, In Situ Synchrotron X-Ray Diffraction and Small Angle X-Ray Scattering Studies on Rapidly Heated and Cooled Ti-Al and Al-Cu-Mg Alloys Using Laser-Based, JOM, 68, 978-984, (2016).

F.G. Santomauro, A. Lübcke, J. Rittmann, E. Baldini, A. Ferrer, M. Silatani, P. Zimmermann, S. Grübel, J. Johnson, P. Beaud, D. Grolimund, C. Borca, G. Ingold, S. Johnson, M. Chergui, Femtosecond X-ray absorption study of electron localization in anatase TiO2, Scientific Reports, 5, 14834, (2015).

M. Silatani, F.A. Lima, T.J. Penfold, J. Rittmann, M. Reinhard, H. Rittmann-Frank, C. Borca, D. Grolimund, C.J. Milne, M. Chergui, NO binding kinetics in Myoglobin investigated by picosecond Fe K-edge absorption spectroscopy, PNAS, 112 (42), 12922-12927, (2015).

A. Guitton, A. Irastorza-Landa, R. Broennimann, D. Grolimund, S. Van Petegem, H. Van Swygenhoven, Picosecond pulsed laser for micro scale sample preparation, Materials Letters, 160, 589-591, (2015).

E. Curti, A. Puranen, D. Grolimund, D. Jädernas, D. Cheptiakov, A. Mesbah, J.A. Ibers, Characterization of 79Se in UO2 spent nuclear fuel by micro X-ray absorption spectroscopy and its thermodynamic stability, Environmental Science: Processes & Impacts, 17 (10), 1760-1768, (2015).

K.H. Kim, J. Kim, K.Y. Oang, J.H. Lee, D. Grolimund, C.J. Milne, S.L. Johnson, A. Galler, T.W. Kim, J.G. Kim, J. Kim, K. Hong, L. Guerin, P. El-Khoury, T.K. Kim, M. Wulff, C. Bressler, H. Ihee, Identifying a major intermediate species by combining time-resolved X-ray absorption spectroscopy and X-ray solution scattering, Phys. Chem. Chem. Phys., 17 (36), 23298-23302, (2015).

M. Burger, A. Gundlach-Graham, S. Allner, G. Schwarz, H.A.O. Wang, L. Gyr, S. Burgener, B. Hattendorf, D. Grolimund, D. Günther, High-speed, high-resolution, multi-elemental LA-ICP-TOFMS imaging: Part II. Quantitative three-dimensional imaging of major, minor and trace elements in geological samples, Analytical Chemistry, 87 (16), 8259-8267, (2015).

M. Žižića, T. Dučič, D. Grolimund, D. Bajuk-Bogdanovićd, M. Nikolica, M. Stanića, S. Križaka, J. Zakrzewskae, X-ray absorption near-edge structure micro-spectroscopy study on vanadium speciation in Phycomyces Blakesleeanus mycelium, Analytical and Bioanalytical Chemistry, 407 (24), 7487-7496, (2015).

A. Gundlach-Graham, M. Burger, S. Allner, G. Schwarz, H.A.O. Wang, L. Gyr, B. Hattendorf, D. Grolimund,D. Günther, High-Speed, High-Resolution, Multi-Elemental LA-ICP-TOFMS Imaging: Part I. Instrumentation and Two-Dimensional Imaging of Geological Samples, Analytical Chemistry, 87 (16), 8250-8258, (2015).

A. Velea, C.N. Borca, G. Socol, D. Grolimund, M. Popescu, J.A. van Bokhoven, In-situ crystallization of GeTe/GaSb phase change memory stacked films, J. Appl. Phys., 116/23, 234306, (2014).

C. Degueldre, C. Mieszczynski, C. Borca, D. Grolimund, M. Martin, J. Bertsch, X-ray fluorescence and absorption analysis of krypton in irradiated nuclear fuel, NIM-B, 336, 116-122, (2014).

T. Rossi, T.J. Penfold, M.H. Rittmann-Frank, M. Reinhard, J. Rittmann, T. Huthwelker, C.N. Borca, D. Grolimund, C.J. Milne, M. Chergui, Characterizing the Structure and Defect Concentration of ZnO Nanostructures in a Colloidal Solution, Journal of Physical Chemistry – Part C, 118/33, 19422-19430, (2014).

P. Karvinen, D. Grolimund, M. Willimann, B. Meyer, M. Birri, C. Borca, J. Patommel, G. Wellenreuther, G. Falkenberg, M. Guizar-Sicairos, A. Menzel, C. David, Kinoform diffractive lenses for efficient nano-focusing of hard X-rays, Optics Express, 22/14, 16676-16685, (2014).

C. Marichal, K. Srivastava, D. Weygand, S. Van Petegem, D. Grolimund, P. Gumbsch, H. Van Swygenhoven, Origin of Anomalous Slip in Tungsten, Phys. Rev. Lett. 113, 025501, (2014).

E. Curti, A. Froideval, I. Günther-Leopold, M. Martin, A. Bullemer, H. Linder, C.N. Borca, D. Grolimund, Selenium redox speciation and coordination in high-burnup UO2 fuel: Consequences for the release of 79Se in a deep underground repository, Journal of Nuclear Materials, Available online 10 July, (2014).

