News & Scientific Highlights

A complete characterization of the unit cell dynamics of a laser-excited tellurium crystal is demonstrated using femtosecond x-ray diffraction. The analysis offers a quantitative measure of the unit cell dynamics without making any assumptions on the symmetry of the excited-state motion.

Photon squeezing has been the subject of intense interest in the field of quantum optics, since it serves as a unique demonstration of the quantum nature of light. On a practical level, squeezing offers opportunities to make interferometric measurements much more precise than would normally be allowed by quantum uncertainty limits.

X-ray absorption spectroscopy is a powerful probe of molecular structure, but it has previously been too slow to track the earliest dynamics after photoexcitation. We investigated the ultrafast formation of the lowest quintet state of aqueous iron(II)tris(bipyridine) upon excitation of the singlet metal-to-ligand-charge-transfer (¹MLCT) state by femtosecond optical pump/x-ray probe techniques based on x-ray absorption near-edge structure (XANES).

We employ grazing-incidence femtosecond x-ray diffraction to characterize the coherent, femtosecond laser-induced lattice motion of a bismuth crystal as a function of depth from the surface with a temporal resolution of ~200 fs. The data show direct consequences on the lattice motion from carrier diffusion and electron-hole interaction, allowing us to estimate the effective diffusion rate for the highly excited carriers and the electron-hole interaction time.

The typical time scale of atomic motion during fundamental physical processes such as phase transitions in solids or molecular dynamics in chemical reactions ranges from ten to hundreds of femtoseconds. The direct observation of these processes on an atomic length scale therefore requires utrashort light pulses at wavelengths capable of resolving the underlying atomic structures.