Scientific Highlights: Research Division "Research with Neutrons and Muons"
In situ stress observation in oxide films and how tensile stress influences oxygen ion conduction
Many properties of materials can be changed by varying the interatomic distances in the crystal lattice by applying stress. Ideal model systems for investigations are heteroepitaxial thin films where lattice distortions can be induced by the crystallographic mismatch with the substrate. Here we describe an in situ simultaneous diagnostic of growth mode and stress during pulsed laser deposition of oxide thin films.
Dramatic pressure-driven enhancement of bulk skyrmion stability
The recent discovery of magnetic skyrmion lattices initiated a surge of interest in the scientic community. Several novel phenomena have been shown to emerge from the interaction of conducting electrons with the skyrmion lattice, such as a topological Hall-effect and a spin-transfer torque at ultra-low current densities.
Coexistence of low-moment magnetism and superconductivity in tetragonal FeS and suppression of Tc under pressure
The family of iron-based superconductors has recently acquired a new member material, FeS. Theoretically, this compound has been shown to have electronic structure similar to that of the superconducting FeSe. However, contradictory ground states have been predicted for FeS. In this work, a collaboration of authors from Switzerland and Germany use muon spin rotation and relaxation to show that weak-moment magnetism microscopically coexists with bulk superconductivity.
Small-Angle Neutron Scattering Study of Interplay of Attractive and Repulsive Interactions in Nanoparticle-Polymer System
The phase behavior of nanoparticle (silica)−polymer (polyethylene glycol) system without and with an electrolyte (NaCl) has been studied. It is observed that nanoparticle−polymer system behaves very differently in the presence of electrolyte. In the absence of electrolyte, the nanoparticle−polymer system remains in one-phase even at very high polymer concentrations.
Mechanically Enhanced Liquid Interfaces at Human Body Temperature Using Thermosensitive Methylated Nanocrystalline Cellulose
The mechanical performance of materials at oil/water interfaces after consumption is a key factor affecting hydrophobic drug release. In this study, we methylated the surface of nanocrystalline cellulose (NCC) by mercerization and dimethyl sulfate exposure to produce thermosensitive biopolymers. These methylated NCC (metNCC) were used to investigate interfacial thermogelation at air/water and medium-chain triglyceride (MCT)/water interfaces at body temperature.
Self-Diffusion in Amorphous Silicon
The present Letter reports on self-diffusion in amorphous silicon. Experiments were done on 29Si/natSi heterostructures using neutron reflectometry and secondary ion mass spectrometry. The diffusivities follow the Arrhenius law in the temperature range between 550 and 700°C with an activation energy of (4.4 ± 0.3) eV.
In-situ visualization of stress-dependent bulk magnetic domain formation by neutron grating interferometry
The performance and degree of efficiency of industrial transformers are directly influenced by the magnetic properties of high-permeability steel laminations (HPSLs). Industrial transformer cores are built of stacks of single HPSLs. While the insulating coating on each HPSL reduces eddy-current losses in the transformer core, the coating also induces favorable inter-granular tensile stresses that significantly influence the underlying magnetic domain structure.
Rate of Molecular Transfer of Allyl Alcohol across an AOT Surfactant Layer Using Muon Spin Spectroscopy
The transfer rate of a probe molecule across the interfacial layer of a water-in-oil (w/o) microemulsion was investigated using a combination of transverse field muon spin rotation (TF-μSR), avoided level crossing muon spin resonance (ALC-μSR), and Monte Carlo simulations. Reverse micro-emulsions consist of nanometer-sized water droplets dispersed in an apolar solvent separated by a surfactant monolayer.
The flip-over effect in pulsed laser deposition: Is it relevant at high background gas pressures?
In pulsed laser deposition the use of a rectangular or elliptical beam spot with a non 1:1 aspect ratio leads to the so called flip-over effect. Here, the longest dimension of the laser spot results in the shortest direction of plasma plume expansion.
Nanostructure surveys of macroscopic specimens by small-angle scattering tensor tomography
The mechanical properties of many materials are based on the macroscopic arrangement and orientation of their nanostructure. This nanostructure can be ordered over a range of length scales. In biology, the principle of hierarchical ordering is often used to maximize functionality, such as strength and robustness of the material, while minimizing weight and energy cost.