C. Giesen, H.A.O Wang, P. Schüffler, B. Hattendorf, D. Grolimund, A. Jacobs, N. Zivanovic, J.M. Buhmann, S. Brandt, Z. Varga, P.J. Wild, D. Günther, B. Bodenmiller, Simultaneous visualization of 32 proteins and protein modifications in formalin-fixed paraffin-embedded tissues with subcellular resolution by imaging mass cytometry, Nature Methods, 11/4, 417-423, (2014).

D.E. Crean, F.R. Livens, M.C. Stennett, D. Grolimund, C.N. Borca, N.C. Hyatt, Microanalytical x-ray imaging of depleted uranium speciation in environmentally aged munitions residues, Env. Sci. Technol., 48/3, 1467-1474, (2014).

R. Dähn, D. Popov, Ph. Schaub, P. Pattison, D. Grolimund, U. Mäder, A. Jenni, E. Wieland, X-ray micro-diffraction studies of heterogeneous interfaces between cementitious materials and geological formations, Physics and Chemistry of the Earth, 70/71, 96-103, (2014).

C. Mieszczynski, G. Kuri, C. Degueldre, M. Martin, J. Bertsch, C.N. Borca, D. Grolimund, C. Delafoy, E. Simoni, Irradiation effects and micro-structural changes in large grain uranium dioxide fuel investigated by micro-beam X-ray diffraction, Journal of Nuclear Materials, 444/1-2, 274–282, (2014).

T. Gimmi, O.X. Leupin, J. Eikenberg, M.A. Glaus, L.R. Van Loon, D. Grolimund, H.A.O. Wang, C.N. Borca, H.N. Waber, P. Wersin, S. Dewonck, C. Wittebroodte, Anisotropic diffusion at the field scale in a four-year multi-tracer diffusion and retention experiment – I: Insights from the experimental data, Geochimica et Cosmochimica Acta, 125, 373-393, (2014).

D.E. Crean, F.R. Livens, M. Sajih, M.C. Stennett, D. Grolimund, C.N. Borca, N.C. Hyatt, Remediation of soils contaminated with particulate depleted uranium by multi stage chemical extraction, J. Haz. Mat., 263 382-390, (2013).

H.A.O Wang, D. Grolimund, C. Giessen, C.N. Borca, J. Shaw-Stewart, B. Bodenmiller, D. Günther, Fast Chemical Imaging at High Spatial Resolution by Laser Ablation Inductively Coupled Plasma Mass Spectrometry, Analytical Chemistry, 85(21), 10107–10116, (2013).

C. Degueldre, C. Cozzo, M. Martin, D. Grolimund, C. Mieszczynski, Americium characterisation by X-ray fluorescence and absorption spectroscopy in plutonium uranium mixed oxide, Journal of Solid State Chemistry, 202, 315–319, (2013).

D.S. Alessi, B. Uster, C.N. Borca, D. Grolimund, R. Bernier-Latmani, Beam induced oxidation of monomeric U(IV) species, J. Synchrotron Rad., 20, 197–199, (2013).

D. Berger, K. Hunger, S. Bolliger-Schreyer, D. Grolimund, S. Hartmann, J. Hovind, F. Müller, E.H. Lehmann, P. Vontobel, M. Wörle, New insights into the manufacturing process and decoration technique of the axe from Thun-Renzenbühl, Antiquaries Journal, 93, 1–29, (2013).

D.R. Fröhlich, S. Amayri1, J. Drebert, D. Grolimund, J. Huth, U. Kaplan, J. Krause, T. Reich, Speciation of Np(V) uptake by Opalinus Clay using synchrotron microbeam techniques, Anal. Bioanal. Chem., 404(8), 2151–2162, (2012).

A.R. Uhl, C. Fella, A. Chirila, M.R. Kaelin, L. Karvonen, A. Weidenkaff, C.N. Borca, D. Grolimund, Y.E. Romanyuk1, A.N. Tiwari, Non-vacuum deposition of Cu(In,Ga)Se2 absorber layers from binder free, alcohol solutions, Progress in Photovoltaics, 20(5), 526-533, (2012).

A. Idhil, C.N. Borca, A. Uldry, N. Zema, S. Turchini, D. Catone, A. Foelske, D. Grolimund, M. Samaras, The influence of Cr-composition on the local magnetic structure of FeCr alloys, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 284, 1-5, (2012).

M. Ranocchiari, Ch. Lothschütz, D. Grolimund, J.A. van Bokhoven, Single-Atom Active Sites on Metal-Organic Frameworks, Proc. R. Soc. A, 468 (2143), 1985-1999, (2012).

H.A.O. Wang, D. Grolimund, L.R. Van Loon, K. Barmettler, C.N. Borca, B. Aeschlimann, D. Günther, High Spatial Resolution Quantitative Imaging by Cross-calibration Using Laser Ablation Inductively Coupled Plasma Mass Spectrometry and Synchrotron Micro-X-ray Fluorescence Technique, CHIMIA, 66(4), 223-228, (2012).

E. Curti, D. Grolimund, C.N. Borca, CeIII/IV distribution and speciation following long-term aqueous alteration of simulated nuclear waste glass: A micro-XAS/XRF study, Applied Geochemistry, 27, 56-63, (2012).

