Scientific Highlights
Unraveling degradation processes in a bipolar membrane CO2 electrolyzer by time-resolved X-ray tomographic microscopy
Employing a bipolar ion conducting membrane (BPM) in forward bias is a convenient solution for the biggest issues in the more common anion exchange membrane (AEM) CO2 co-electrolysis: the degradation of the performance caused by carbonate salt precipitation at the cathode and the decrease of net CO2 conversion caused by the crossover of this molecule from cathode to anode also requiring energy for downstream gas separation. However, the performance and stability of this device remain largely insufficient when using such a BPM configuration. To understand the reasons for this, we performed time-resolved X-ray tomographic microscopy of an operating BPM CO2 electrolyzer. The imaging method reveals partly unexpected degradation processes that result in design recommendations for improvement.
Developing detectors to transform science with light (part 1)
Part I: How the Jungfrau detector went from inception to perfection to ubiquity.
Ptychographic Nanoscale Imaging of the Magnetoelectric Coupling in Freestanding Bismuth Ferrite Films
Through soft X-ray ptychographic imaging, researchers at the Swiss Light Source have directly imaged the magneto-electric coupling between the ferroelectric domain structure and the spin-cycloidal state in freestanding BiFeO3 thin films.
Phonon promoted charge density wave in topological kagome metal ScV6Sn6
Charge density wave (CDW) orders in vanadium-based kagome metals have recently received tremendous attention, yet their origin remains a topic of debate. The discovery of ScV6Sn6, a bilayer kagome metal featuring an intriguing √3 × √3 × √3 CDW order, offers a novel platform to explore the underlying mechanism behind the unconventional CDW. Here we combine ...
Tuning of the flat band and its impact on superconductivity in Mo5Si3−xPx
The superconductivity in systems containing dispersionless (flat) bands is seemingly paradoxical, as traditional Bardeen-Cooper-Schrieffer theory requires an infinite enhancement of the carrier masses. However, the combination of flat and steep (dispersive) bands within the multiple band scenario might boost superconducting responses, potentially explaining high-temperature superconductivity in cuprates and metal hydrides. Here, we report ...
Altermagnetism proves its place on the magnetic family tree
Experiments at the Swiss Light Source SLS prove the existence of a new type of magnetism, with broad implications for technology and research.
Interface-induced superconductivity in magnetic topological insulators
One of the recipes for realizing topological superconductivity calls for interfacing a topological insulator with a superconductor. In a variant of that approach, Yi et al. grew a heterostructure consisting of layers of a magnetic topological insulator, (Bi,Sb)2Te3 doped with chromium, and antiferromagnetic iron telluride. Neither of these materials is superconducting, but iron telluride is a parent compound for a family of iron-based superconductors. Interfacing the layers led to the appearance of superconductivity in the presence of ferromagnetism and topological band structure. This combination of properties makes the heterostructure a promising, although not yet proven, platform for observing chiral topological superconductivity.
Extreme ultraviolet for scalable silicon quantum devices
Experiments at the Swiss Light Source (SLS) show the potential of extreme ultraviolet light (EUV) to make the building blocks of scalable quantum computers.
Unravelling the amorphous structure and crystallization mechanism of GeTe phase change memory materials
Here we use in-situ high-temperature x-ray absorption spectroscopy (XAS) and theoretical calculations to quantify the amorphous structure of bulk and nanoscale GeTe. Based on XAS experiments, we develop a theoretical model of the amorphous GeTe structure, consisting of a disordered fcc-type Te sublattice and randomly arranged chains of Ge atoms in a tetrahedral coordination.
Insights into the superior oxygen evolution reaction activity of CoOx/CeO2 composite electrocatalyst
CeO2 significantly enhances the oxygen evolution reaction (OER) activity of CoOx, although the mechanism behind this synergy is still unclear. Here, operando hard X-ray absorption spectroscopy (hXAS) is applied to monitor the Co-K edge and Ce L3 edge in CoOx/CeO2 to shed light on the evolution of Co and Ce oxidation states during OER. In addition, ex situ soft XAS (sXAS) characterizations provide information on the irreversible surface-specific transformations of the Co L3 edge as well as the O K edge.