Advanced Characterization of Battery Materials

The Advanced Characterization group as 2016

The development and utilization of innovative characterization techniques, either in post mortem or operando mode, enable to probe the different reaction mechanisms taking place in a cell on the micro and macro-scopic length scales at the bulk level, i.e., lithium insertion and extraction, at the surface level, i.e., SEI formation, as well as at the electrolyte level. Knowing such reaction mechanisms is essential to understand the battery performance. For this purpose, we use and combine a wide range of techniques dedicated to surface and bulk characterization such as x-ray photoemission spectroscopy (XPS)*, scanning electron microscopy (SEM), vibrational spectroscopy (IR and Raman)*, impedance spectroscopy*, x-ray diffraction (XRD)*, etc, in house; and at the synchrotron sources like SLS and SOLEIL, soft and hard x-ray photoemission spectroscopy, x-ray photoemission electron microscopy (XPEEM), x-ray diffraction*, x-ray absorption spectroscopy*, etc. *Operando electrochemical cells are also available for these techniques.

Alice Judith Gillen 2014 University of Dublin, Trinity College
  • Surface investigation of Li-ion battery electrodes at the micro and nano scale combining XPS and XPEEM techniques. (Elucidating the different reaction mechanisms taking place at the interface electrolyte/electrode)
  • Structural and electrochemical studies of insertion anode materials for lithium-ion battery electrodes.
  • Surface and bulk studies of LiNi0.80Co0.15Al0.05O2 (NCA) electrodes.
  • Thin film surface and bulk investigation of alloys materials used as model electrodes (e.g) Si, SiO2, Sn, and SnO2.
  • Conversion (redox) processes: New chemical reactions beyond Li-ion intercalation for high energy density materials.
  • Interface stability in solid state batteries using post mortem and operando XPS.
  • Switch of the charge storage mechanism of LixNi0.80Co0.15Al0.05O2 at overdischarge conditions R. Robert, P. Novák
    Chem. Mater. 30, 1907−1911 (2018)
    DOI: 10.1021/acs.chemmater.7b04784OG-5410 , OG-5414
  • Monitoring the chemical and electronic properties of electrolyte-electrode interfaces in all-solid-state batteries using operando X-ray photoelectron spectroscopy X. Wu, C. Villevieille, P. Novák, M. El Kazzi
    Phys. Chem. Chem. Phys. 20, 11123-11129 (2018)
    DOI: 10.1039/C8CP01213JOG-5410 , OG-5411 , OG-5414
  • Electrochemical performance of all-solid-state Li-ion batteries based on garnet electrolyte using silicon as a model electrode G. Ferraresi, M. El Kazzi, L. Czornomaz, C.-L. Tsai, S. Uhlenbruck, C. Villevieille
    ACS Energy Lett. 3, 1006-1012 (2018)
    DOI: 10.1021/acsenergylett.8b00264OG-5410 , OG-5411 , OG-5414
  • SnO2 model electrode cycled in Li-ion battery reveals the formation of Li2SnO3 and Li8SnO6 phases through conversion reactions G. Ferraresi, C. Villevieille, I. Czekaj, M. Horisberger, P. Novák, M. El Kazzi
    ACS Appl. Mater. & Interfaces 10 (10), 8712-8720 (2018)
    DOI: 10.1021/acsami.7b19481OG-5410 , OG-5411 , OG-5414
  • Interface and safety properties of phosphorus-based negative electrodes in Li-ion batteries C. Marino, M. El Kazzi, E.J. Berg, M. He, C. Villevieille
    Chem. Mater. 29 (17), 7151-7158 (2017)
    DOI: 10.1021/acs.chemmater.7b01128OG-5410 , OG-5411 , OG-5412 , OG-5414
  • Colloidal synthesis and electrochemistry of surface coated nano-LiNi0.80Co0.15Al0.05O2 R. Asakura, P. Novák, R. Robert
    J. Electrochem. Soc. 164 (12), A2617-A2624 (2017)
    DOI: 10.1149/2.1431712jesOG-5410 , OG-5414
  • Surface and morphological investigation of the electrode/electrolyte properties in an all-solid-state battery using a Li2S-P2S5 solid electrolyte X. Wu, M. El Kazzi, C. Villevieille
    J. Electroceram. 38, 1-8 (2017)
    DOI: 10.1007/s10832-017-0084-zOG-5410 , OG-5411 , OG-5414
  • Elucidating the surface reactions of an amorphous Si thin film as a model electrode for Li-Ion batteries G. Ferraresi, L. Czornomaz, C. Villevieille, P. Novák, M. El Kazzi
    ACS Appl. Mater. Interfaces 8 (43), 29791-29798 (2016)
    DOI: 10.1021/acsami.6b10929OG-5410 , OG-5411 , OG-5414