H.A.O. Wang, D. Grolimund, D. Guenther, L. von Loon, K. Barmettler, C.N. Borca, B. Aeschlimann, Quantitative Chemical Imaging of Element Diffusion into Heterogeneous Media Using Laser Ablation Inductively Coupled Plasma Mass Spectrometry, Synchrotron Micro-X-ray Fluorescence, and Extended X-ray Absorption Fine Structure Spectroscopy, Analytical Chemistry, 16, 6259–6266, (2011).

F. Lima, Ch. Milne, D. Amarasinghe, M.H. Rittmann-Frank, R. van der Veen, M. Reinhard, V.-T. Pham, S. Karlsson, S.L. Johnson, D. Grolimund, C.N. Borca, Th. Huthwelker, M. Janousch, R. Abela, F. van Mourik, M. Chergui, A high-repetition rate scheme for synchrotron-based picosecond laser pump/x-ray probe experiments on chemical and biological systems in solution, Review of Scientific Instruments, 82, 063111-(1-16), (2011).

D. Grolimund, D. Berger, S. Bolliger-Schreyer, C.N. Borca, F. Müller, J. Hovind, K. Hunger, E.H. Lehmann, P. Vontobel, H.A.O. Wang, Combined neutron and synchrotron X-Ray microscope analysis: attempt to disclose 3600 years-old secrets of a unique bronze age metal artifact, J. Anal. At. Spectrom., 26 (5), 1012 – 1023, (2011).

C. Degueldre, M. Martin, G. Kuri, D. Grolimund, C.N. Borca, Plutonium uranium mixed oxide characterization by coupling micro- X-ray diffraction and absorption investigations, Journal of Nuclear Materials, 416(1-2), 142-150, (2011).

G. Vanko, P. Glatzel, V-T. Pham, R. Abela, D. Grolimund, C.N. Borca, S.L. Johnson, C.J. Milne, Ch. Bressler, Picosecond Time-Resolved X-Ray Emission Spectroscopy: Ultrafast Spin-State Determination in an Iron Complex, Angew. Chemie, 49(34), 5910-5912, (2010).

R. Abela, D. Grolimund, E. Pretsch, Analytical applications of synchrotron radiation, (editorial), Trends in Analytical Chemistry, 29(6), 452, (2010). M. Casapu, O. Kröcher, M. Mehring, M. Nachtegaal, C.N. Borca, H. Harfouche, D. Grolimund, Characterization of Nb-containing MnOx-CeO2 catalyst for low-temperature selective catalytic reduction of NO with NH3, J. Physical Chemistry C, 114(21), 9791-9801, (2010).

C. Milne, V.-T. Pham, W. Gawelda, A.E. Nahhas, R.M. van der Veen, S.L. Johnson, P. Beaud, G. Ingold, C. Borca, D. Grolimund, R. Abela, M. Chergui, Ch. Bressler, Femtosecond X-ray Absorption Spectroscopy οf a Light Driven Spin Crossover Process, Acta Physica Polonica A, 117(2), 391-393, (2010).

J. Zimmermann, S. Van Petegem, H. Bei, D. Grolimund, E.P. George, H. Van Swygenhoven, Effects of focused ion beam milling and pre-straining on the microstructure of directionally solidified molybdenum pillars: A Laue diffraction analysis, Scripta Materialia, 62(10), 746-749, (2010). M. Katsikini, F. Pinakidou, E. Mavromati, E. C. Paloura, D. Gioulekas, D. Grolimund, Fe distribution and speciation in human nails, Nuclear Instruments & Methods B, 268(3-4), 420–424, (2010).

M. Harfouche, J. Labanowski, F. Farges, E. van Hullebusch, C.N. Borca, D. Grolimund, F. van Oort, Assessment of Zn bioavailability: XAFS study on speciation of zinc-particulate organic matter associations in polluted soils, Journal of Physics Conference Series, 190, 012189(1-4), (2009).

J. Dubrail, F. Farges, L. Gautron, M. Harfouche, C.N. Borca, D. Grolimund, Pb in naturally irradiated monazites and zircons, Journal of Physics Conference Series, 190, 012180(1-4), (2009).

C.J. Milne, V.T. Pham, W. Gawelda, R.M. van der Veen, A. El Nahhas, S.L. Johnson, P. Beaud, G. Ingold, F. Lima, D.A. Vithanage, M. Benfatto, D. Grolimund, C.N. Borca, M. Kaiser, A. Hauser, R. Abela, Ch. Bressler, M. Chergui, Time-resolved x-ray absorption spectroscopy: Watching atoms dance, Journal of Physics Conference Series, 190, 012052(1-11), (2009).

M. Podgorczyk, W.M. Kwiatek, W.M. Zajaca, J. Dulinska-Litewka, E. Welterc, D. Grolimund, Zinc in native tissues and cultured cell lines of human prostate studied by SR-XRF and XANES, X-Ray Spectrom., 38(6), 557–562, (2009).

R. Maaß, S. Van Petegem, D. Ma, J. Zimmermann, D. Grolimund, F. Roters, H. Van Swygenhoven, D. Raabe, Smaller is stronger: The effect of strain hardening, Acta Materialia, 57(20), 5996-6005, (2009).

M. Podgórczyk, W.M. Kwiatek, D. Grolimund, C.N. Borca, Technical aspects of Zn microanalysis of human prostate cancer tissues and cells, Radiation Physics and Chemistry, 78, 53-57, (2009).

