Claire Villevieille

Clairenew.jpg
Position Group leader
Address Paul Scherrer Institut
OVGA/123
5232 Villigen PSI
Switzerland
Phone +41 56 310 2410
E-mail claire.villevieille@psi.ch

CV

Field of competence

  • in situ Characterizations applied to batteries (Li-ion, Na-ion, Li-S and all-solid-state)
  • Solid state chemistry
  • X-ray diffraction
  • Mössbauer spectroscopy (57Fe, 119Sn, 121Sb)
  • Neutron diffraction
  • X-ray absorption

Awards

  • International Battery Association (IBA) Early Career Award 2018
  • ISE Prize for Electrochemical Materials Science 2017
  • RS2E, Young Energy Storage Scientist (YESS) award 2016
  • Young Investigator Award IMLB 2012
  • Poster Award GFECI 2009
  • Master Thesis Price 2006

Education

  • 2004: Bachelor degree Physics & Chemistry, Université de Nîmes, France
  • 2006: Master degree Materials Science, Université de Montpellier, France
  • 2009: PhD Thesis, Electrochemistry of Li-Ion batteries, AIME Laboratory, Montpellier, France "Insertion and/or conversion materials used as negative electrode for Li-ion batteries"

Publications



  • A cylindrical cell for operando neutron diffraction of Li-Ion battery electrode materials L. Vitoux, M. Reichardt, S. Sallard, P. Novák, D. Sheptyakov, C. Villevieille
    Front. Energ. Res. 6 (76), (2018)
    DOI: 10.3389/fenrg.2018.00076OG-5410 , OG-5411
  • Phosphorus anionic redox activity revealed by operando P K-edge X-ray absorption spectroscopy on diphosphonate-based conversion materials in Li-ion batteries S. Schmidt, S. Sallard, C. Borca. T. Huthwelker, P. Novák, C. Villevieille
    Chem. Commun. 54, 4939-4942 (2018)
    DOI: 10.1039/C8CC01350KOG-5410 , OG-5411
  • Monitoring the chemical and electronic properties of electrolyte-electrode interfaces in all-solid-state batteries using operando X-ray photoelectron spectroscopy X. Wu, C. Villevieille, P. Novák, M. El Kazzi
    Phys. Chem. Chem. Phys. 20, 11123-11129 (2018)
    DOI: 10.1039/C8CP01213JOG-5410 , OG-5411 , OG-5414
  • Electrochemical performance of all-solid-state Li-ion batteries based on garnet electrolyte using silicon as a model electrode G. Ferraresi, M. El Kazzi, L. Czornomaz, C.-L. Tsai, S. Uhlenbruck, C. Villevieille
    ACS Energy Lett. 3, 1006-1012 (2018)
    DOI: 10.1021/acsenergylett.8b00264OG-5410 , OG-5411 , OG-5414
  • SnO2 model electrode cycled in Li-ion battery reveals the formation of Li2SnO3 and Li8SnO6 phases through conversion reactions G. Ferraresi, C. Villevieille, I. Czekaj, M. Horisberger, P. Novák, M. El Kazzi
    ACS Appl. Mater. & Interfaces 10 (10), 8712-8720 (2018)
    DOI: 10.1021/acsami.7b19481OG-5410 , OG-5411 , OG-5414
  • Do imaging techniques add real value to the development of better post-Li-ion batteries? J. Conder, C. Marino, P. Novák, C. Villevieille
    J. Mater. Chem. A 6, 3304-3327 (2018)
    DOI: 10.1039/C7TA10622JOG-5410 , OG-5411
  • Multiple redox couples cathode material for Li-ion battery: Lithium chromium phosphate M. Reichardt, S. Sallard, C. Marino, D. Sheptyakov, P. Novák, C. Villevieille
    J. Energy Storage 15, 266-273 (2018)
    DOI: 10.1016/j.est.2017.12.001OG-5410 , OG-5411