  • Vanadium (V) reduction reaction on modified glassy carbon electrodes - Role of Oxygen functionalities and microstructure S.M. Taylor, A. Patru, D. Streich, M. El Kazzi, E. Fabbri, T.J. Schmidt
    Carbon 109, 472-478 (2016)
    DOI: 10.1016/j.carbon.2016.08.044OG-5414 , OG-5423
  • Advanced water management in PEFCs: Diffusion layers with patterned wettability
    I. Synthetic routes, wettability tuning and thermal stability
    A. Forner-Cuenca, V. Manzi-Orezzoli, J. Biesdorf, M. El Kazzi, D. Streich, L. Gubler, T.J. Schmidt, P. Boillat
    J. Electrochem. Soc. 163 (8), F788-F801 (2016)
    DOI: 10.1149/2.0271608jesOG-5414 , OG-5420 , OG-5424
  • Investigation of Li-Ion solvation in carbonate based electrolytes using near ambient pressure photoemission M. El Kazzi, I. Czekaj, E.J. Berg, P. Novák, M.A. Brown
    Top Catal 59, 628–634 (2016)
    DOI: 10.1007/s11244-015-0518-2OG-5410 , OG-5412 , OG-5414
  • Size-resolved identification, characterization, and quantification of primary biological organic aerosol at a European rural site C. Bozzetti, K.R. Daellenbach, Ch. Hueglin, P. Fermo, J. Sciare, A. Kasper-Giebl, Y. Mazar, G. Abbaszade, M. El Kazzi, R. Gonzalez, T. Shuster-Meiseles, M. Flasch, R. Wolf, A. Křepelová, F. Canonaco, J. Schnelle-Kreis, J.G. Slowik, R. Zimmermann, Y. Rudich, U. Baltensperger, I. El Haddad, A.S.H. Prévôt
    Environmental Science & Technology 50 (7), 3425-3434 (2016)
    DOI: 10.1021/acs.est.5b05960OG-5410 , OG-5414
  • Structural changes and microstrain generated on LiNi0.80Co0.15Al0.05O2 during cycling: Effects on the electrochemical performance R. Robert, P. Novák
    J. Electrochem. Soc. 162 (9), A1823-A1828 (2015)
    DOI: 10.1149/2.0721509jesOG-5410 , OG-5414
  • Surface/Interface study on full xLi2MnO3{middle dot}(1 - x)LiMO2 (M = Ni, Mn, Co)/graphite cells L. Boulet-Roblin, M. El Kazzi, P. Novák, C. Villevieille
    J. Electrochem. Soc. 162, 7, A1297-A1300 (2015)
    DOI: 10.1149/2.0491507jesOG-5410 , OG-5411 , OG-5414
  • Understanding the interaction of the carbonates and binder in Na-Ion batteries: A combined bulk and surface study L.O. Vogt, M. El Kazzi, E. Jämstorp Berg, S. Pérez Villar, P. Novák, C. Villevieille
    Chem. Mater. 27, 1210-1216 (2015)
    DOI: 10.1021/cm5039649OG-5410 , OG-5411 , OG-5412 , OG-5414
  • Activation mechanism of LiNi0.80Co0.15Al0.05O2: Surface and bulk operando electrochemical, differential electrochemical mass spectrometry, and X‑ray diffraction analyses R. Robert, Ch. Bünzli, E.J. Berg, P. Novák
    Chem. Mater. 27, 526−536 (2015)
    DOI: 10.1021/cm503833bOG-5410 , OG-5412 , OG-5413 , OG-5414
  • One-pot polyol synthesis of Pt/CeO2 and Au/CeO2 nanopowders as catalysts for CO oxidation F. Pilger, A. Testino, M.A. Lucchini, A. Kambolis, M. Tarik, M. El Kazzi, Y. Arroyo, M.D. Rossell, Ch. Ludwig
    J. Nanoscience and Nanotechnology 15, 5 (10), 3530-3539 (2015)
    DOI: 10.1166/jnn.2015.9861OG-5410 , OG-5414
  • Oxygen Evolution Reaction on La1-xSrxCoO3 Perovskites: A Combined Experimental and Theoretical Study of Their Structural, Electronic, and Electrochemical Properties X. Cheng, E. Fabbri, M. Nachtegaal, I. Castelli, M. El Kazzi, R. Haumont, N. Marzari, T.J. Schmidt
    Chem. Mater. 27, 7662-7672 (2015)
    DOI: 10.1021/acs.chemmater.5b03138OG-5414 , OG-5423
  • Differential electrochemical mass spectrometry study of the interface of xLi2MnO3·(1−x)LiMO2 (M = Ni, Co, and Mn) Material as a positive electrode in Li-Ion batteries E. Castel, E.J. Berg, M. El Kazzi, P. Novak, C. Villevieille
    Chem. Mater. 26, 5051-5057 (2014)
    DOI: 10.1021/cm502201zOG-5410 , OG-5411 , OG-5412 , OG-5414
  • Continuous synthesis of nickel nanopowders: Characterization, process optimization, and catalytic properties M.A. Lucchini, A. Testino, Ch. Ludwig, A. Kambolis, M. El Kazzi, A. Cervellino, P. Riani, F. Canepa
    Applied Catalysis B: Environmental 156–157, 404–415 (2014)
    DOI: 10.1016/j.apcatb.2014.03.045OG-5410 , OG-5414
  • Enhancement of the high potential specific charge in layered electrode materials for lithium-ion batteries R. Robert, C. Villevielle, P. Novák
    J. Mater. Chem. A 2, 8589-8598 (2014).
    DOI: 10.1039/C3TA12643AOG-5410 , OG-5411 , OG-5414