J. Vila-Comamala, K. Jefimovs, T. Pilvi, M. Ritala, S.S. Sarkar, H.H. Solak, V.A. Guzenko, M. Stampanoni, F. Marone, J. Raabe, G. Tzvetkov, R.H. Fink, D. Grolimund, C.N. Borca, B. Kaulich, C. David, Advanced X-Ray Diffractive Optics, Journal of Physics: Conference Series, 186, 012078-1/3, (2009).

C.N. Borca, D. Grolimund, M. Willimann, B. Meyer, K. Jefimovs, J. Vila-Comamala, C. David, The microXAS beamline at the Swiss Light source: towards nano-scale imaging, Journal of Physics: Conference Series, 186, 012003-1/3, (2009).

C. Degueldre, G. Kuri, C.N. Borca, D. Grolimund, X-ray micro- fluorescence, diffraction and absorption spectroscopy for local structure investigation of a radioactive zinc ferrite deposit, Corrosion Science, 51(8), 1690-1695, (2009).

A. Froideval, M. Samaras, R. Iglesias, M. Pouchon, J.-C. Chen, D. Grolimund, J. Raabe, S. Schuppler, V. Max, W. Hoffelner, Application of synchrotron radiation techniques for model validation of advanced structural materials, Advanced Engineering Materials, 11(6), 459-463, (2009).

W. Gawelda, V.-T. Pham, R. Van der Veen, D. Grolimund, R. Abela, M. Chergui, Ch. Bressler, Structural Analysis of ultrafast extended X-ray Absorption Fine Structure with Subpicometer Spatial Resolution: Application to Spin Cross-Over Complexes, Journal of Chemical Physics, 130, 124590-1-9, (2009).

Ch. Bressler, C. Milne, V.-T. Pham, A. ElNahhas, R.M. van der Veen, W. Gawelda, S. Johnson, P. Beaud, D. Grolimund, M. Kaiser, C.N. Borca, G. Ingold, R. Abela, M. Chergui, Femtosecond XANES of the light-induced spin cross-over in a Iron(II) complex, SCIENCE, 323, 489–492, (2009).

A. Froideval, S. Abolhassani, D. Gavillet, D. Grolimund, C. Borca, J. Krbanjevic, C. Degueldre, Microprobe analysis of neutron irradiated and autoclaved zirconium niobium claddings using synchrotron-based hard X-ray imaging and spectroscopy, Journal of Nuclear Materials, 385(2), 346–350, (2009).

R. Maaß, S. Van Petegem, H. Van Swygenhoven, D. Grolimund, P.M. Derlet, C.A. Volkert, , In-situ time resolved Laue diffraction during micro-compression experiments, Advances in Synchrotron Radiation, 1(2), 151-157, (2008)

N. Bukowiecki, P. Lienemann, C.N. Zwicky, M. Furger, A. Richard, G. Falkenberg, K. Rickers, D. Grolimund, C. Borca, M. Hill, R. Gehrig, U. Baltensperger, X-ray fluorescence spectrometry for high throughput analysis of atmospheric aerosol samples: The benefits of synchrotron X-rays, Spectrochimica Acta Part B, 63, 929–938, (2008).

F. Krasniqi, S. L. Johnson, P. Beaud, M. Kaiser, D. Grolimund, G. Ingold. Influence of Lattice Heating Time on the Laser-Induced Strain Waves in InSb, Phys. Rev. B, 78, 174302, (2008).

P. Beaud, S. L. Johnson, A. Streun, R. Abela, D. Abramsohn, D. Grolimund, F. Krasniqi, T. Schmidt, V. Schlott, G. Ingold, Spatiotemporal Stability of Femtosecond Hard X-ray Undulator Radiation Studied by Control of Coherent Optical Phonons (vol 99, art no 174801, 2007), Physical Review Letters, 100, 099901, (2008).

M. Lenz, E.D. van Hullebusch, F. Farges, S. Nikitenko, C.N. Borca, D. Grolimund, P.N.L. Lens. Selenium speciation in anaerobic biofilms assessed by X-ray absorption spectroscopy and sequential extraction procedures, Environ. Sci. Technol., 42(20), 7587-7593, (2008).

S. L. Johnson, P. Beaud, F. Krasniqi, C. Milne, M. Kaiser, D. Grolimund, R. Abela, G. Ingold. Nanoscale depth-resolved coherent femtosecond motion in laser excited bismuth, Physical Review Letters, 100(15): Art. No. 155501, (2008).

F.C. Küpper, L.J. Carpenter, G.B. McFiggans, C.J. Palmer, T.J. Waite, E.-M. Boneberg, S. Woitsch, M. Weiller, R. Abela, D. Grolimund, Ph. Potin, A. Butler, G.W. Luther III, P.M.H. Kroneck, W. Meyer-Klaucke, M.C. Feiters, Iodide in kelp: an inorganic antioxidant in life impacting atmospheric chemistry, PNAS, 105(19), 6954-6958, (2008).

P. Wersin, J.M. Soler, L. Van Loon, J. Eikenberg, B. Baeyens, D. Grolimund, T. Gimmi, S. Dewonck, Diffusion of HTO, Br-, I-, Cs+, 85Sr2+ and 60Co2+ in a Clay Formation: Results and Modelling from an In-Situ Experiment in Opalinus Clay, Applied Geochemistry, 23(4), 678-691, (2008).