  • Crystal structure evolution via operando neutron diffraction during long-term cycling of a customized 5 V full Li-ion cylindrical cell LiNi0.5Mn1.5O4vs. graphite L. Boulet-Roblin, D. Sheptyakov, P. Borel, C. Tessier, P. Novák, C. Villevieille
    J. Mater. Chem. A 5, 25574-25582 (2017)
    DOI: 10.1039/C7TA07917FOG-5410 , OG-5411
  • Elucidation of reaction mechanisms of Ni2SnP in Li-ion and Na-ion systems C. Marino, N. Dupré, C. Villevieille
    J. Power Sources 365, 339-347 (2017)
    DOI: 10.1016/j.jpowsour.2017.08.096OG-5410 , OG-5411
  • Interface and safety properties of phosphorus-based negative electrodes in Li-ion batteries C. Marino, M. El Kazzi, E.J. Berg, M. He, C. Villevieille
    Chem. Mater. 29 (17), 7151-7158 (2017)
    DOI: 10.1021/acs.chemmater.7b01128OG-5410 , OG-5411 , OG-5412 , OG-5414
  • Electrochemical impedance spectroscopy of a Li–S battery: Part 2. Influence of separator chemistry on the lithium electrode/electrolyte interface J. Conder, C. Villevieille, S. Trabesinger, P. Novák, L. Gubler, R. Bouchet
    Electrochim. Acta 255, 379-390 (2017)
    DOI: 10.1016/j.electacta.2017.09.148OG-5410 , OG-5411 , OG-5413 , OG-5421
  • Improved electrochemical performances of Li-rich nickel cobalt manganese oxide by partial substitution of Li+ by Mg2+ S. Sallard, D. Sheptyakov, C. Villevieille
    J. Power Sources 359, 27–36 (2017)
    DOI: 10.1016/j.jpowsour.2017.05.028OG-5410 , OG-5411
  • Surface and morphological investigation of the electrode/electrolyte properties in an all-solid-state battery using a Li2S-P2S5 solid electrolyte X. Wu, M. El Kazzi, C. Villevieille
    J. Electroceram. 38, 1-8 (2017)
    DOI: 10.1007/s10832-017-0084-zOG-5410 , OG-5411 , OG-5414
  • Elucidation of the reaction mechanisms of isostructural FeSn2 and CoSn2 negative electrodes for Na-ion batteries L.O. Vogt, C. Villevieille
    J. Mater. Chem. A 5, 3865-3874 (2017)
    DOI: 10.1039/C6TA10535AOG-5410 , OG-5411
  • Direct observation of lithium polysulfides in lithium–sulfur batteries using operando X-ray diffraction J. Conder, R. Bouchet, S. Trabesinger, C. Marino, L. Gubler, C. Villevieille
    Nature Energy 2, 17069 (2017)
    DOI: 10.1038/nenergy.2017.69OG-5410 , OG-5411 , OG-5421
  • Electrochemical impedance spectroscopy of a Li–S battery: Part 1. Influence of the electrode and electrolyte compositions on the impedance of symmetric cells J. Conder, C. Villevieille, S. Trabesinger, P. Novák, L. Gubler, R. Bouchet
    Electrochim. Acta 244, 61-68 (2017)
    DOI: 10.1016/j.electacta.2017.05.041OG-5410 , OG-5411 , OG-5413 , OG-5421
  • Ligand influence in Li-ion battery hybrid active materials: Ni methylenediphosphonate vs. Ni dimethylamino methylenediphosphonate S. Schmidt, S. Sallard, D. Sheptyakov, P. Novák, C. Villevieille
    Chem. Commun. 53, 5420-5423 (2017)
    DOI: 10.1039/C7CC01982COG-5410 , OG-5411
  • Impact of cobalt content in Na0.67MnxFeyCozO2 (x + y + z = 1), a cathode material for sodium ion batteries C. Marino, E. Marelli, C. Villevieille
    RSC Adv. 7 (23), 13851-13857 (2017)
    DOI: 10.1039/C7RA00566KOG-5410 , OG-5411
  • Fe and Co methylene diphosphonates as conversion materials for Li-ion batteries S. Schmidt, S. Sallard, D. Sheptyakov, M. Nachtegaal, P. Novák, C. Villevieille
    J. Power Sources 342, 879-885 (2017)
