Scientific Highlights
Methane storage in flexible metal–organic frameworks with intrinsic thermal management
As a cleaner, cheaper, and more globally evenly distributed fuel, natural gas has considerable environmental, economic, and political advantages over petroleum as a source of energy for the transportation sector. Despite these benefits, its low volumetric energy density at ambient temperature and moderate pressure presents substantial challenges, particularly for light-duty vehicles with little space available for on-board fuel storage.
Room-temperature carbon monoxide oxidation by oxygen over Pt-Al2O3 mediated by reactive platinum carbonates
A new possibility for the attainment of low-temperature oxidation of carbon monoxide is demonstrated. Here we report using time-resolved DRIFTS, XAS, and mass spectrometry a platinum carbonate-mediated mechanism for the room-temperature oxidation of carbon monoxide.
Interfacial Control of Magnetic Properties at LaMnO3/LaNiO3 heterostructures
Using a X-ray magnetic circular dichroism measured at the X-Treme beamline, SLS, in conjunction with X-ray reflectivity measured at the SEXTANTS beamline, SOLEIL, the authors show that the degree of intermixing at the monolayer scale allows interface-driven properties such as charge transfer and the induced magnetic moment in the nickelate layer to be controlled.
Fermi states and anisotropy of Brillouin zone scattering in the decagonal Al–Ni–Co quasicrystal
Quasicrystals (QCs) are intermetallic alloys where excellent long-range order coexists with lack of translational symmetry in one or more dimensions. These materials have a high potential in application as a material for a solar cells, hydrogen storage applications, heat insulating layers, and others.
Observation of Gravitationally Induced Vertical Striation of Polarized Ultracold Neutrons by Spin-Echo Spectroscopy
We describe a spin-echo method for ultracold neutrons (UCNs) confined in a precession chamber and exposed to a |B0| = 1μT magnetic field. We have demonstrated that the analysis of UCN spin-echo resonance signals in combination with knowledge of the ambient magnetic field provides an excellent method by which to reconstruct the energy spectrum of a confined ensemble of neutrons.
Response of Plasma-Polymerized Hexamethyldisiloxane Films to Aqueous Environments
Thin plasma polymer films were deposited in hexamethyldisiloxane (HMDSO) and HMDSO/O2 low-pressure discharges and their chemical structures analyzed using infrared (IR) spectroscopy and neutron reflectometry (NR). The (plasma-polymerized) ppHMDSO film exhibits hydrophobic, poly(dimethylsiloxane)-like properties, while the retention of carbon groups is reduced by O2 addition, yielding a more inorganic, hydrophilic ppSiOx film.
2015 Otto Kratky award
Marianne Liebi was awarded the 2015 Otto Kratky award by the Helmholtz-Centre Berlin for excellence in the field of small-angle X-ray scattering (SAXS) analysis. The award was bestowed in the last SAS2015 conference in Berlin. Marianne is a postdoctoral fellow in the coherent X-ray scattering group (CXS) in PSI, carrying out research in scanning SAXS measurement and analysis in 2D and 3D. Image credit ©HZB/Michael Setzpfandt
Remotely induced magnetism in a normal metal using a superconducting spin-valve
Superconducting spintronics has emerged in the past decade as a promising new field that seeks to open a new dimension for nanoelectronics by utilizing the internal spin structure of the superconducting Cooper pair as a new degree of freedom. Its basic building blocks are spin-triplet Cooper pairs with equally aligned spins, which are promoted by proximity of a conventional superconductor to a ferromagnetic material with inhomogeneous macroscopic magnetization.
Laser arrival time measurement and correction for the SwissFEL lasers
To probe ultrafast processes at SwissFEL it is crucial that the pump laser, used at the end stations, arrives in time with the generated X-ray pulses. For fs resolution pump probe experiments a path-length change of few-hundred nanometers already affects the measurement quality. The length of SwissFEL and the total propagation path of the pump laser light to the experiment is in the scale of several hundred meters, which makes this task challenging.
Thermodynamic phase transitions in a frustrated magnetic metamaterial
Materials with interacting magnetic degrees of freedom display a rich variety of magnetic behaviour that can lead to novel collective equilibrium and out-of-equilibrium phenomena. In equilibrium, thermodynamic phases appear with the associated phase transitions providing a characteristic signature of the underlying collective behaviour.