A. Froideval, C. Degueldre, C.U. Segre, M.A. Pouchon, D. Grolimund, Niobium speciation at the metal/oxide interface of corroded niobium-doped Zircaloys: A X-ray absorption near-edge structure study, Corrosion Science, 50(5), 1313-1320, (2008).

R. Maaß, S. Van Petegem, D. Grolimund, H. Van Swygenhoven, D. Kiener, G. Dehm, Crystal rotation in Cu single crystal micro pillars: insitu Laue and electron backscatter diffraction, Applied Physical Letters, 92(7), 071905, (2008).

C.N. Borca, S. Canulescu, F. Loviat, T. Lippert, D. Grolimund, M. Döbeli, J. Wambach, A. Wokaun, Analysis of the electronic configuration of the pulsed laser deposited La0.7Ca0.3MnO3 thin films, Applied Surface Science, 254(4), 1352-1355, (2007).

R. Maaß, S. Van Petegem, H. Van Swygenhoven, P.M. Derlet, C.A. Volkert, D. Grolimund, Time resolved Laue diffraction of deforming micropillars, Physical Review Letters, 99 (14): Art. No. 145505, (2007).

A. Froideval, R. Iglesias, M. Samaras, S. Schuppler, P. Nagel, D. Grolimund, M. Victoria, W. Hoffelner, Magnetic and structural properties of Fe-Cr alloys, Physical Review Letters, 99, 237201(1-4), (2007).

P. Beaud, S. L. Johnson, A. Streun, R. Abela, D. Abramsohn, D. Grolimund, F. Krasniqi, T. Schmidt, V. Schlott, G. Ingold, Spatiotemporal Stability of Femtosecond Hard X-ray Undulator Radiation Studied by Control of Coherent Optical Phonons, Physical Review Letters, 99, 174801(1-4), (2007).

M. Vespa, E. Wieland, R. Dähn, D. Grolimund, A.M. Scheidegger, Determination of the elemental distribution and chemical speciation in highly heterogeneous cementitious materials using synchrotron-based micro-spectroscopic techniques, Cement and Concrete Research, 37, 1473-1482, (2007).

G. Ingold, P. Beaud, S.L. Johnson, D. Grolimund, V. Schlott, T. Schmidt, A. Streun, FEMTO: A sub-ps tunable hard x-ray undulator source for laser/x-ray pump-probe experiments at the SLS, Synchroton Radiation News, 20, 5, 35-39, (2007).

R. Maaß, S. Van Petegem, D. Grolimund, H. Van Swygenhoven, M.D. Uchic, A strong micropillar containing a low angle grain boundary, Applied Physical Letters, 91, 131909(1-3), (2007).

M. Vespa, R. Dähn, D. Grolimund, E. Wieland, A.M. Scheidegger, Co speciation in hardened cement past: A macro- and micro-spectroscopic investigation, Environ. Sci. Technol., 41/6, 1902-1908, (2007).

K. Jefimovs, O. Bunk, F. Pfeiffer, D. Grolimund, J. F. van der Veen, C. David, Fabrication of Fresnel zone plates for hard X-rays, Microelectronic Engineering, 84, 1467–1470, (2007).

W. Gawelda, V. Pham, M. Benfatto, Y. Zaushitsyn, M. Kaiser, D. Grolimund, S.L. Johnson, R. Abela, A. Hauser, M. Chergui, Ch. Bressler, Structural Determination of a Short-lived Iron(II) Complex by Picosecond X-ray Absorption Spectroscopy, Physical Review Letters, 98, 057401(1-4), (2007).

W. Gawelda, V. T. Pham, A. El Nahhas, M. Kaiser, Y. Zaushitsyn, S.L. Johnson, D. Grolimund, R. Abela, A. Hauser, C. Bressler, M. Chergui, Capturing Transient Electronic and Molecular Structures in Liquids by Picosecond X-Ray Absorption Spectroscopy, American Institute of Physics CP882 - X-ray Absorption Fine Structure—XAFS 13, 31-36, (2007)

V.-T. Pham, W. Gawelda, Y. Zaushitsyn, M. Kaiser, D. Grolimund, S.L. Johnson, R. Abela, Ch. Bressler, M Chergui, Observation of the Solvent Shell Reorganization around Photoexcited Atomic Solutes by Picosecond X-ray Absorption Spectroscopy, J. Am. Chem. Soc., 129(6), 1530-1531 (Communication), (2007).

G. Ingold, P. Beaud, S. Johnson, A. Streun, R. Abela, A. Al-Adwan, D. Abrahamson, M. Boege, D. Grolimund, A. Keller, L. Rivkin, T. Schilcher, T. Schmidt, V. Schlott, L. Schulz, F. Van der Veen, D. Zimoch, Sub-picosecond tunable hard x-ray undulator source for laser/x-ray pump-probe experiments, American Institute of Physics CP 879, 1198-2002 (2006).

R. Maaß, D. Grolimund, S. Van Petegem, M. Willimann , M. Jensen, H. Van Swygenhoven, T. Lehnert, M.A.M. Gijs, C.A. Volkert, E.T. Lilleodden, R. Schwaiger, Defect structure in micropillars using X-ray microdiffraction, Applied Physical Letters, 89, 151905(1-3), (2006). M. Vespa, R. Dähn, D. Grolimund, M. Harfouche, E. Wieland, A.M. Scheidegger, The influence of hydration time on Ni uptake by cement, Czechoslovak Journal of Physics, 56, D596-D607 (2006).