    DOI: 10.1016/j.jpowsour.2016.12.090OG-5410 , OG-5411
  • CuSbS2 as a negative electrode material for sodium ion batteries C. Marino, T. Block, R. Pöttgen, C. Villevieille
    J. Power Sources 342, 616-622 (2017)
    DOI: 10.1016/j.jpowsour.2016.12.100OG-5410 , OG-5411
  • MnSn2 negative electrodes for Na-ion batteries: a conversion-based reaction dissected L.O. Vogt, C. Villevieille
    J. Mater. Chem. A, 4, 19116–19122 (2016)
    DOI: 10.1039/C6TA07788AOG-5410 , OG-5411
  • Elucidating the surface reactions of an amorphous Si thin film as a model electrode for Li-Ion batteries G. Ferraresi, L. Czornomaz, C. Villevieille, P. Novák, M. El Kazzi
    ACS Appl. Mater. Interfaces 8 (43), 29791-29798 (2016)
    DOI: 10.1021/acsami.6b10929OG-5410 , OG-5411 , OG-5414
  • Mechanism of the carbonate-based-electrolyte degradation and its effects on the electrochemical performance of Li1+x(NiaCobMn1-a-b)1-xO2 cells H.-J. Peng, C. Villevieille, S. Trabesinger, H. Wolf, K. Leitner, P. Novák
    J. Power Sources 335, 91-97 (2016)
    DOI: 10.1016/j.jpowsour.2016.10.031OG-5410 , OG-5411 , OG-5413
  • FeSn2 and CoSn2 electrode materials for Na-Ion batteries L.O. Vogt, C. Villevieille
    J. Electrochem. Soc. 163 (7), A1306-A1310 (2016)
    DOI: 10.1149/2.0791607jesOG-5410 , OG-5411
  • Operando neutron powder diffraction using cylindrical cell design: The case of LiNi0.5Mn1.5O4 vs Graphite L. Boulet-Roblin, P. Borel, D. Sheptyakov, C. Tessier, P. Novák, C. Villevieille
    J. Phys. Chem. C 120 (31), 17268-17273 (2016)
    DOI: 10.1021/acs.jpcc.6b05777OG-5410 , OG-5411
  • Versatile approach combining theoretical and experimental aspects of Raman spectroscopy to investigate battery materials: The case of the LiNi0.5Mn1.5O4 spinel L. Boulet-Roblin, C. Villevieille, P. Borel, C. Tessier, P. Novák, M. Ben Yahia
    J. Phys. Chem. C 120 (30), 16377–16382 (2016)
    DOI: 10.1021/acs.jpcc.6b04155OG-5410 , OG-5411
  • Magnetically aligned graphite electrodes for high-rate performance Li-ion batteries J. Billaud, F. Bouville, T. Magrini, C. Villevieille, A.R. Studart
    Nature Energy 1, 16097 (2016)
    DOI: 10.1038/nenergy.2016.97OG-5410 , OG-5411
  • Effects of solvent, lithium salt, and temperature on stability of carbonate-based electrolytes for 5.0 V LiNi0.5Mn1.5O4 electrodes M. He, L. Boulet-Roblin, P. Borel, C. Tessier, P. Novák, C. Villevieille, E.J. Berg
    J. Electrochem. Soc. 163 (2), A83-A89 (2016)
    DOI: 10.1149/2.0201602jesOG-5410 , OG-5411 , OG-5412
  • Electrode engineering of conversion-based negative electrodes for Na-ion batteries L.O. Vogt, C. Marino, C. Villevieille
    Chimia 69 (12), 729-733 (2015)
    DOI: 10.2533/chimia.2015.729OG-5411
  • Rechargeable batteries: Grasping for the limits of chemistry E.J. Berg, C. Villevieille, D. Streich, S. Trabesinger, P. Novák
    J. Electrochem. Soc. 162 (14), A2468-A2475 (2015)
    DOI: 10.1149/2.0081514jesOG-5410 , OG-5411 , OG-5412 , OG-5413
  • Lithium chromium pyrophosphate as an insertion material for Li-ion batteries M. Reichardt, S. Sallard, P. Novák, C. Villevieille
    Acta Cryst. B71, 661-667 (2015)
    DOI: 10.1107/S2052520615017539OG-5410 , OG-5411
