Various gas-phase mechanisms are supported in CAMx (version CAMx v5.30). These are Carbon Bond Mechanism IV (Gery et al., 1989), CB05 (Yarwood et al., 2005), SAPRC99 chemical mechanism (Carter, 2000). We are using CB05 with aerosol chemistry.
CAMx provides two options for treating aerosol size distributions: the CF scheme and CMU scheme. The CF scheme divides the size distribution into two static modes (coarse and fine). Primary species are modeled as fine and/or coarse particles, while all secondary species are modeled as fine particles only. The CMU scheme employs a sectional approach that dynamically models the size evolution of each aerosol constituent across a number of fixed size sections. The user defines the number of size sections and their size ranges.
In CAMx, aerosol processes are linked to all gas-phase mechanisms. The gas-phase photochemistry forms aerosol precursors via the OH initiated oxidation of SO2 to sulfate, production of nitric acid, and formation of condensable organic gases. The aerosol precursors are supplied to aerosol chemistry, which performs the following processes:
* aqueous sulfate and nitrate formation in resolved cloud water using RADM aqueous chemistry algorithm (Chang et al., 1987)
* partitioning of condensable organic gases (CG1-CG7) to secondary organic aerosols (SOA1-SOA7) to form a condensed organic solution phase using a semi-volatile equilibrium scheme called SOAP (Strader et al., 1999)
* partitioning of inorganic aerosol constituents (sulfate, nitrate, ammonium, sodium, and chloride) between the gas and particle phases using the ISORROPIA thermodynamic module (Nenes et al., 1998)
* uptake of nitric acid by calcium in soil dust particles is calculated external to ISORROPIA
The CAMx SOA module consists of two parts: gas-phase oxidation chemistry that forms condensable gases (CGs) and equilibrium partitioning between gas and aerosol phases for each CG/SOA pair. Anthropogenic SOA precursors are toluene and xylene. Biogenic SOA precursors are isoprene, monoterpenes and sesquiterpenes. Polymerization is also included. based on limited available data, it was assumed that SOA polymerized to a non-volatile form (i.e. moved permanently to the aerosol phase) with a lifetime of about 1 day. Polymerization slowly forms organic aerosol polymers called SOPA (anthropogenic) and SOPB (biogenic).
Trace gases and small particles are removed from the atmosphere via deposition to the surface. Dry deposition refers to the direct sedimentation and/or diffusion of material to various terrestrial surfaces and uptake into biota. Dry deposition of gases is based on the resistance models of Wesely (1989) and most recently Zhang et al.(2003). Surface deposition of particles occurs via diffusion, impaction and/or gravitational settling. The resistance approach used in UAM-AERO has been adopted in CAMx4. Wet deposition refers to the uptake of material via chemical absorption (gases) or nucleation/impaction into cloud water, and subsequent transfer to the Earth’s surface by precipitation. The efficiency of wet and dry deposition processes to remove pollutants from the air depends on the physical and chemical properties of the pollutants, local meteorological conditions, the type of surface on which they are being deposited, and on the frequency, duration, and intensity of precipitation events. The wet scavenging model implemented in CAMx4, calculates the following processes: wet scavenging of gases within and below precipitating clouds, wet scavenging of gases dissolved in cloud water, and in-cloud aerosols, and wet scavenging of dry particles.
Input and Output Files
CAMx requires inputs to describe photochemical conditions, surface characteristics, initial and boundary conditions, emission rates, and various meteorological fields over the entire modeling domain. Preparing this information requires several preprocessing steps to translate raw data to final input files. The model produces hourly average concentration output files, deposition and mass budget.
Particulate Source Apportionment Technology (PSAT)
CAMx has a tool for source apportionment of particles. PSAT is designed to source apportion both primary and secondary particles in CAMx.
Carter W.P.L., 2000. Programs and files implementing the SAPRC-99 mechanism and its associates emissions processing procedures for Models-3 and other regional models. January 31, 2000.
Chang J.S., R.A.Brost, I.S.A.Isaksen, S.Madronich, P.Middleton, W.R.Stockwell, and C.J.Walcek, 1987. A three-dimensional eulerian acid deposition model: Physical concepts and formulation, J. Geophys. Res., 92, 14,681-14,700.