M. Vespa, R. Dähn, E. Gallucci, D. Grolimund, E. Wieland, A.M. Scheidegger, Micro-scale investigation of Ni uptake by cement using a combination of scanning electron microscopy and synchrotron-based techniques, Environ. Sci. Technol., 40, 7702-7709, (2006).

F. Farges, M.-P. Etcheverry, A.M. Scheidegger, D. Grolimund, Speciation and weathering of copper in “copper red ruby” medieval stained glasses from the Tours cathedral (XII-XIVth centuries), Applied Geochemistry, 21, 1715-1731, (2006).

D. Grolimund, M. Borkovec, Release of Colloidal Particles in Natural Porous Media by Monovalent and Divalent Cations, J. Contam. Hydrol., 87, 155-175, (2006).

A.M. Scheidegger, M. Vespa, E. Wieland, M. Harfouche, D. Grolimund, R. Dähn, Micro-scale chemical speciation of highly heterogeneous cementitious materials using synchrotron-based x-ray absorption spectroscopy. Published in ‘Highlights of analytical Chemistry in Switzerland’, Chimia, 60 (3), 149-149, (2006).

M. Vespa, R. Dähn, D. Grolimund, M. Harfouche, E. Wieland, A.M. Scheidegger, Spectroscopic investigation of Ni in hardened cement paste, Environ. Sci. Technol., 40 (7), 2275-2282, (2006).

A.M. Scheidegger, M. Vespa, D. Grolimund, E. Wieland, M. Harfouche, I. Bonhoure, R. Dähn, The use of (micro)-x-ray absorption spectroscopy in cement research, Waste Management, 26 (7), 699-705, (2006).

F. Farges, S. Djanarthany, S. de Wispelaere, M. Munoz, B. Magassouba, A. Haddi, M. Wilke, Ch. Schmidt, M. Borchert, P. Trocellier, W., Crichton, A. Simionovici, P-E. Petit, M. Mezouard, M.P. Etcheverry, I. Pallot-Frossard, J.R. Bargar, G.E. Brown, Jr., D. Grolimund, A.M. Scheidegger, Water in Silicate Glasses and Melts of Environmental Interest: From Volcanoes to Cathedrals, Physics and Chemistry of Glasses, 46 (4), 350-353 (2005).

M. Vespa, R. Daehn, D. Grolimund, M. Harfouche, E. Wieland, A.M. Scheidegger, Speciation of heavy metals in cement-stabilized waste forms: A micro-spectroscopic study Journal of Geochemical Exploration, 88 (1-3), 77-80, (2006).

A.M. Scheidegger, D. Grolimund, C. R. Cheeseman, R. D. Rogers, Micro-spectroscopic investigations of highly heterogeneous waste repository materials, Journal of Geochemical Exploration, 88 (1-3), 59-63, (2006).

D. Grolimund, M. Borkovec, Colloid-Facilitated Transport of Strongly Sorbing Contaminants in Natural Porous Media: Mathematical Modeling and Laboratory Column Experiments, Environ. Sci. Technol., 39 (17): 6378-6386, (2005).

W. Gawelda, C. Bressler, M. Saes, M. Kaiser, A.N. Tarnovsky, D. Grolimund, S.L. Johnson, R. Abela,and M. Chergui, Picosecond Time-Resolved X-Ray Absorption Spectroscopy of Solvated Organometallic Complexes, Physica Scripta, T115, 102-106, (2005).

D. Grolimund, M. Senn, M. Trottmann, M. Janousch, I. Bonhoure, A.M. Scheidegger, M. Marcus, Shedding new Light on Historical Metal Samples using Micro-focused Synchrotron X-Ray Fluorescence and Spectroscopy, Spectrochimica Acta Part B: Atomic Spectroscopy, 59, 1627-1635, (2004).

W. Gawelda, M. Saes, M. Kaiser, A. Tarnovsky, S.-L. Johnson, D. Grolimund, R. Abela, M. Chergui, C. Bressler, Structural dynamics and electronic structure changes probed with lasers and X-rays, p. 353ff, in “Femtochemistry and Femtobiology: Ultrafast Events in Molecular Science” edited by M.M. Martin and J.T. Hynes, Elsevier, (2004)

M. Saes, Ch. Bressler, F. van Mourik, W. Gawelda, M. Kaiser, M. Chergui, D. Grolimund, R. Abela, Th.E. Glover, Ph.A. Heimann, R.W. Schoenlein, S.L. Johnson, A.M. Lindenberg, R.W. Falcone, A Setup for Ultrafast Time-Resolved X-Ray Absorption Spectroscopy, Review of Scientific Instruments, 75, 24-30, (2004).

M. Saes, W. Gawelda, M. Kaiser, A. Tarnovsky, Ch. Bressler, M. Chergui, S.L. Johnson, D. Grolimund, R. Abela, Picosecond Time-Resolved X-Ray Absorption Spectroscopy of Solvated Organometallic Complexes, Synchrotron Radiation News (invited), 16, 12, (2003).

A.M. Scheidegger, D. Grolimund, D. Cui, J. Devoy, K. Spahiu, P. Wersin, I. Bonhoure, M. Janousch, Reduction of selenite on iron surfaces: A micro-spectroscopic study, J. Phys. IV, 104, 417, (2003).