  • Lithium iron methylenediphosphonate: A model material for new organic–inorganic hybrid positive electrode materials for Li ion batteries S. Schmidt, D. Sheptiakov, J.-C. Jumas, M. Medarde, P. Benedek, P. Novák, S. Sallard, C. Villevieille
    Chem. Mater. 27 (23), 7889–7895 (2015)
    DOI: 10.1021/acs.chemmater.5b02595OG-5410 , OG-5411
  • Freeze-dryed LixMoO3 nanobelts used as cathode materials for lithium-ion batteries: A bulk and interface study C. Villevieille, A. Gorzkowska-Sobas, H. Fjellvåg, P. Novák
    J. Power Sources 297, 276-282 (2015)
    DOI: 10.1016/j.jpowsour.2015.07.082OG-5410 , OG-5411
  • Consequences of electrolyte degradation for the electrochemical performance of Li1+x(NiaCobMn1-a-b)1-xO2 H.-J. Peng, S. Urbonaite, C. Villevieille, H. Wolf, K. Leitner, P. Novák
    J. Electrochem. Soc., 162 (13), A7072-A7077 (2015)
    DOI: 10.1149/2.0061513jesOG-5410 , OG-5411 , OG-5413
  • A low-temperature benzyl alcohol/Benzyl mercaptan synthesis of iron oxysulfide/iron oxide composite materials for electrodes in Li-ion batteries S. Sallard, E. Castel, C. Villevieille, P. Novák
    J. Mater. Chem. A 3, 16112 (2015)
    DOI: 10.1039/c5ta03155aOG-5410 , OG-5411
  • _In situ_ X-ray diffraction characterisation of Fe0.5TiOPO4 and Cu0.5TiOPO4 as electrode material for sodium-ion batteries P. Bleith, H. Kaiser, P. Novák, C. Villevieille
    Electrochim. Acta 176, 18–21 (2015)
    DOI: 10.1016/j.electacta.2015.06.105OG-5410 , OG-5411
  • Understanding inhomogeneous reactions in li-ion batteries: Operando synchrotron X-Ray diffraction on two-layer electrodes T. Sasaki, C. Villevieille, Y. Takeuchi, P. Novák
    Adv. Sci. 1500083 (2015)
    DOI: 10.1002/advs.201500083OG-5410 , OG-5411
  • Surface/Interface study on full xLi2MnO3{middle dot}(1 - x)LiMO2 (M = Ni, Mn, Co)/graphite cells L. Boulet-Roblin, M. El Kazzi, P. Novák, C. Villevieille
    J. Electrochem. Soc. 162, 7, A1297-A1300 (2015)
    DOI: 10.1149/2.0491507jesOG-5410 , OG-5411 , OG-5414
  • Understanding the interaction of the carbonates and binder in Na-Ion batteries: A combined bulk and surface study L.O. Vogt, M. El Kazzi, E. Jämstorp Berg, S. Pérez Villar, P. Novák, C. Villevieille
    Chem. Mater. 27, 1210-1216 (2015)
    DOI: 10.1021/cm5039649OG-5410 , OG-5411 , OG-5412 , OG-5414
  • Simultaneous in situ x‑ray absorption spectroscopy and x‑ray diffraction studies on battery materials: The case of Fe0.5TiOPO4 P. Bleith, W. van Beek, H. Kaiser, P. Novák, C. Villevieille
    J. Phys. Chem. C 119, 3466-3471 (2015)
    DOI: 10.1021/jp511042xOG-5410 , OG-5411
  • Influence of conversion material morphology on electrochemistry studied with operando x-ray tomography and diffraction C. Villevieille, M. Ebner, J.L. Gómez-Cámer, F. Marone, P. Novák, V. Wood
    Adv. Mater. 27, 1676-1681 (2015)
    DOI: 10.1002/adma.201403792OG-5410 , OG-5411 , OG-5413
  • MoS2 coating on MoO3 nanobelts: A novel approach for a high specific charge electrode for rechargeable Li-ion batteries C. Villevieille, X.-J. Wang, F. Krumeich, R. Nesper, P. Novák
    J. Power Sources 279, 636-644 (2015)
    DOI: 10.1016/j.jpowsour.2014.12.129OG-5410 , OG-5411
  • MSnS2 (M = Cu, Fe) electrode family as dual-performance electrodes for Li–S and Li–Ion batteries C. Villevieille, P. Novák
    J. Electrochem. Soc. 162, 3, A284-A287 (2015)