Gery M.W., G.Z.Whitten, J.P.Killus, and M.C.Dodge, 1989. A Photochemical kinetics mechanism for urban and regional scale computer modeling. J. Geophys. Res., 94, 925-956.
Nenes A., C. Pilinis, ans S.N. Pandis, 1998. “ISORROPIA: A new thermodynamic model for multiphase multicomponent Inorganic aerosols” Aquatic Geochemistry, 4, 123-152.
Strader R., C. Gurciullo, S.N.Pandis, N.Kumar, and F.W.Lurmann, 1998. Development of gas-phase chemistry, secondary organic aerosol, and aqueous-phase chemistry modules for PM modeling. Final report for CRC Project A21-1 prepared for the Coordinating Research Council, Atlanta, GA by Sonoma Technology, Inc. Petaluma, CA, STI-97510-1822-FR, October.
Wesely M.L., 1989. Parameterization of surface resistances to gaseous dry deposition in regional-scale numerical models. Atmos. Environ., 23, 1293-1304.
Yarwood G., S. Rao, M. Yocke, G.Z. Whitten (2005). Updates to the Carbon Bond Chemical Mechanism : CB05. Final report prepared for US EPA. Available at http://www.camx.com/publ/pdfs/CB05_Final_Report_120805.pdf.
Zhang L., J.R. Brook and R. Vet. 2003. A revised parameterization for gaseous dry deposition in air-quality models. Atmos. Chem. Phys., 3, 2067-2082.
firstname.lastname@example.org WRF) Model is a next-generation mesoscale numerical weather prediction system designed to serve both operational forecasting and atmospheric research needs. It features multiple dynamical cores, a 3-dimensional variational (3DVAR) data assimilation system, grid and observation nudging, and a software architecture allowing for computational parallelism and system extensibility. WRF is suitable for a broad spectrum of applications for 2-way nested domains across scales ranging from meters to thousands of kilometers.
At LAC the Advanced Research WRF (WRF-ARW, Version 3.2.1) is used as the meteorological driver for the Air Quality model CAMx. Input data for WRF is provided by the WRF pre-processing System (WPS), which is controlled by global/regional forecasts or re-analyses. Currently ECMWF re-analyses with 0.72 deg and 3h resolutions are used. The WRF output is post-processed by the utility WRFCAMx, which converts the NetCDF data into the quantities and format required by CAMx.
WRF-ARW supports numerous projections. In previous air quality projects covering Central Europe , e.g. BAFU GOTHENBURG-2010, the lambert conical projection was used. Recent projects such as BAFU GOTHENBURG-2020, however, are extended to whole Europe, which require lon / lat coordinates to avoid geometric distortion. Since WRFCAMx does not support lon / lat to lon / lat transformation, the utility had to be modified. Current studies are based on 2 nested domains (whole Europe, Central Europe), the coarse domain having a spatial resolution of 0.250 deg (lon) and 0.125 deg (lat).
The WRF package runs on Cray XT5 (rosa.cscs.ch) at the Swiss National Supercomputing Centre (CSCS) at Manno. WRF-ARW jobs are submitted as distributed memory parallel MPI jobs. The optimum number of cpu’s for whole Europe is about 180.
WPS, WRF-ARW and WRFCAMx requires quite a few input data, in particular namelists for job control and the external meteorological forecasts or re-analyses. Parameters set in namelists and paths of I/O files depend on time and have to be consistent within the whole program system. To make sure that this consistency is fulfilled, the pre-processor package wrfprep has been developed. It is written in IDL and runs on the PSI linux cluster.
For most species and source categories the emissions are available as country specific yearly totals. Road traffic emissions are usually calculated on the basis of emission factors, which depend on vehicle type, speed, traffic intensity, etc. From space and time distributions of characteristics such as industrial activity, road traffic, etc., gridded emission rates are generated. The emission inventory of a given country is usually available in the coordinate system specific for that country.
Meso-scale air quality models such as CAMx are mostly applied to domains of interest that cover several countries. Hence, in most cases the coordinates of the original emission inventories must be converted to the model system. In addition, the species of the inventories and of the chemical mechanisms implemented in the model are not the same. For instance, there is often no sufficient splitting of non-methane volatile organic compounds (NMVOC) into the species required by the mechanism. CAMx v5.30 supports various versions of the Carbon Bond Mechanism. We currently apply the CB05 mechanism. This mechanism is based on chemical bonds. Examples are the single (paraffinic, PAR) and the double (olefinic, OLE) bond. Molecules are split into a specified number of PARs and OLEs according to their number of reactive bonds. For instance, n-butane is represented by 4 PAR, propene by 1 OLE + 1 PAR.