Strong enhancement of s-wave superconductivity near a quantum critical point of Ca3Ir4Sn13
We report microscopic studies by muon spin rotation/relaxation as a function of pressure of the Ca3Ir4Sn13 and Sr3Ir4Sn13 cubic compounds, which are members of the (Ca1−xSrx)3Ir4Sn13 system displaying superconductivity and a structural phase transition associated with the formation of a charge density wave (CDW).
Direct evidence for a pressure-induced nodal superconducting gap in the Ba0.65Rb0.35Fe2As2 superconductor
The superconducting gap structure in iron-based high-temperature superconductors (Fe-HTSs) is non-universal. In contrast to other unconventional superconductors, in the Fe-HTSs both d-wave and extended s-wave pairing symmetries are close in energy. Probing the proximity between these very different superconducting states and identifying experi- mental parameters that can tune them is of central interest.
Intrinsic Paramagnetic Meissner Effect Due to s-Wave Odd-Frequency Superconductivity
In 1933, Meissner and Ochsenfeld reported the expulsion of magnetic flux - the diamagnetic Meissner effect - from the interior of superconducting lead. This discovery was crucial in formulating the Bardeen-Cooper-Schrieffer (BCS) theory of superconductivity. In exotic superconducting systems BCS theory does not strictly apply.
Visualizing the morphology of vortex lattice domains in a bulk type-II superconductor
Alike materials in the solid state, the phase diagram of type-II superconductors exhibit crystalline, amorphous, liquid and spatially inhomogeneous phases. The multitude of different phases of vortex matter has thence proven to act as almost ideal model system for the study of both the underlying properties of superconductivity but also of general phenomena such as domain nucleation and morphology.
Observation of Gravitationally Induced Vertical Striation of Polarized Ultracold Neutrons by Spin-Echo Spectroscopy
We describe a spin-echo method for ultracold neutrons (UCNs) confined in a precession chamber and exposed to a |B0| = 1μT magnetic field. We have demonstrated that the analysis of UCN spin-echo resonance signals in combination with knowledge of the ambient magnetic field provides an excellent method by which to reconstruct the energy spectrum of a confined ensemble of neutrons.
Response of Plasma-Polymerized Hexamethyldisiloxane Films to Aqueous Environments
Thin plasma polymer films were deposited in hexamethyldisiloxane (HMDSO) and HMDSO/O2 low-pressure discharges and their chemical structures analyzed using infrared (IR) spectroscopy and neutron reflectometry (NR). The (plasma-polymerized) ppHMDSO film exhibits hydrophobic, poly(dimethylsiloxane)-like properties, while the retention of carbon groups is reduced by O2 addition, yielding a more inorganic, hydrophilic ppSiOx film.
Remotely induced magnetism in a normal metal using a superconducting spin-valve
Superconducting spintronics has emerged in the past decade as a promising new field that seeks to open a new dimension for nanoelectronics by utilizing the internal spin structure of the superconducting Cooper pair as a new degree of freedom. Its basic building blocks are spin-triplet Cooper pairs with equally aligned spins, which are promoted by proximity of a conventional superconductor to a ferromagnetic material with inhomogeneous macroscopic magnetization.
Thermodynamic phase transitions in a frustrated magnetic metamaterial
Materials with interacting magnetic degrees of freedom display a rich variety of magnetic behaviour that can lead to novel collective equilibrium and out-of-equilibrium phenomena. In equilibrium, thermodynamic phases appear with the associated phase transitions providing a characteristic signature of the underlying collective behaviour.
Pressure-induced electronic phase separation of magnetism and superconductivity in CrAs
The recent discovery of pressure (p) induced superconductivity in the binary helimagnet CrAs has raised questions on how superconductivity emerges from the magnetic state and on the mechanism of the superconducting pairing. In the present work the suppression of magnetism and the occurrence of superconductivity in CrAs were studied by means of muon spin rotation.
Néel-type skyrmion lattice with confined orientation in the polar magnetic semiconductor GaV4S8
Following the early prediction of the skyrmion lattice (SkL) - a periodic array of spin vortices - it has been observed recently in various magnetic crystals mostly with chiral structure. Although non-chiral but polar crystals with Cnv symmetry were identified as ideal SkL hosts in pioneering theoretical studies, this archetype of SkL has remained experimentally unexplored.