    DOI: 10.1149/2.0121503jesOG-5410 , OG-5411
  • Differential electrochemical mass spectrometry study of the interface of xLi2MnO3·(1−x)LiMO2 (M = Ni, Co, and Mn) Material as a positive electrode in Li-Ion batteries E. Castel, E.J. Berg, M. El Kazzi, P. Novak, C. Villevieille
    Chem. Mater. 26, 5051-5057 (2014)
    DOI: 10.1021/cm502201zOG-5410 , OG-5411 , OG-5412 , OG-5414
  • Elucidation of the reaction mechanism upon lithiation and delithiation of Cu0.5TiOPO4 P. Bleith, M. Valla, P. Novák, C. Villevieille
    J. Mater. Chem. A 2, 12513-12518 (2014).
    DOI: 10.1039/C4TA01627KOG-5410 , OG-5411
  • Reducing mass transfer effects on the kinetics of 5V HE-NCM electrode materials for Li-Ion batteries C. Villevieille, J.L. Gómez-Cámer, M. Hess, P. Novák
    J. Electrochem. Soc 161 (6), A871-A874 (2014).
    DOI: 10.1149/2.067405jesOG-5410 , OG-5411 , OG-5413
  • Bulk and surface analyses of ageing of a 5V-NCM positive electrode material for lithium-ion batteries C. Villevieille, P. Lanz, Ch. Bünzli, P. Novák
    J. Mater. Chem. A 2, 6488-6493 (2014).
    DOI: 10.1039/C3TA13112BOG-5410 , OG-5411 , OG-5412 , OG-5413
  • _Ex situ_ and in situ Raman microscopic investigation of the differences between stoichiometric LiMO2 and high-energy xLi2MnO3·(1–x)LiMO2 (M = Ni, Co, Mn) P. Lanz, C. Villevieille, P. Novák
    Electrochim. Acta 130, 206–212 (2014).
    DOI: 10.1016/j.electacta.2014.03.004OG-5410 , OG-5411 , OG-5412
  • Novel electrochemical cell designed for operando techniques and impedance studies C. Villevieille, T. Sasaki, P. Novák
    RSC Adv. 4, 6782-6789 (2014)
    DOI: 10.1039/C3RA46184JOG-5410 , OG-5411
  • A metastable b-sulfur phase stabilized at room temperature during cycling of high efficiency carbon fibre–sulfur composites for Li–S batteries C. Villevieille, P. Novák
    J. Mater. Chem. A 1, 13089-13092 (2013).
    DOI: 10.1039/c3ta13072jOG-5410 , OG-5411
  • Antimony based negative electrodes for next generation Li-ion batteries J.L. Gómez-Cámer, C. Villevieille, P. Novák
    J. Mater. Chem. A 1, 13011–13016 (2013).
    DOI: 10.1039/c3ta12762aOG-5410 , OG-5411 , OG-5413
  • Electrochemical activation of Li2MnO3 at elevated temperature investigated by in situ Raman microscopy P. Lanz, C. Villevieille, P. Novák
    Electrochim. Acta 109, 426-432 (2013).
    DOI: 10.1016/j.electacta.2013.07.130OG-5410 , OG-5411 , OG-5412
  • Circular in situ neutron powder diffraction cell for study of reaction mechanism in electrode materials for Li-ion batteries V.A. Godbole, M. Hess, C. Villevieille, H. Kaiser, J.-F. Colin, P. Novák
    RSC Adv. 3, 757-763 (2013).
    DOI: 10.1039/c2ra21526hOG-5410 , OG-5411
  • Effect of metal ion and ball milling on the electrochemical properties of M0.5TiOPO4 (M = Ni, Cu, Mg)
    V.A. Godbole, C. Villevieille, P. Novák
    Electrochim. Acta 93, 179-188 (2013).
    DOI: 10.1016/j.electacta.2013.01.104OG-5410 , OG-5411
  • Ammonolyzed MoO3 nanobelts as novel cathode material of rechargeable Li-ion batteries X.-J. Wang, R. Nesper, C. Villevieille , P. Novák
    Adv. Energy Mater. 3, 606–614 (2013).
    DOI: 10.1002/aenm.201200692OG-5410 , OG-5411
  • Influence of cut-off potential on the electrochemistry of M0.5TiOPO4 (M=Fe, Cu) synthesized by a new route P. Bleith, P. Novák, C. Villevieille