Annual emissions refer to a specific year. The European data set, for instance, is available for 2006. To harmonize data from different sources and reference years, emissions have to be converted to a common reference year. Emissions for most European countries are available for the past (submitted to EMEP / CEIP) and as projections for the future (simulation of the IIASA / GAINS model) to be used for scaling emission data to a year of interest. The hourly emissions for a specific year in the format required by CAMx is compiled from the raw data described below using the IDL based procedure package EMISSCAMX developed at LAC. MACC) project has been developed by The Netherlands Organisation for Applied Scientific Research (TNO). The inventory includes PM10, PM2.5, CH4, CO, NH3, NMVOC, NOx and SO2 for 15 source categories following the SNAP classification:
|1||public power, cogeneration and district heating plants|
|2||commercial, institutional and residential combustion|
|3||industrial combustion and processes with combustion|
|4||non-combustion production processes|
|5||extraction and distribution of fossil fuels|
|7.1||road transport gasoline|
|7.2||road transport diesel|
|7.3||road transport LPG|
|7.4||road transport evaporation|
|7.5||road transport non-exhaust (brake, tyre and road wear)|
|7||road transport (total of 7.1 to 7.5)|
|8||other mobile sources and machinery (including ships)|
|9||waste treatment and disposal|
Road traffic emissions
Annual road traffic emissions of PM10, PM2.5, NOx, CO, NMVOC, toluene, benzene and xylene were prepared by INFRAS and Meteotest on the basis of contracts with the Federal Office of the Environment (BAFU). Data are split into link and zone emissions. The spatial resolution is 250m, the co-ordinates are based on the Swiss co-ordinate system. Reference year is 2000 or 2005, depending on the species. An average diurnal variation was provided as well.
Industrial and residential emissions
Annual CO, NOx NMVOC, PM10 and PM2.5 NOx emissions from residential activities, heating, industry, off-road traffic and agriculture / forestry on a 200 m resolution were provided by Meteotest. Reference year is 2000. Spatial distributions of total annual NMVOC emissions from industry and household were also provided by INFRAS. The split into the explicit speciation according to the scheme of Passant and the conversion to CBM05 was performed on the basis of a survey of different sources such as paint production, paint use, printing industry, solvent use, etc. performed by Carbotech.
Ammonia is released mainly by manure, followed by waste treatment and road traffic. Meteotest provided annual NH3 emissions for 2007 on a 1 km grid
Gridded temperature and shortwave irradiance data were extracted from the WRF-ARW
The biogenic emission algorithm is currently extended for additional tree species and substances, e.g. sesquiterpenes.
Daily Monoterpene Emissions in Europe
Andreani-Aksoyoglu S., Keller J., 1995. Estimates of monoterpene and isoprene emissions from the forests in Switzerland. J. Atmospheric Chemistry 20 71-87.
BFS, 1999. GEOSTAT Benuetzerhandbuch, Bern.
Keller J., Andreani-Aksoyoglu S., Joss U., 1995. Inventory of natural emissions in Switzerland. In Air Pollution III, Air Pollution Engineering and Management, 339-346. Computational Mechanics Publications, Southampton.
Mahrer F., Vollenweider C., 1983. Landesforstinventar LFI, Eidgenössische Forschungsanstalt für Wald, Schnee und Landschaft (WSL), Birmensdorf.
Passant N. R., 2002. Speciation of UK emissions of non-methane volatile organic compounds. AEA Technology, Culham.
Simpson D., Winiwarter W., Börjesson G., Cinderby S., Ferreiro A., Guenther A., Hewitt N. C., Janson R., Khalil M. A. K., Owen S., Pierce T. E., Puxbaum H., Shearer M., Skiba U., Steinbrecher R., Tarrasón L., Öquist M. G., 1999. Inventorying emissions from nature in Europe. Journal of Geophysical Research 104 (D7), 8113-8152.
email@example.com BAFU GOTHENBURG-2010
BAFU Ozone Summer 2003
BAFU Summer Winter Air Quality