M. Saes, Ch. Bressler, R. Abela, D. Grolimund, S.L. Johnson, P.A. Heimann, M. Chergui, Observing Transient Chemical Changes by Ultrafast X-ray Absorption Spectroscopy, Physical Review Letters, 90, 047403, (2003).

Ch. Bressler, M. Saes, M. Chergui, D. Grolimund, R. Abela, Towards Structural Dynamics Research with Ultrashort Pulse Lasers and Synchrotron Radiation, in: Femtochemistry and Femtobiology, A. Douhal and J. Santamaria, Eds., World Scientific, Singapore, 449, (2002).

Ch. Bressler, M. Saes, M. Chergui, D. Grolimund, R. Abela, Ph. Pattison, Towards Structural Dynamics in Condensed Chemical Systems Exploiting Ultrafast Time-Resolved X-Ray Absorption Spectroscopy, J. Chem. Phys., 116, 2955, (2002).

V.M. Vulava, R. Kretzschmar, K. Barmettler, A. Voegelin, D. Grolimund, M. Borkovec, Cation Competition in a Natural Subsurface Material: Prediction of Transport Behavior, Water Resources Res., 38, 7-1, (2002).

T.P. Trainor, J.P. Fitts, A. S. Templeton, D. Grolimund, G.E. Brown, Jr., Grazing-Incidence XAFS Study of Aqueous Zn(II) Sorption on α-Al2O3 Single Crystals, J. Colloid and Interface Science, 244, 239, (2001).

D. Grolimund, M. Elimelech, M. Borkovec, Aggregation and Deposition Kinetics of Mobile Colloidal Particles in Natural Porous Media, Colloids and Surfaces A, 191, 179, (2001).

D. Grolimund, K. Barmettler, M. Borkovec, Release and Transport of Colloidal Particles in Natural Porous Media: 2. Experimental Results and Effects of Ligands, Water Resources Res., 37, 571, (2001).

D. Grolimund, M. Borkovec, Release and Transport of Colloidal Particles in Natural Porous Media: 1. Modeling, Water Resources Res., 37, 559, (2001).

G.E. Brown, Jr., S.A. Chambers, J.E. Amonette, J.R. Rustad, T. Kendelewicz, P. Liu, C. Doyle, D. Grolimund, N.S. Foster-Mills, S.A. Joyce, S. Thevuthasan, Interaction of Aqueous Chromium Ions with Iron Oxide Surfaces, in Nuclear Site Remediation, ACS Symposium Series, No. 778, P.G. Eller, and W. Heineman, eds., pp. 212-246, Oxford University Press, (2001).

V.M. Vulava, U. Rusch, R. Kretzschmar, D. Grolimund, M. Borkovec, J.C. Westall, Cation Competition in a Natural Subsurface Material: I. Modeling of Adsorption Equilibria, Environ. Sci. Technol., 34, 2149, (2000).

D. Grolimund, M. Borkovec, Long-term Release of Colloidal Particles from Natural Porous Media, Environ. Sci. Technol., 33, 4054, (1999).

D. Grolimund, T.P. Trainor, J.P. Fitts, T. Kendelewicz, P. Liu, S.A. Chambers, G.E. Brown, Jr., Identification of Cr Species at the Solution-Hematite Interface after Cr(VI)-Cr(III) Reduction using GI-XAFS and Cr L-Edge NEXAFS, Journal of Synchrotron Radiation, 6, 612, (1999).

T.P. Trainor, J.P. Fitts, D. Grolimund, J.R. Bargar, G.E. Brown, Jr., Grazing-Incidence XAFS Studies of Aqueous Zn(II) on Sapphire Single Crystals, Journal of Synchrotron Radiation, 6, 618, (1999).

J.P. Fitts, T.P. Trainor, D. Grolimund, J.R. Bargar, G.A. Parks, G.E. Brown, Jr., Grazing-Incidence XAFS Investigation of Cu(II) Sorption Products at the Oxide-Water Interface, Journal of Synchrotron Radiation, 6, 627, (1999).

D. Freese, P.G. Weidler, D. Grolimund, H. Sticher, A Flow-Through Reactor with an Infinite Sink for Monitoring Desorption Processes, J. Environ. Qual., 28, 537, (1999).

D. Grolimund, M. Elimelech, M. Borkovec, R. Kretzschmar, K. Barmettler, H. Sticher, Transport of in-situ Mobilized Colloidal Particles in a Natural Porous Material, Environ. Sci. Technol., 32, 3562, (1998).

R. Kretzschmar, K. Barmettler, D. Grolimund, Y. Yan, M. Borkovec, H. Sticher, Experimental Determination of Colloid Deposition Rates and Attachment Efficiencies in Natural Porous Media, Water Res. Res., 33, 1129, (1997).

D. Grolimund, M. Borkovec, K. Barmettler, H. Sticher, Colloid Facilitated Transport of Strongly Sorbing Contaminants in Natural Porous Media: A Laboratory Column Study, Research Communication, Environ. Sci. Technol., 30, 3118, (1996).

D. Grolimund, M. Borkovec, P. Federer, H. Sticher, Measurement of Sorption Isotherms with Flow-Through Reactors, Environ. Sci. Technol., 29, 2317, (1995).

M. Cernik, K. Barmettler, D. Grolimund, W. Rohr, M. Borkovec, H. Sticher, Cation Transport in Natural Porous Media on Laboratory Scale: Multicomponent Effects, J. Contam. Hydrol., 16, 319, (1994).