    J. Electrochem. Soc. 160, A1534-A1538 (2013).
    DOI: 10.1149/2.096309jesOG-5410 , OG-5411
  • A structural and electrochemical study of Ni 0.5TiOPO 4 synthesized via modified solution route. V. A. Godbole, C. Villevieille, H. H. Sommer, J. F. Colin, and P. Novák
    Electrochimica Acta 77 (2012) 244-249
    DOI: 10.1016/j.electacta.2012.05.094OG-5410 , OG-5411
  • Self supported nickel antimonides based electrode for Li ion battery C. Villevieille, C. M. Ionica-Bousquet, A. De Benedetti, F. Morato, J.F. Pierson, P. Simon, and L. Monconduit
    Solid State Ionics 192 (2011) 298
    DOI: 10.1016/j.ssi.2010.03.019OG-5411
  • Comparative study of NiSb2 and FeSb2 as negative electrode for li-ion batteries C. Villevieille, C. M. Ionica-Bousquet, B. Fraisse, D. Zitoun, M. Womes, J.C. Jumas, and L. Monconduit
    Solid State ionics 192 (2011) 351
    DOI: 10.1016/j.ssi.2010.04.029OG-5411
  • Modified tridoped Li2Ti3O7 ramsdellite electrode for Li-ion batteries C. Villevieille, M. Van Thournout, C. Tessier, J. Olivier-Fourcade, J.C. Jumas, and L. Monconduit
    Electrochemica Acta 55 (2010) 7080
    DOI: 10.1016/j.electacta.2010.06.052OG-5411
  • Direct evidence of morphological changes in conversion type electrodes in Li-ion battery by acoustic emission C. Villevieille, M. Boinet, L. Monconduit
    Electrochemistry Communications 12 (2010) 1336
    DOI: 10.1016/j.elecom.2010.07.014OG-5411
  • A new ternary Li4FeSb2 structure formed upon discharge of the Fesb2/Li cell C. Villevieille, B. Fraisse, M. Womes, J.C. Jumas, L. Monconduit
    Journal of Power Sources 189 (2009) 324
    DOI: 10.1016/j.jpowsour.2008.08.089OG-5411
  • The good reactivity of lithium with nanostructured copper phosphide C. Villevieille, F. Robert, P.L. Taberna, L. Bazin, P.Simon, L. Monconduit.
    Journal of Materials Chemistry 18 (2008) 5956
    DOI: 10.1039/B810841BOG-5411
  • 121Sb Mössbauer spectroscopy of the electrochemical reaction of NiSb2 vs Lithium C. Villevieille, C. Ionica-Bousquet, J.C. Jumas, L. Monconduit.
    Hyperfine Interactions 187 (2008) 71
    DOI: 10.1007/s10751-008-9865-8OG-5411
  • Nanostructured transition metal phosphide as negative electrode for lithium-ion batteries S. Boyanov, K. Annou, C. Villevieille, M. Pelosi, D. Zitoun, L. Monconduit.
    Ionics 14 (2008) 183
    DOI: 10.1007/s11581-007-0170-3OG-5411
  • NiSb2 as negative electrode for Li-ion batteries. An original conversion reaction C. Villevieille, C. Ionica-Bousquet, B. Ducourant, J.C. Jumas, L. Monconduit.
    Journal of Power Sources 172 (2007) 388
    DOI: 10.1016/j.jpowsour.2007.06.256OG-5411

Patents

  • Negative Electrode Material for Li-ion Batteries C. Villevieille, C. Ionica-Bousquet, J. Olivier-Fourcade, M. Van Thournout, S. Levasseur, C. Tessier, and L. Monconduit
    2007 WO/2009/074208
  • High voltage negative active material for a rechargeable lithium battery C. Villevieille, J. Olivier-Fourcade, J.C. Jumas, L. Monconduit, M. Van Thournout, C. Tessier
    2008 WO/2010/112103
  • Enveloppe Soleau, "électrodes négatives à base de titane pour batteries Li-ion" C. Villevieille, J. Olivier-Fourcade, J.C. Jumas, L. Monconduit
    2008