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D. Grolimund, K. Barmettler, M. Borkovec, Colloid Facilitated Transport in Natural Porous Media: Fundamental Phenomena and Modeling, invited contribution, Colloidal Transport in Porous Media, F. H. Frimmel, F. von der Kammer, H.-C. Flemming, Eds., Springer Verlag, pp. 3-27, (2007)

R. Kretzschmar, M. Borkovec, D. Grolimund, M. Elimelech, Role of Mobile Colloids in Contaminant Transport through Subsurface Porous Media, Advances in Agronomy, 66, 121, (1999).

D. Grolimund, H.A.O Wang, L.R. Van Loon, F. Marone, N. Diaz, A. Kaestner, A. Jakob, Microscopic Chemical Imaging: A Key to Understand Ion Mobility in Tight Formations, CMS Workshop Lecture Series, Chapter 9, 105-128, in: Filling the Gaps – from Microscopic Pore Structures to Transport Properties in Shales (T. Schäfer, R. Dohrmann, and H.C. Greenwell, editors). CMS Workshop Lectures, 21. The Clay Minerals Society, Chantilly, Virginia, USA. ISBN - 978-1-881208-46-4, (2016).

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D. Guenther, D. Grolimund, H.A.O. Wang (inventors), Ablation cell for laser ablation of sample material has sample chamber which receives sample in state which enables laser beam to enter sample chamber through lateral window and lateral opening, and to impinge on sample surface, Patent Number(s): WO2014146724-A1; US2014287953-A1; AU2013382989-A1; CA2907483-A1; WO2014147260-A1; CA2907573-A1, Patent Assignee Name(s) and Code(s): ETH ZUERICH (ETHZ-Non-standard), SCHERRER INST PAUL (SCHE-Non-standard), GUENTHER D(GUEN-Individual), GROLIMUND D(GROL-Individual), WANG H(WANG-Individual). Derwent Primary Accession Number: 2014-R61808 [82], (2014).

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M. Lebugle, G. Seniutinas, V.A. Guzenko, D. Grolimund, C. David, A tunable kinoform X ray beamsplitter, submitted, (2017).

F. Sava, C.N. Borca, A.C. Galca, G. Socol, D. Grolimund, C. Mihai, A. Velea, Structural characterization and thermal stability of SnSe\GaSb stacked films, submitted, (2017).

S.A. Sinclair, M.J. Haydon, C. Larue, L. Bonk, H. Castillo, R. Stein, D. Grolimund, D. Begerow, U. Neumann, U. Krämer, Etiolated seedling development requires a small cell wall-derived dark signal, submitted, (2017).

D. Ferreira Sanchez, A.S. Simionovici, L. Lemelle, V. Cuartero Yague, O. Mathon, S. Pascarelli, A. Bonnin, R. Shapiro, K. Konhauser, D. Grolimund, P. Bleuet, Fast Novel 2D/3D Microanalysis by Energy Dispersive X-ray Absorption Spectroscopy Tomography, submitted, (2017)

Abreu, I., Saéz, Á., Castro-Rodríguez, R. Escudero, V., Rodríguez-Haas, B., Senovilla, M., Larue, C., Grolimund, D, Tejada-Jiménez, M., Imperial, J., González-Guerrero, M., Medicago truncatula Zinc-Iron Permease6 provides zinc to rhizobia-infected nodule cells, submitted, (2017).

H. Yang, D. Cui, D. Grolimund, V. Rondinella, M. Amme, C. Kutahyali, K. Spahiu, Reductive precipitation of neptunium on iron surface under anaerobic conditions, submitted, (2017).

C.L. Corkhill, D.E. Crean, D.J. Bailey, C. Makepeace, M.C. Stennett, R. Tappero, D. Grolimund, N.C. Hyatt, Natural attenuation of uranium by arsenic at an abandoned uranium mine, South Terras, submitted,(2017).

Y. Fukatsu, Luc R. van Loon, Amir Shafizadeh, D. Grolimund, Y. Ikeda, T. Tsukahara, Effect of Celestite Precipitation in Compacted Illite on the Diffusion of HTO, 36Cl-, and 22Na+, submitted to Energy Procedia, (2017).

J, Ihli, R.R. Jacob, M. Holler, M. Guizar Sicairos, A. Diaz, J.C. da Silva, D. Ferreira Sanchez, F. Krumeich, D. Grolimund, M. Taddai, C. Borca, W.C. Cheng, Y.Y. Shu, A. Menzel, J.A. van Bokhoven, Deactivation of Fluid Catalytic Cracking Catalysts a 3D View of Structural Changes, submitted, (2016).

C. Civardi, D. Grolimund, M. Schubert, P. Wick, F.W.M.R. Schwarze, Micronized copper-treated wood: copper remobilization into spores from the copper-tolerant wood-destroying fungus Rhodonia placenta, near submission, (2017).

F. Gervilla, M.P. Asta, I. Fanlo, D. Grolimund, V.A. Samson, V. Colas, J. M. González-Jiménez, T.N. Kerestedjian, I. Sergeeva, Monitoring the diffusion of Fe2+ and Fe3+ during the formation of ferrian chromite: a μXANES study, near submission, (2017).

-- Main.DanielGrolimund - 17 Jul 2014